公开(公告)号：US08900333B2

公开(公告)日：2014-12-02

申请号：US12316721

申请日：2008-12-16

Applicant: Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

Inventor： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

IPC: C10L10/14 ,  C10L1/236 ,  C10L1/198 ,  C10L1/196

CPC classification number: C10L10/14 ,  C10L1/1963 ,  C10L1/1985 ,  C10L1/2364 ,  C10L1/2366 ,  C10L2200/0476 ,  Y02E50/13

Abstract: The present invention is directed to the use of alkyl(meth)acrylate polymers or copolymers of the formula (I) In-Poly-(E)y  (I) as cold flow improvers in biodiesel fuel (or bio-fuel) and biodiesel compositions incorporating said polymers or copolymers, obtained by nitroxyl mediated controlled free radical polymerization, wherein In is the initiator fragment starting the polymerization reaction; E is an end group bearing at least one stable free nitroxyl radical, which is bound via an oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; Poly is any polymer or copolymer formed from ethylenically unsaturated monomer(s); and y is a number 1 or greater than 1 indicating the average number of end groups E attached to Poly.

Abstract translation: 本发明涉及在生物柴油燃料（或生物燃料）和生物柴油组合物中使用（甲基）丙烯酸烷基酯聚合物或共聚物（I）In-Poly-（E）y（I））作为冷流动改进剂 加入通过硝酰基介导的受控自由基聚合获得的所述聚合物或共聚物，其中In是开始聚合反应的引发剂片段; E是具有至少一个稳定的游离硝酰基的端基，其通过氧原子与聚合物或共聚物结合; 或由所连接的稳定游离硝酰基的取代或消除反应产生的基团; Poly是由烯属不饱和单体形成的任何聚合物或共聚物; y是数字1或大于1，表示连接到Poly的端基E的平均数。

公开(公告)号：US20110040018A1

公开(公告)日：2011-02-17

申请号：US12867770

申请日：2009-02-03

Applicant: Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

Inventor： Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

IPC: C09D133/16 ,  C09D133/26

CPC classification number: C09D133/26 ,  C08L33/16 ,  C08L2312/00 ,  C08L2666/04

Abstract: The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerisation or by conventional radical polymerisation comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.

Abstract translation: 本发明涉及包含短链氟化丙烯酸酯和使用短链氟化丙烯酸酯作为着色和未着色涂料组合物的流平剂的涂料组合物。 涂料组合物包含a）成膜粘合剂树脂，和b）通过控制聚合制备的共聚物或通过常规自由基聚合制备的共聚物，其包含选自（甲基）丙烯酸酯，苯乙烯类单体或（甲基）丙烯酸酯的组中的不饱和单体的单体（M1x） 甲基）丙烯酰胺，由此共聚物含有至少> 30重量％的（甲基）丙烯酸酯; 和选自（甲基）丙烯酸C 1 -C 4 - 氟烷基酯的单体（M2y）; x表示结构元素（M1x）中单体M1的总数：x> 5，优选10-1000，最优选10-500; y表示结构元素（M2y）中单体M2的总数：y> 1，优选2-20，最优选2-10; c）可选的其它常规涂料组分和/或添加剂。

公开(公告)号：US08669336B2

公开(公告)日：2014-03-11

申请号：US12867770

申请日：2009-02-03

Applicant: Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

Inventor： Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

IPC: C08F18/20

CPC classification number: C09D133/26 ,  C08L33/16 ,  C08L2312/00 ,  C08L2666/04

Abstract: The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerization or by conventional radical polymerization comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.

