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公开(公告)号：US08986533B2
公开(公告)日：2015-03-24
申请号：US13472039
申请日：2012-05-15
CPC分类号： C25B3/04 , C25B1/003 , C25B9/08 , Y02P20/134 , Y02P20/135
摘要： The invention relates to various embodiments of an environmentally beneficial method for reducing carbon dioxide. The methods in accordance with the invention include electrochemically or photoelectrochemically reducing the carbon dioxide in a divided electrochemical cell that includes an anode, e.g., an inert metal counterelectrode, in one cell compartment and a metal or p-type semiconductor cathode electrode in another cell compartment that also contains an aqueous solution of an electrolyte and a catalyst of one or more substituted or unsubstituted aromatic amines to produce therein a reduced organic product.
摘要翻译： 本发明涉及减少二氧化碳的环境有益的方法的各种实施方案。 根据本发明的方法包括电化学或光电化学还原分离的电化学电池中的二氧化碳，其包括在一个电池室中的阳极，例如惰性金属反电极，以及另一电池室中的金属或p型半导体阴极电极 其还含有电解质的水溶液和一种或多种取代或未取代的芳族胺的催化剂，以在其中产生还原的有机产物。
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公开(公告)号：US20120132538A1
公开(公告)日：2012-05-31
申请号：US13307965
申请日：2011-11-30
摘要： Methods and systems for electrochemical production of butanol are disclosed. A method may include, but is not limited to, steps (A) to (D). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of the electrochemical cell. The second compartment may include a solution of an electrolyte, a catalyst, and a cathode. Step (C) may apply an electrical potential between the anode and the cathode in the electrochemical cell sufficient for the cathode to reduce the carbon dioxide to a product mixture. Step (D) may separate butanol from the product mixture.
摘要翻译： 公开了用于电化学生产丁醇的方法和系统。 方法可以包括但不限于步骤（A）至（D）。 步骤（A）可以将水引入电化学电池的第一隔室。 第一隔室可以包括阳极。 步骤（B）可以将二氧化碳引入电化学电池的第二隔室。 第二隔室可以包括电解质，催化剂和阴极的溶液。 步骤（C）可以在电化学电池中的阳极和阴极之间施加足以使阴极将二氧化碳还原成产物混合物的电位。 步骤（D）可以从产物混合物中分离出丁醇。
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公开(公告)号：US5368701A
公开(公告)日：1994-11-29
申请号：US75026
申请日：1993-06-11
CPC分类号： C25B3/12 , C07F1/005 , C07F5/003 , C07F9/5442 , C07F9/908
摘要： Crystalline solids including Zintl anions have been synthesized by an electrolytic process that uses a cathode whose composition is an alloy including the elements forming the Zintl ion and an electrolyte that comprises a solvent that is basic and polar, such as ethylenediamine, and a supporting electrolyte, advantageously organic, that provides a suitable cation for the Zintl anion. Specific examples of solids that have been crystallized include tetraphenylphosphonium gold telluride, tetraphenylphosphonium gallium telluride, and tetrapropylammonium antimony telluride.
摘要翻译： 包括Zintl阴离子的结晶固体已经通过电解方法合成，该电解方法使用组成为包含形成Zintl离子的元素的合金的阴极和包含碱性和极性的溶剂如乙二胺和支持电解质的电解质， 有利的是有机物，其为Zintl阴离子提供合适的阳离子。 已经结晶的固体的具体实例包括四苯基碲碲化镉，四苯基鏻镓碲化物和锑化锑四丙铵。
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公开(公告)号：US08961774B2
公开(公告)日：2015-02-24
申请号：US13307965
申请日：2011-11-30
摘要： Methods and systems for electrochemical production of butanol are disclosed. A method may include, but is not limited to, steps (A) to (D). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of the electrochemical cell. The second compartment may include a solution of an electrolyte, a catalyst, and a cathode. Step (C) may apply an electrical potential between the anode and the cathode in the electrochemical cell sufficient for the cathode to reduce the carbon dioxide to a product mixture. Step (D) may separate butanol from the product mixture.
