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    END-FUNCTIONALIZED POLYMERS
    1.
    发明申请
    END-FUNCTIONALIZED POLYMERS 审中-公开

    公开(公告)号：US20130030071A1

    公开(公告)日：2013-01-31

    申请号：US13638191

    申请日：2011-03-29

    申请人： Huiguang Kou ,  Andreas Moeck ,  Clemens Auschra ,  Peter Nesvadba ,  Frank Oliver Heinrich Pirrung ,  Andreas Gernandt

    发明人： Huiguang Kou ,  Andreas Moeck ,  Clemens Auschra ,  Peter Nesvadba ,  Frank Oliver Heinrich Pirrung ,  Andreas Gernandt

    IPC分类号： C08F120/10 ,  C08J9/228 ,  C09D133/08

    CPC分类号： C08F8/44 ,  C08F2/001 ,  C08F8/00 ,  C08F8/30 ,  C08F8/42 ,  C08F12/08 ,  C08F16/12 ,  C08F20/12 ,  C08F20/54 ,  C08F26/10 ,  C08F36/06 ,  C08F36/08 ,  C08F293/005 ,  C08F2438/02 ,  C08F2810/40

    摘要： This invention relates to end-functionalized living polymers or copolymers having a structure represented by the general formula 1 or 2, wherein R1 is a hydrogen atom, a methyl group, or a radically non-polymerizable organic group containing 1 to 20 carbon atoms. R2 is a functional end group of a vinyl hetero monomer selected from the group consisting of hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl), N(C1-C6alkyl)2, —CH═CH2, —C≡CH, —C(CH3)═CH2, -0-CH═CH2, (—O—CH2—CH2)1-10—OH, —OR20, —COOR20, —CONHR20, —OCONHR20, —OCOR20 and —NH—CO—R20, wherein R20 is linear or branched C1-C20 alkyl or linear or branched C1-C20 alkyl substituted with hydroxy, epoxy, silyl, NH2 or N(C1-C6alkyl)2; or R20 is phenyl, benzyl, —CH═CH2, —C≡CH or —C(CH3)═CH2, or R2 is a residue of an acrylic acid (CH2═CH—COO—*), methacrylic acid, (CH2═C(CH3)—COO—*) or CH(CH3)═CH—COO—* or R2 is a residue of a dicarboxylic acid HOOC—Rc—COO—* or C1-C6alkyl-OOC—Rc—COO—* wherein Rc is C1-C20 alkylene, C1-C20alkenylene or phenylene; or R2 is a residue derived from the reaction of an isocyanate Ra—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being Ra—NHCOO—* or Ra—NHCO—NH—* wherein Ra is unsubstituted C1-C20alkyl, C1-C20cycloalkyl or C1-C20alkyl substituted with hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl) or N(C1-C6alkyl)2; or R2 is a residue derived from the reaction of a diisocyanate residue OCN—Rb—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being *—OOC—NH—Rb—NCO or *—HNOC—NH—Rb—NCO or *—OOC—NH—Rb—NHCOR30 wherein Rb is C1-C20 alkylene or C1-C20cycloalkylene or phenylene and R30 is a residue of hydroxyethylacrylate (CH2═CH—COO—(CH2)2-0*), hydroxyethylmethacrylate (CH2═C(CH3)—COO—(CH2)2-0*), hydroxybutylacrylate (CH2═CH—COO—(CH2)4-0*) or hydroxybutylmethacrylate (CH2═C(CH3)—COO—(CH2)4-0*), A is the hetero atom of the vinyl hetero monomer selected from the group consisting of oxygen, nitrogen, sulfur and silicon; and if R2 is silyl and M is a direct bond, A is a direct bond; M is a bond or a divalent group linking the heteroatom of the vinyl hetero monomer and the functional end group of the vinyl hetero monomer said M being selected from the group consisting of C1-50 alkylene, C1-50 (hetero)alkylene, arylene and heteroarylene; X is a halogen atom, a nitroxide group or a sulphide group, Zn is a polymer or copolymer segment of random-, gradient- or block-type structure, which is built up from vinylic monomers selected from the group consisting of isoprene, 1,3-butadiene, α-C5-18alkene, 4-vinyl-pyridine, 2-vinyl-pyridine, vinyl-imidazole, N-vinylpyrrolidone, dimethylacrylamide, 3-dimethylamino-propylmethacrylamide, styrene, substituted styrene and a compound of formula CH2═C(R3)—C(═R4)—R5, wherein R3 is a hydrogen atom or a methyl group, R4 is oxygen atom or sulfur atom; R5 is NH2, hydroxy, unsubstituted C1-18 alkoxy, C2-100alkoxy interrupted by at least one N and/or O atom, hydroxy-substituted C1-18alkoxy, unsubstituted C1-18alkylamino, di(C1-18alkyl)amino, hydroxy-substituted C1-18alkylamino, hydroxy-substituted di(C1-18alkyl)amino or -0-CH2—CH2—N(CH3)2; Y is the chain terminus of the polymer/copolymer Zn and Y represents the fragment of a polymerization initiator capable of initiating polymerization; Y1 represents a di-, tri- or polyvalent fragment of a di-, tri-, or polyfunctional NMP initiator; m is 2, 3 or 4, preferably 2; n is the number of monomer units Z and is between 10 and 5000.

