公开(公告)号：US08497327B2

公开(公告)日：2013-07-30

申请号：US12936764

申请日：2009-04-09

申请人： Atsuhiro Nakahara ,  Jin Tokuyasu ,  Takashi Hori ,  Hiroyuki Ohgi

发明人： Atsuhiro Nakahara ,  Jin Tokuyasu ,  Takashi Hori ,  Hiroyuki Ohgi

IPC分类号： C08C19/02 ,  C08F8/02 ,  C08F8/42

CPC分类号： C08F8/04 ,  C08F210/14 ,  C08F2800/20 ,  C08F10/14 ,  C08F210/10

摘要： The present invention provides hydrogenated β-pinene-based polymers with excellent heat resistance and light resistance, low absorptivity and high transparency, as well as molded articles thereof. The polymers of the present invention contain 50% by mass or more of β-pinene units and are hydrogenated β-pinene-based polymers where the ratio of the proton integral value at 6 to 8 ppm to the total proton integral value in a 1H-NMR spectrum is 2.3×10−5 or less or the p-phenylene group content is 0.0055% by mass or less, and the ratio of the proton integral value at 4.5 to 6 ppm to the total proton integral value is 2.8×10−4 or less or the cyclohexene-1,4-diyl group content is 0.29% by mass or less. The molded articles of the present invention contain the above hydrogenated β-pinene-based polymers.

摘要翻译： 本发明提供具有优异的耐热性和耐光性，低吸收性和高透明度的氢化β-蒎烯系聚合物及其成型品。 本发明的聚合物含有50质量％以上的β-蒎烯单元，是氢化β-蒎烯系聚合物，其中6〜8ppm的质子积分值与1H- NMR谱为2.3×10-5以下，对亚苯基含量为0.0055质量％以下，4.5质量％〜6ppm质子积分值与总质子积分值的比为2.8×10 -4 或环己烯-1,4-二基的含量为0.29质量％以下。 本发明的成型体含有上述氢化β-蒎烯系聚合物。

公开(公告)号：US20110124830A1

公开(公告)日：2011-05-26

申请号：US12936764

申请日：2009-04-09

申请人： Atsuhiro Nakahara ,  Jin Tokuyasu ,  Takashi Hori ,  Hiroyuki Ohgi

发明人： Atsuhiro Nakahara ,  Jin Tokuyasu ,  Takashi Hori ,  Hiroyuki Ohgi

IPC分类号： C08F4/80 ,  C08F32/08 ,  C08F2/00

CPC分类号： C08F8/04 ,  C08F210/14 ,  C08F2800/20 ,  C08F10/14 ,  C08F210/10

摘要： The present invention provides hydrogenated β-pinene-based polymers with excellent heat resistance and light resistance, low absorptivity and high transparency, as well as molded articles thereof. The polymers of the present invention contain 50% by mass or more of β-pinene units and are hydrogenated β-pinene-based polymers where the ratio of the proton integral value at 6 to 8 ppm to the total proton integral value in a 1H-NMR spectrum is 2.3×10−5 or less or the p-phenylene group content is 0.0055% by mass or less, and the ratio of the proton integral value at 4.5 to 6 ppm to the total proton integral value is 2.8×10−4 or less or the cyclohexene-1,4-diyl group content is 0.29% by mass or less. The molded articles of the present invention contain the above hydrogenated β-pinene-based polymers.

摘要翻译： 本发明提供具有优异的耐热性和耐光性，低吸收性和高透明度的氢化和蒎烯系聚合物及其成型体。 本发明的聚合物含有50质量％以上的蒎烯单元，并且是氢化和蒎烯基聚合物，其中质子积分值在6至8ppm与总质子积分值的比率 1 H-NMR谱为2.3×10-5以下或对亚苯基含量为0.0055质量％以下，4.5质量％至6ppm质子积分值与总质子积分值的比为2.8×10 -4以下或环己烯-1,4-二基含量为0.29质量％以下。 本发明的模塑制品含有上述氢化蒎烯系聚合物。

公开(公告)号：US20110237796A1

公开(公告)日：2011-09-29

申请号：US13059766

申请日：2009-08-19

申请人： Yasutaka Inubushi ,  Takashi Hori ,  Hiroyuki Ohgi

发明人： Yasutaka Inubushi ,  Takashi Hori ,  Hiroyuki Ohgi

IPC分类号： C07F1/08

CPC分类号： C07F1/005 ,  B01D53/02 ,  B01D2253/204 ,  B01D2257/102 ,  B01D2257/104 ,  B01D2257/108 ,  B01D2257/11 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/556 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2258/06 ,  B01J20/223 ,  C07C65/105 ,  C07C65/11 ,  Y02C10/08 ,  Y02P20/152