摘要翻译： 公开了用于电化学生产丁醇的方法和系统。 方法可以包括但不限于步骤（A）至（D）。 步骤（A）可以将水引入电化学电池的第一隔室。 第一隔室可以包括阳极。 步骤（B）可以将二氧化碳引入电化学电池的第二隔室。 第二隔室可以包括电解质，催化剂和阴极的溶液。 步骤（C）可以在电化学电池中的阳极和阴极之间施加足以使阴极将二氧化碳还原成产物混合物的电位。 步骤（D）可以从产物混合物中分离出丁醇。
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公开(公告)号：US20120247969A1
公开(公告)日：2012-10-04
申请号：US13472039
申请日：2012-05-15
IPC分类号： C25B3/04
CPC分类号： C25B3/04 , C25B1/003 , C25B9/08 , Y02P20/134 , Y02P20/135
摘要： The invention relates to various embodiments of an environmentally beneficial method for reducing carbon dioxide. The methods in accordance with the invention include electrochemically or photoelectrochemically reducing the carbon dioxide in a divided electrochemical cell that includes an anode, e.g., an inert metal counterelectrode, in one cell compartment and a metal or p-type semiconductor cathode electrode in another cell compartment that also contains an aqueous solution of an electrolyte and a catalyst of one or more substituted or unsubstituted aromatic amines to produce therein a reduced organic product.
摘要翻译： 本发明涉及减少二氧化碳的环境有益的方法的各种实施方案。 根据本发明的方法包括电化学或光电化学还原分离的电化学电池中的二氧化碳，其包括在一个电池室中的阳极，例如惰性金属反电极，以及另一电池室中的金属或p型半导体阴极电极 其还含有电解质的水溶液和一种或多种取代或未取代的芳族胺的催化剂，以在其中产生还原的有机产物。
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6.发明申请METHOD OF PREPARING HIGH DENSITY METAL OXIDE LAYERS AND THE LAYERS PRODUCED THEREBY 审中-公开制备高密度金属氧化物层的方法及其生产的层公开(公告)号：US20090148714A1
公开(公告)日：2009-06-11
申请号：US12206210
申请日：2008-09-08
申请人： Andrew B. Bocarsly , Brent Kirby , David Dowling
发明人： Andrew B. Bocarsly , Brent Kirby , David Dowling
CPC分类号： C23F13/08
摘要： A method for the production of an oxide layer, involving oxidizing a metal surface, wherein the metal surface is electrically connected to an electronic control unit (ECU); wherein the metal oxide layer produced has an amount of metal present in said metal oxide layer that is higher than that present in a metal oxide layer produced by oxidizing the metal surface in the absence of the ECU; or oxidizing an oxidizable non-metallic conductive surface, wherein the oxidizable non-metallic conductive surface is electrically connected to an electronic control unit (ECU); wherein the oxide layer produced is denser than that produced by oxidizing the oxidizable non-metallic conductive surface in the absence of the ECU; and the metal oxide or oxide layers produced thereby.
摘要翻译： 一种用于生产氧化物层的方法，包括氧化金属表面，其中金属表面电连接到电子控制单元（ECU）; 其中所生成的金属氧化物层的金属含量高于在不存在ECU的情况下通过氧化金属表面而生成的金属氧化物层中存在的金属; 或氧化可氧化的非金属导电表面，其中所述可氧化的非金属导电表面电连接到电子控制单元（ECU）; 其中所生成的氧化物层比在不存在ECU的情况下氧化可氧化的非金属导电表面产生的氧化物层更致密; 和由此制备的金属氧化物或氧化物层。
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7.发明授权Methods for the preparation of metallic alloy nanoparticles and compositions thereof 失效金属合金纳米颗粒的制备方法及其组合物公开(公告)号：US06932851B2
公开(公告)日：2005-08-23
申请号：US10287456
申请日：2002-11-04
申请人： Andrew B. Bocarsly , Shu Zhu
发明人： Andrew B. Bocarsly , Shu Zhu
CPC分类号： B82Y25/00 , B22F9/026 , B22F9/30 , B22F2998/00 , B22F2998/10 , H01F1/0063 , B22F1/0018
摘要： A method of producing metal alloy nanoparticles comprising forming a cyanosol by reacting a mixture of a chlorometallate complex and a cyanometallate complex, spin-coating the mixture onto a substrate to form a film, and sintering the film to form metal alloy nanoparticles.