    Water based concentrated product forms of light stabilizers made by a heterophase polymerization technique
    2.
    发明授权
    Water based concentrated product forms of light stabilizers made by a heterophase polymerization technique 有权
    通过异相聚合技术制备的水稳定的光稳定剂形式

    公开(公告)号：US07687554B2

    公开(公告)日：2010-03-30

    申请号：US10570736

    申请日：2004-09-01

    申请人： Carsten Schellenberg ,  Clemens Auschra ,  Wolfgang Peter ,  Delphine Kimpel ,  Pascal Hayoz

    发明人： Carsten Schellenberg ,  Clemens Auschra ,  Wolfgang Peter ,  Delphine Kimpel ,  Pascal Hayoz

    IPC分类号： C08K5/34

    CPC分类号： C08F2/44

    摘要： The instant invention pertains to a concentrated aqueous dispersion of organic light stabilizers with a particle size of less than 1000 nm, prepared by heterophase radical polymerization of ethylenically unsaturated monomers in the presence of the light stabilizers, wherein the weight ratio of light stabilizer to polymeric carrier is greater than 50/100. Another aspect of the invention is a process for the preparation of such aqueous dispersions with high light stabilizer content. Aqueous dispersions prepared according to this process are useful ingredients for adhesives, aqueous emulsions of natural or synthetic rubbers, water based inks or a water based coating compositions, which are consequently also subjects of the invention.

    摘要翻译： 本发明涉及在光稳定剂存在下通过烯属不饱和单体的异相自由基聚合制备的粒径小于1000nm的有机光稳定剂的浓缩水分散体，其中光稳定剂与聚合物载体的重量比 大于50/100。 本发明的另一方面是制备具有高光稳定剂含量的这种水性分散体的方法。 根据该方法制备的水性分散体是粘合剂，天然或合成橡胶的水性乳液，水基油墨或水基涂料组合物的有用成分，其也是本发明的主题。

    Additive for biodiesel and biofuel oils
    5.
    发明授权
    Additive for biodiesel and biofuel oils 有权
    添加剂用于生物柴油和生物燃料油

    公开(公告)号：US06409778B1

    公开(公告)日：2002-06-25

    申请号：US09530972

    申请日：2000-06-28

    申请人： Clemens Auschra ,  Joachim Vetter ,  Uwe Boehmke ,  Michael Neusius

    发明人： Clemens Auschra ,  Joachim Vetter ,  Uwe Boehmke ,  Michael Neusius

    IPC分类号： C10L118

    CPC分类号： C10L1/1963 ,  C08F220/18 ,  C08F290/062 ,  Y02E50/13

    摘要： The invention relates to a copolymer consisting of the following monomer components: a) 48-98 wt. % of compounds of formula (I), b) 2-30 wt. % of one or several oxygen-containing methacrylates of formula (II) and c) 0-30 wt. % of a methacrylate of formula (III) of styrol, the quantities a)-c) totalling 100 wt. %. The inventive copolymer is suitable as a an additive for diesel fuels and biodiesel.

    摘要翻译： 本发明涉及由以下单体组分组成的共聚物：a）48-98wt。 ％的式（I）化合物，b）2-30wt。 ％的一种或多种式（II）的含氧甲基丙烯酸酯和c）0-30wt。 ％的苯乙烯的式（III）的甲基丙烯酸酯，其量a）-c）总计100wt。 ％。 本发明的共聚物适合作为柴油和生物柴油的添加剂。