摘要： Disclosed is a metal complex that can be used as a gas absorption material with superior gas absorbing properties, a gas storage material with a high storage capacity, and a gas separation material with superior gas separation performance and high adsorption capacity. Disclosed is a metal complex, and a manufacturing method therefor, which consists of: a polycyclic aromatic dihydroxy monocarboxylic acid compound, in the structural formula of which hydroxyl groups are at the farthest locations from each other, which has carboxyl groups at the locations adjacent to the hydroxyl groups, and which has 10 or more circularly conjugated it electrons, such as 3,7-dihydorxy-2-naphtoic acid or 4,4′-dihydroxy-3-biphenylcaroxylic acid; at least one metal selected from chromium, molybdenum, tungsten, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, copper, zinc, and cadmium; and an organic ligand, such as 4,4′-bipyridyl, capable of bidentate bonding with said metal.

摘要翻译： 公开了可以用作气体吸收性优异的气体吸收材料的金属络合物，具有高储存能力的储气材料和具有优异的气体分离性能和高吸附能力的气体分离材料。 公开了一种金属络合物及其制造方法，其由以下结构构成：多环芳族二羟基单羧酸化合物，其结构式为羟基在彼此最远的位置，在邻近的位置具有羧基 羟基，并且具有10个或更多个环状共轭电子，例如3,7-二羟基-2-萘甲酸或4,4'-二羟基-3-联苯羧酸; 选自铬，钼，钨，锰，铁，钌，钴，铑，镍，钯，铜，锌和镉中的至少一种金属; 以及能够与所述金属二齿键合的有机配体，例如4,4'-联吡啶。

公开(公告)号：US08592626B2

公开(公告)日：2013-11-26

申请号：US13059766

申请日：2009-08-19

申请人： Yasutaka Inubushi ,  Takashi Hori ,  Hiroyuki Ohgi

发明人： Yasutaka Inubushi ,  Takashi Hori ,  Hiroyuki Ohgi

IPC分类号： C07C63/34 ,  C07C63/36 ,  B01J20/26

CPC分类号： C07F1/005 ,  B01D53/02 ,  B01D2253/204 ,  B01D2257/102 ,  B01D2257/104 ,  B01D2257/108 ,  B01D2257/11 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/556 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2258/06 ,  B01J20/223 ,  C07C65/105 ,  C07C65/11 ,  Y02C10/08 ,  Y02P20/152

摘要： Disclosed is a metal complex that can be used as a gas absorption material with superior gas absorbing properties, a gas storage material with a high storage capacity, and a gas separation material with superior gas separation performance and high adsorption capacity. Disclosed is a metal complex, and a manufacturing method therefor, which consists of: a polycyclic aromatic dihydroxy monocarboxylic acid compound, in the structural formula of which hydroxyl groups are at the farthest locations from each other, which has carboxyl groups at the locations adjacent to the hydroxyl groups, and which has 10 or more circularly conjugated π electrons, such as 3,7-dihydorxy-2-naphtoic acid or 4,4′-dihydroxy-3-biphenylcaroxylic acid; at least one metal selected from chromium, molybdenum, tungsten, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, copper, zinc, and cadmium; and an organic ligand, such as 4,4′-bipyridyl, capable of bidentate bonding with said metal.

摘要翻译： 公开了可以用作气体吸收性优异的气体吸收材料的金属络合物，具有高储存能力的储气材料和具有优异的气体分离性能和高吸附能力的气体分离材料。 公开了一种金属络合物及其制造方法，其由以下结构构成：多环芳族二羟基单羧酸化合物，其结构式为羟基在彼此最远的位置，在邻近的位置具有羧基 羟基，并且具有10个或更多个环状共轭π电子，例如3,7-二羟基-2-萘甲酸或4,4'-二羟基-3-联苯基羟基酸; 选自铬，钼，钨，锰，铁，钌，钴，铑，镍，钯，铜，锌和镉中的至少一种金属; 以及能够与所述金属二齿键合的有机配体，例如4,4'-联吡啶。

公开(公告)号：US08138246B2

公开(公告)日：2012-03-20

申请号：US12444461

申请日：2007-10-02

申请人： Toshinori Kato ,  Hiroyuki Ohgi ,  Masayoshi Watanabe

发明人： Toshinori Kato ,  Hiroyuki Ohgi ,  Masayoshi Watanabe

IPC分类号： C08K5/34

CPC分类号： H01G9/028 ,  C08F293/005 ,  C08F297/00 ,  C08F297/02 ,  C08F297/026 ,  C08L53/00 ,  C08L53/005 ,  C08L53/02 ,  C08L53/025 ,  H01B1/122 ,  H01G5/16 ,  H01G9/038 ,  H01G9/155 ,  H01G11/48 ,  H01G11/56 ,  H01M6/181 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/13 ,  C08L2666/02