摘要翻译： 一种生产金属合金纳米颗粒的方法，包括通过使氯金属配合物和氰基金属络合物的混合物反应形成氰基溶胶，将该混合物旋转到基底上以形成膜，并烧结该膜以形成金属合金纳米颗粒。
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8.发明申请ADVANCED AROMATIC AMINE HETEROCYCLIC CATALYSTS FOR CARBON DIOXIDE REDUCTION 有权用于二氧化碳还原的高级芳族胺杂环化合物催化剂公开(公告)号：US20120175269A1
公开(公告)日：2012-07-12
申请号：US13340733
申请日：2011-12-30
摘要： Methods and systems for electrochemical reduction of carbon dioxide using advanced aromatic amine heterocyclic catalysts are disclosed. A method for electrochemical reduction of carbon dioxide may include, but is not limited to, steps (A) to (C). Step (A) may introduce water to a first compartment of an electrochemical cell. Said first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of said electrochemical cell. Said second compartment may include a solution of an electrolyte, a catalyst, and a cathode. Said catalyst may include at least two aromatic amine heterocycles that are at least one of (a) fused or (b) configured to become electronically conjugated upon one electron reduction. Step (C) may apply an electrical potential between said anode and said cathode in said electrochemical cell sufficient for said cathode to reduce said carbon dioxide to a product mixture.
摘要翻译： 公开了使用先进的芳族胺杂环催化剂电化学还原二氧化碳的方法和系统。 二氧化碳的电化学还原的方法可以包括但不限于步骤（A）至（C）。 步骤（A）可以将水引入电化学电池的第一隔室。 所述第一隔室可包括阳极。 步骤（B）可以将二氧化碳引入所述电化学电池的第二隔室。 所述第二隔室可以包括电解质，催化剂和阴极的溶液。 所述催化剂可以包括至少两个芳族胺杂环，其至少一个（a）稠合或（b）配置成在一次电子还原时电子共轭。 步骤（C）可以在所述电化学电池中的所述阳极和所述阴极之间施加足以使所述阴极将所述二氧化碳还原成产物混合物的电势。
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公开(公告)号：US20100187123A1
公开(公告)日：2010-07-29
申请号：US12696840
申请日：2010-01-29
CPC分类号： C25B3/04 , C25B1/003 , C25B9/08 , Y02P20/134 , Y02P20/135
摘要： The invention relates to various embodiments of an environmentally beneficial method for reducing carbon dioxide. The methods in accordance with the invention include electrochemically or photoelectrochemically reducing the carbon dioxide in a divided electrochemical cell that includes an anode, e.g., an inert metal counterelectrode, in one cell compartment and a metal or p-type semiconductor cathode electrode in another cell compartment that also contains an aqueous solution of an electrolyte and a catalyst of one or more substituted or unsubstituted aromatic amines to produce therein a reduced organic product.
摘要翻译： 本发明涉及减少二氧化碳的环境有益的方法的各种实施方案。 根据本发明的方法包括电化学或光电化学还原分离的电化学电池中的二氧化碳，其包括在一个电池室中的阳极，例如惰性金属反电极，以及另一电池室中的金属或p型半导体阴极电极 其还含有电解质的水溶液和一种或多种取代或未取代的芳族胺的催化剂，以在其中产生还原的有机产物。
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10.发明授权公开(公告)号：US08592633B2
公开(公告)日：2013-11-26
申请号：US13542152
申请日：2012-07-05
摘要： Methods and systems for electrochemical conversion of carbon dioxide to carboxylic acids, glycols, and carboxylates are disclosed. A method may include, but is not limited to, steps (A) to (D). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of the electrochemical cell. The second compartment may include a solution of an electrolyte and a cathode. Step (C) may apply an electrical potential between the anode and the cathode in the electrochemical cell sufficient to reduce the carbon dioxide to a carboxylic acid intermediate. Step (D) may contact the carboxylic acid intermediate with hydrogen to produce a reaction product.
摘要翻译： 公开了将二氧化碳电化学转化成羧酸，二醇和羧酸盐的方法和系统。 方法可以包括但不限于步骤（A）至（D）。 步骤（A）可以将水引入电化学电池的第一隔室。 第一隔室可以包括阳极。 步骤（B）可以将二氧化碳引入电化学电池的第二隔室。 第二隔室可以包括电解质和阴极的溶液。 步骤（C）可以在电化学电池中的阳极和阴极之间施加足以将二氧化碳还原成羧酸中间体的电位。 步骤（D）可以将羧酸中间体与氢接触以产生反应产物。
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