    Demulsifiers
    6.
    发明授权
    Demulsifiers 有权
    破乳剂

    公开(公告)号：US6080794A

    公开(公告)日：2000-06-27

    申请号：US117455

    申请日：1998-09-25

    申请人： Clemens Auschra ,  Horst Pennewiss ,  Uwe Boehmke ,  Michael Neusius

    发明人： Clemens Auschra ,  Horst Pennewiss ,  Uwe Boehmke ,  Michael Neusius

    IPC分类号： B01D17/04 ,  B01D17/05 ,  C08F220/18 ,  C08F220/26 ,  C08F290/06 ,  C10G33/04 ,  C08F8/00 ,  C08F8/14

    CPC分类号： B01D17/047 ,  C10G33/04

    摘要： The invention concerns demulsifiers and methods of demulsifying based on polyalkyl (meth)acrylated co-oligomers or copolymers, CNP, built up from the following components consisting essentially of:A) 10 to less than 60 weight % of alkyl (meth)acrylic acid esters (CH.sub.2 .dbd.C(R)C(O)OR.sub.1), wherein the alkyl group is an optionally branched alkyl group having 1 to 32 carbon atoms;B) more than 40 to 90 weight % (meth)acrylic acid esters of alkoxylated radicals (CH.sub.2 .dbd.C(R)C(O)O(R.sub.A).sub.n --(R.sub.B).sub.m --R.sub.2 ), wherein R.sub.2 has 1 to 50 carbon atoms and is an optionally branched alkyl group, a cycloalkyl group, aryl group, or an alkaryl group; R.sub.A and R.sub.B represent the alkoxylation radicals a) --CH.sub.2 --CH.sub.2 --O--, b) --CH(CH3)--CH.sub.2 --O--, or c) --CH.sub.2 --CH(CH.sub.3)--O--; with the proviso n+m is a number between 3 and 200 and any individual member a), b), or c) does not exceed 100; andC) 0 to less than 40 weight % of a 1-alkene with 4 to 32 carbon atoms, with the proviso that the components A)+B)+C) add up to 100 weight %.

    摘要翻译： PCT No.PCT / EP97 / 00176 Sec。 371日期：1998年9月25日 102（e）1998年9月25日PCT 1997年1月16日PCT PCT。 公开号WO97 / 28234 日期1997年8月7日本发明涉及基于由以下组分构成的聚烷基（甲基）丙烯酸酯化共聚物或共聚物CNP的破乳剂和破乳方法，所述组分主要包含：A）10至小于60重量％的烷基（ 甲基）丙烯酸酯（CH 2 = C（R）C（O）OR 1），其中烷基是任选支化的具有1至32个碳原子的烷基; B）大于40至90重量％的烷氧基化基团（CH 2 = C（R）C（O）O（RA）n - （RB）m -R 2）的（甲基）丙烯酸酯，其中R 2具有1至50个碳 原子并且是任选支化的烷基，环烷基，芳基或烷芳基; RA和RB表示烷氧基化基团a）-CH2-CH2-O-，b）-CH（CH3）-CH2-O-或c）-CH2-CH（CH3）-O-; 条件是n + m是3和200之间的数字，任何单个成员a），b）或c）不超过100; 和C）0至小于40重量％的具有4至32个碳原子的1-烯烃，条件是组分A）+ B）+ C）加起来至100重量％。

    Biodiesel cold flow improver
    7.
    发明授权
    Biodiesel cold flow improver 有权
    生物柴油冷流改进剂

    公开(公告)号：US08900333B2

    公开(公告)日：2014-12-02

    申请号：US12316721

    申请日：2008-12-16

    申请人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

    发明人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

    IPC分类号： C10L10/14 ,  C10L1/236 ,  C10L1/198 ,  C10L1/196

    CPC分类号： C10L10/14 ,  C10L1/1963 ,  C10L1/1985 ,  C10L1/2364 ,  C10L1/2366 ,  C10L2200/0476 ,  Y02E50/13

    摘要： The present invention is directed to the use of alkyl(meth)acrylate polymers or copolymers of the formula (I) In-Poly-(E)y  (I) as cold flow improvers in biodiesel fuel (or bio-fuel) and biodiesel compositions incorporating said polymers or copolymers, obtained by nitroxyl mediated controlled free radical polymerization, wherein In is the initiator fragment starting the polymerization reaction; E is an end group bearing at least one stable free nitroxyl radical, which is bound via an oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; Poly is any polymer or copolymer formed from ethylenically unsaturated monomer(s); and y is a number 1 or greater than 1 indicating the average number of end groups E attached to Poly.