摘要： A polymer electrolyte which comprises an ionic liquid (A) and a block copolymer (B) as essential ingredients, which block copolymer (B) comprises one or more of polymer block(s) (P) being compatible with (A) and one or more of polymer block(s) (Q) being incompatible with (A). (A) and (P) mutually dissolve each other to form one phase (X), and (Q) forms a phase (Y) being incompatible with phase (X), and phase (X) and phase (Y) are mutually micro phase separated. The polymer electrolyte of the present invention shows practical ion conductivity, is excellent in retention of ionic liquid, and moreover, is also excellent in heat resistance and mechanical strength. Furthermore, the electrochemical device and actuator element of the invention are swiftly displaced in accordance with application of a voltage, and can be actuated stably for a long period due to the liquid-retaining property and mechanical strength of the polymer electrolyte used, and, therefore, can suitably be used in the fields of medical instruments, micro-machines, industrial robot, personal robot, etc.

摘要翻译： 一种聚合物电解质，其包含离子液体（A）和嵌段共聚物（B）作为必要成分，其中嵌段共聚物（B）包含一种或多种与（A）相容的聚合物嵌段（P），和 更多的聚合物嵌段（Q）与（A）不相容。 （A）和（P）相互溶解形成一相（X），（Q）形成与相（X）不相容的相（Y），相（X）和相（Y） 相分离。 本发明的高分子电解质显示出实用的离子传导性，离子液体的保留性优异，耐热性和机械强度也优异。 此外，本发明的电化学装置和致动器元件根据电压的施加而迅速地移位，并且由于所使用的聚合物电解质的液体保持性和机械强度而可长期稳定地致动，因此 可适用于医疗器械，微机械，工业机器人，个人机器人等领域。

公开(公告)号：US06753370B2

公开(公告)日：2004-06-22

申请号：US10091482

申请日：2002-03-07

申请人： Shigeki Nakatsukasa ,  Hiroyuki Ohgi ,  Kazuyori Yoshimi

发明人： Shigeki Nakatsukasa ,  Hiroyuki Ohgi ,  Kazuyori Yoshimi

IPC分类号： B32B2808

CPC分类号： C08L23/0815 ,  C08L23/08 ,  Y10S526/943 ,  Y10T428/1341 ,  Y10T428/1379 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T428/31928 ,  Y10T428/31938 ,  C08L2666/04

摘要： A resin composition comprises a copolymer (A) comprising ethylene as a major component produced with a single-site catalyst, and an ethylene-vinyl alcohol copolymer (B) having an ethylene content of 20-60 mol. % and a degree of hydrolysis of 95% or above, the resin composition satisfying the equation (1): 1/99≦{weight of (A)}/{weight of (B)}≦

摘要翻译： 树脂组合物包含含有乙烯作为主要成分的单一部位催化剂的共聚物（A）和乙烯含量为20-60摩尔的乙烯 - 乙烯醇共聚物（B）。 ％和水解度为95％以上，树脂组合物满足式（1）：优选的树脂组合物包含密度为0.90-0.94g / cm 3的共聚物（A）和树脂组合物 进一步包含羧酸改性聚烯烃（C）并且满足式（2）和（3）：其中X = {（C）} / {（A）和（B）}的总重量的另一优选树脂 组合物包含密度为0.85-0.90g / cm 3的共聚物（A），其满足式（5）：树脂组合物具有优异的熔融成型性，阻气性，抗弯曲疲劳性和耐冲击性 。 它可以用于制备多层结构以赋予结构良好的外观，耐分层性，透明性，耐冲击性和阻气性。

公开(公告)号：US06291990B1

公开(公告)日：2001-09-18

申请号：US09196248

申请日：1998-11-20

申请人： Mitsutoshi Nakane ,  Hiroyuki Ohgi ,  Ryoichi Kobayashi

发明人： Mitsutoshi Nakane ,  Hiroyuki Ohgi ,  Ryoichi Kobayashi

IPC分类号： G01B714

CPC分类号： G01P3/488 ,  G01P1/00 ,  G01P1/026

摘要： Electrical connective terminals for an input use and an output use of magneto-electric conversion element and a magnet are insert molded to a synthetic resin holder. At least one part of one end face of magnet is covered by one end of the synthetic resin holder 5. At an outer face of the covering part a circuit board 6 on which the magneto-electric converter element is mounted is installed. The covering part is arranged between the magnet and thr magneto-electric converter element. Thereby a predetermined gap is assured between the magnet and the magneto-electric converter element. When a distance formed between the magnet and the rotor of magnetic material is expressed as L, a distance formed between the magnet and a magnetic sensing part of the magneto-electric converter element is expressed as L1, then L1 equals to ¼L−¾L (L1=¼L−¾L) and the distance L1 is set with a range of 1.5 mm−4.5 mm.