Abstract translation: 本发明涉及包含短链氟化丙烯酸酯和使用短链氟化丙烯酸酯作为着色和未着色涂料组合物的流平剂的涂料组合物。 涂料组合物包括a）成膜粘合剂树脂，和b）通过控制聚合或通过常规自由基聚合制备的共聚物，其包含选自（甲基）丙烯酸酯，苯乙烯类单体或（甲基）丙烯酸酯的组中的不饱和单体的单体（M1x） 甲基）丙烯酰胺，由此共聚物含有至少> 30重量％的（甲基）丙烯酸酯; 和选自（甲基）丙烯酸C 1 -C 4 - 氟烷基酯的单体（M2y）; x表示结构元素（M1x）中单体M1的总数：x> 5，优选10-1000，最优选10-500; y表示结构元素（M2y）中单体M2的总数：y> 1，优选2-20，最优选2-10; c）可选的其它常规涂料组分和/或添加剂。

公开(公告)号：US07731761B2

公开(公告)日：2010-06-08

申请号：US12309300

申请日：2007-07-09

Applicant: Sophie Marquais-Bienewald ,  Olof Wallquist ,  Christian Cremer ,  Beate Fröhling ,  Andreas Möck

Inventor： Sophie Marquais-Bienewald ,  Olof Wallquist ,  Christian Cremer ,  Beate Fröhling ,  Andreas Möck

IPC: A61Q5/10 ,  C07D213/22

CPC classification number: A61K8/84 ,  A61K8/8152 ,  A61K8/8158 ,  A61K8/86 ,  A61K8/898 ,  A61K2800/43 ,  A61K2800/5426 ,  A61K2800/57 ,  A61K2800/594 ,  A61Q5/02 ,  A61Q5/065 ,  A61Q5/12 ,  C09B69/105 ,  C09B69/106 ,  C09B69/107 ,  C09B69/109

Abstract: Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1000; n is a number from O to 1000; and p is a number from 1 to 1000; wherein the sum of m+n+p≧3.

Abstract translation: 公开了式（1a）的聚合染料; （1b）; 或（1c）; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-C1-C10亚烷基 - 的连接基团; -C 2 -C 12亚烯基 -C 5 -C 10环亚烷基 - C5-C10亚芳基 -C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ; -C（O） - ; - （CH 2 CH 2 -O）1-5-; -C（O）O-; -OCO-; -N（R 1） - ; -CON（R 1） - ; - （R1）NC（O） - ; -0-; -S-; -所以）-; -S（O）2 - ; -S（O）2 -N（R 1 R 2）; 或直接债券; R1和R2彼此独立地是氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2中的至少一个是有机染料的残基; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到1000的数字; n是从0到1000的数字; p是从1到1000的数字; 其中m + n +p≥3的和。

公开(公告)号：US20090255063A1

公开(公告)日：2009-10-15

申请号：US12309300

申请日：2007-07-09

Applicant: Sophie Marquais-Bienewald ,  Olof Wallquist ,  Christian Cremer ,  Beate Fröhling ,  Andreas Möck

Inventor： Sophie Marquais-Bienewald ,  Olof Wallquist ,  Christian Cremer ,  Beate Fröhling ,  Andreas Möck

IPC: A61K8/42 ,  A61Q5/10 ,  C08G73/04 ,  C08F283/12 ,  C08F283/04

CPC classification number: A61K8/84 ,  A61K8/8152 ,  A61K8/8158 ,  A61K8/86 ,  A61K8/898 ,  A61K2800/43 ,  A61K2800/5426 ,  A61K2800/57 ,  A61K2800/594 ,  A61Q5/02 ,  A61Q5/065 ,  A61Q5/12 ,  C09B69/105 ,  C09B69/106 ,  C09B69/107 ,  C09B69/109

Abstract: Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1000; n is a number from O to 1000; and p is a number from 1 to 1000; wherein the sum of m+n+p≧3.

Abstract translation: 公开了式（1a）的聚合染料; （1b）; 或（1c）; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-C1-C10亚烷基 - 的连接基团; -C 2 -C 12亚烯基 -C 5 -C 10环亚烷基 - C5-C10亚芳基 -C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ; -C（O） - ; - （CH 2 CH 2 -O）1-5-; -C（O）O-; -OCO-; -N（R 1） - ; -CON（R1） - ; - （R1）NC（O） - ; -0-; -S-; -所以）-; -S（O）2 - ; -S（O）2 -N（R 1 R 2）; 或直接债券; R1和R2彼此独立地是氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2中的至少一个是有机染料的残基; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到1000的数字; n是从0到1000的数字; p是从1到1000的数字; 其中m + n + p> = 3的和。