    摘要翻译： 本发明涉及在生物柴油燃料（或生物燃料）和生物柴油组合物中使用（甲基）丙烯酸烷基酯聚合物或共聚物（I）In-Poly-（E）y（I））作为冷流动改进剂 加入通过硝酰基介导的受控自由基聚合获得的所述聚合物或共聚物，其中In是开始聚合反应的引发剂片段; E是具有至少一个稳定的游离硝酰基的端基，其通过氧原子与聚合物或共聚物结合; 或由所连接的稳定游离硝酰基的取代或消除反应产生的基团; Poly是由烯属不饱和单体形成的任何聚合物或共聚物; y是数字1或大于1，表示连接到Poly的端基E的平均数。

    Encapsulated dispersions comprising electrophoretically mobile organic colorants
    8.
    发明授权
    Encapsulated dispersions comprising electrophoretically mobile organic colorants 有权
    包含电泳移动有机着色剂的包封分散体

    公开(公告)号：US08270063B2

    公开(公告)日：2012-09-18

    申请号：US12676765

    申请日：2008-08-28

    申请人： Margherita Fontana ,  Gerardus De Keyzer ,  Philippe Bugnon ,  Marcel Hahn ,  Kishor Kumar Mistry ,  Clemens Auschra

    发明人： Margherita Fontana ,  Gerardus De Keyzer ,  Philippe Bugnon ,  Marcel Hahn ,  Kishor Kumar Mistry ,  Clemens Auschra

    IPC分类号： G02B26/00 ,  G03G17/04 ,  G09G3/34 ,  G02F1/133

    CPC分类号： G02F1/167 ,  C09B67/0008 ,  C09B67/006

    摘要： The invention relates to an electrophoretic display, comprising electrodes and cells containing at least one kind of ionic, monochrome particles, a non-polar liquid and a dispersant, wherein the ionic, monochrome particles of at least one kind are essentially aggregates consisting of a carbon containing pigment and a cationic pigment orcationic pigment derivative, and the dispersantis selected from the group consisting of polyacrylates, polyesters, polyurethanes and copolymers, with the proviso that the cationic pigment or cationic pigment derivative is not a reaction product of carbonblack with diazotated procaine hydrochloride. In general, the whole quantity of the pigment and the main part, preferably at least 80%, most preferred from 95% to 100%, of the whole cationic pigment or cationic pigment derivative present within the cells is comprised in the aggregates, with essentially no pigment and only a minor part of the cationic pigment or cationic pigment derivative physically distinct from the aggregates.

    摘要翻译： 本发明涉及一种电泳显示器，包括至少含有一种离子型的，单色颗粒的电极和细胞中，非极性液体和分散剂，其中至少一种的离子，单色颗粒基本上聚集体由碳的 含颜料和阳离子颜料orcationic颜料衍生物，和选自聚丙烯酸酯，聚酯，聚氨酯和共聚物的组中选择的dispersantis，前提条件是所述阳离子颜料或阳离子颜料衍生物不与重氮化盐酸普鲁卡因碳黑的反应产物。 在一般情况下，颜料和主要部分的全量，优选至少80％，最从95％，优选至100％，整个阳离子颜料或阳离子颜料衍生物本的细胞中被包括在所述聚集体，以基本 无色素并只从聚集体物理上不同的阳离子颜料或阳离子颜料衍生物的一小部分。

    FLUORO LEVELLING AGENTS
    9.
    发明申请
    FLUORO LEVELLING AGENTS 有权
    FLUORO平衡剂

    公开(公告)号：US20110040018A1

    公开(公告)日：2011-02-17

    申请号：US12867770

    申请日：2009-02-03

    申请人： Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

    发明人： Andreas Möck ,  Ralf Knischka ,  Clemens Auschra

    IPC分类号： C09D133/16 ,  C09D133/26

    CPC分类号： C09D133/26 ,  C08L33/16 ,  C08L2312/00 ,  C08L2666/04

    摘要： The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerisation or by conventional radical polymerisation comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.

    摘要翻译： 本发明涉及包含短链氟化丙烯酸酯和使用短链氟化丙烯酸酯作为着色和未着色涂料组合物的流平剂的涂料组合物。 涂料组合物包含a）成膜粘合剂树脂，和b）通过控制聚合制备的共聚物或通过常规自由基聚合制备的共聚物，其包含选自（甲基）丙烯酸酯，苯乙烯类单体或（甲基）丙烯酸酯的组中的不饱和单体的单体（M1x） 甲基）丙烯酰胺，由此共聚物含有至少> 30重量％的（甲基）丙烯酸酯; 和选自（甲基）丙烯酸C 1 -C 4 - 氟烷基酯的单体（M2y）; x表示结构元素（M1x）中单体M1的总数：x> 5，优选10-1000，最优选10-500; y表示结构元素（M2y）中单体M2的总数：y> 1，优选2-20，最优选2-10; c）可选的其它常规涂料组分和/或添加剂。