Process for forming Zintl phases and the products thereof
    1.
    发明授权
    Process for forming Zintl phases and the products thereof 失效
    用于形成Zintl相的方法及其制品

    公开(公告)号:US5368701A

    公开(公告)日:1994-11-29

    申请号:US75026

    申请日:1993-06-11

    摘要: Crystalline solids including Zintl anions have been synthesized by an electrolytic process that uses a cathode whose composition is an alloy including the elements forming the Zintl ion and an electrolyte that comprises a solvent that is basic and polar, such as ethylenediamine, and a supporting electrolyte, advantageously organic, that provides a suitable cation for the Zintl anion. Specific examples of solids that have been crystallized include tetraphenylphosphonium gold telluride, tetraphenylphosphonium gallium telluride, and tetrapropylammonium antimony telluride.

    摘要翻译: 包括Zintl阴离子的结晶固体已经通过电解方法合成,该电解方法使用组成为包含形成Zintl离子的元素的合金的阴极和包含碱性和极性的溶剂如乙二胺和支持电解质的电解质, 有利的是有机物,其为Zintl阴离子提供合适的阳离子。 已经结晶的固体的具体实例包括四苯基碲碲化镉,四苯基鏻镓碲化物和锑化锑四丙铵。