PI-ELECTRON CONJUGATED BLOCK COPOLYMER AND PHOTOELECTRIC CONVERSION ELEMENT
    4.
    发明申请
    PI-ELECTRON CONJUGATED BLOCK COPOLYMER AND PHOTOELECTRIC CONVERSION ELEMENT 审中-公开
    PI-ELECTRON共混嵌段共聚物和光电转换元件

    公开(公告)号:US20140084220A1

    公开(公告)日:2014-03-27

    申请号:US14004563

    申请日:2012-03-09

    IPC分类号: H01L51/00

    摘要: Provided is a conjugated block copolymer that is capable of morphology control and that can achieve superior conversion efficiency. A π-electron conjugated block copolymer contiguously or non-contiguously bonding polymer block (A) involving a monomer unit having in a portion of a chemical structure at least one heteroaryl skeleton selected from a thiophene, a fluorine, a carbazole, a dibenzosilole and a dibenzogermole; and a polymer block (B) involving a monomer unit similarly having at least one heteroaryl skeleton; wherein the polymer block (A) comprises a homopolymer block of a monomer unit having a substituent RnA that is an alkoxy group or an alkyl group having 1-18 carbon atoms, and the polymer block (B) comprises a copolymer block of at least two different each other types of monomer units having substituent RnB selected from an alkoxy group or an alkyl group having 1-18 carbon atoms, which may be substituted with an alkoxy group, a halogen atom, a hydroxyl group, an amino group, a thiole group, a silyl group, an ester group, an aryl group, hetero aryl group.

    摘要翻译: 提供能够形态控制并且可以实现优异的转化效率的共轭嵌段共聚物。 涉及具有化学结构部分中的至少一个选自噻吩,氟,咔唑,二苯并噻唑的杂芳基骨架的单体单元的邻苯二胺共轭嵌段共聚物连续或非连续键合聚合物嵌段(A) 二苯并呋喃; 和包含类似地具有至少一个杂芳基骨架的单体单元的聚合物嵌段(B); 其中所述聚合物嵌段(A)包含具有取代基RnA(其为烷氧基或具有1-18个碳原子的烷基)的单体单元的均聚物嵌段,并且所述聚合物嵌段(B)包含至少两个 具有可以被烷氧基,卤素原子,羟基,氨基,硫代基团取代的具有1-18个碳原子的烷氧基或烷基的取代基RnB的不同类型的单体单元 甲硅烷基,酯基,芳基,杂芳基。

    HYDROGENATED BETA-PINENE-BASED POLYMERS AND MOLDED ARTICLES COMPRISING THE SAME
    5.
    发明申请
    HYDROGENATED BETA-PINENE-BASED POLYMERS AND MOLDED ARTICLES COMPRISING THE SAME 有权
    加氢的基于蒎烯的聚合物和包含其的成型制品

    公开(公告)号:US20110124830A1

    公开(公告)日:2011-05-26

    申请号:US12936764

    申请日:2009-04-09

    IPC分类号: C08F4/80 C08F32/08 C08F2/00

    摘要: The present invention provides hydrogenated β-pinene-based polymers with excellent heat resistance and light resistance, low absorptivity and high transparency, as well as molded articles thereof. The polymers of the present invention contain 50% by mass or more of β-pinene units and are hydrogenated β-pinene-based polymers where the ratio of the proton integral value at 6 to 8 ppm to the total proton integral value in a 1H-NMR spectrum is 2.3×10−5 or less or the p-phenylene group content is 0.0055% by mass or less, and the ratio of the proton integral value at 4.5 to 6 ppm to the total proton integral value is 2.8×10−4 or less or the cyclohexene-1,4-diyl group content is 0.29% by mass or less. The molded articles of the present invention contain the above hydrogenated β-pinene-based polymers.

    摘要翻译: 本发明提供具有优异的耐热性和耐光性,低吸收性和高透明度的氢化和蒎烯系聚合物及其成型体。 本发明的聚合物含有50质量%以上的蒎烯单元,并且是氢化和蒎烯基聚合物,其中质子积分值在6至8ppm与总质子积分值的比率 1 H-NMR谱为2.3×10-5以下或对亚苯基含量为0.0055质量%以下,4.5质量%至6ppm质子积分值与总质子积分值的比为2.8×10 -4以下或环己烯-1,4-二基含量为0.29质量%以下。 本发明的模塑制品含有上述氢化蒎烯系聚合物。

    Hydrogenated β-pinene-based polymers and molded articles comprising the same
    8.
    发明授权
    Hydrogenated β-pinene-based polymers and molded articles comprising the same 有权
    氢化的β-蒎烯基聚合物和包含其的模制品

    公开(公告)号:US08497327B2

    公开(公告)日:2013-07-30

    申请号:US12936764

    申请日:2009-04-09

    IPC分类号: C08C19/02 C08F8/02 C08F8/42

    摘要: The present invention provides hydrogenated β-pinene-based polymers with excellent heat resistance and light resistance, low absorptivity and high transparency, as well as molded articles thereof. The polymers of the present invention contain 50% by mass or more of β-pinene units and are hydrogenated β-pinene-based polymers where the ratio of the proton integral value at 6 to 8 ppm to the total proton integral value in a 1H-NMR spectrum is 2.3×10−5 or less or the p-phenylene group content is 0.0055% by mass or less, and the ratio of the proton integral value at 4.5 to 6 ppm to the total proton integral value is 2.8×10−4 or less or the cyclohexene-1,4-diyl group content is 0.29% by mass or less. The molded articles of the present invention contain the above hydrogenated β-pinene-based polymers.

    摘要翻译: 本发明提供具有优异的耐热性和耐光性,低吸收性和高透明度的氢化β-蒎烯系聚合物及其成型品。 本发明的聚合物含有50质量%以上的β-蒎烯单元,是氢化β-蒎烯系聚合物,其中6〜8ppm的质子积分值与1H- NMR谱为2.3×10-5以下,对亚苯基含量为0.0055质量%以下,4.5质量%〜6ppm质子积分值与总质子积分值的比为2.8×10 -4 或环己烯-1,4-二基的含量为0.29质量%以下。 本发明的成型体含有上述氢化β-蒎烯系聚合物。