摘要翻译： 用于输入使用的电连接端子和磁电转换元件和磁体的输出使用被插入模制到合成树脂保持器。 磁体的一个端面的至少一部分被合成树脂保持器5的一端覆盖。在覆盖部分的外表面上安装有安装有磁电转换元件的电路板6。 覆盖部分布置在磁体和磁电转换器元件之间。 从而在磁体和磁电转换器元件之间确保预定的间隙。 当磁体和磁性材料的转子之间形成的距离表示为L时，磁体与磁电转换元件的磁感应部分之间形成的距离表示为L1，则L1等于¼L-¾L（L1 =¼L-¾L），距离L1设定为1.5mm-4.5mm的范围。

公开(公告)号：US08420276B2

公开(公告)日：2013-04-16

申请号：US12526276

申请日：2008-01-23

申请人： Shinji Nakai ,  Keiji Kubo ,  Hiroyuki Ohgi ,  Tomohiro Ono

发明人： Shinji Nakai ,  Keiji Kubo ,  Hiroyuki Ohgi ,  Tomohiro Ono

IPC分类号： H01M4/60

CPC分类号： H01M4/8605 ,  H01M4/8668 ,  H01M8/1004

摘要： In a membrane-electrode assembly for polymer electrolyte fuel cells comprising a polymer electrolyte membrane and two gas diffusion electrodes being bonded to the membrane so that the membrane can be between them, at least one catalyst layer constituting the gas diffusion electrodes characterized in that the ion-conductive binder comprises a block copolymer having a particle size of 1 μm or less comprising a polymer block (A) having ion-conductive groups and a polymer block (B) having no ion-conductive group, both polymer blocks phase separate from each other, polymer block (A) forms a continuous phase, and the contact parts of the block copolymer with catalyst particles are comprised of polymer block (A) having ion-conductive groups; a membrane-electrode assembly and a polymer electrolyte fuel cell.

摘要翻译： 在聚合物电解质燃料电池的膜 - 电极组件中，包括聚合物电解质膜和两个气体扩散电极接合到膜上，使得膜可以在它们之间，构成气体扩散电极的至少一个催化剂层的特征在于，离子 导电性粘合剂包含粒径为1μm以下的嵌段共聚物，其含有具有离子传导性基团的聚合物嵌段（A）和不具有离子传导性基团的聚合物嵌段（B），两相聚合物嵌段相分离 聚合物嵌段（A）形成连续相，嵌段共聚物与催化剂颗粒的接触部分由具有离子传导性基团的聚合物嵌段（A）构成; 膜 - 电极组件和聚合物电解质燃料电池。

公开(公告)号：US20100035158A1

公开(公告)日：2010-02-11

申请号：US12444461

申请日：2007-10-02

申请人： Toshinori Kato ,  Hiroyuki Ohgi ,  Masayoshi Watanabe

发明人： Toshinori Kato ,  Hiroyuki Ohgi ,  Masayoshi Watanabe

IPC分类号： H01M6/18 ,  H01G9/022 ,  H01G9/00

CPC分类号： H01G9/028 ,  C08F293/005 ,  C08F297/00 ,  C08F297/02 ,  C08F297/026 ,  C08L53/00 ,  C08L53/005 ,  C08L53/02 ,  C08L53/025 ,  H01B1/122 ,  H01G5/16 ,  H01G9/038 ,  H01G9/155 ,  H01G11/48 ,  H01G11/56 ,  H01M6/181 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/13 ,  C08L2666/02

摘要： A polymer electrolyte which comprises an ionic liquid (A) and a block copolymer (B) as essential ingredients, which block copolymer (B) comprises one or more of polymer block(s) (P) being compatible with (A) and one or more of polymer block(s) (Q) being incompatible with (A). (A) and (P) mutually dissolve each other to form one phase (X), and (Q) forms a phase (Y) being incompatible with phase (X), and phase (X) and phase (Y) are mutually micro phase separated. The polymer electrolyte of the present invention shows practical ion conductivity, is excellent in retention of ionic liquid, and moreover, is also excellent in heat resistance and mechanical strength. Furthermore, the electrochemical device and actuator element of the invention are swiftly displaced in accordance with application of a voltage, and can be actuated stably for a long period due to the liquid-retaining property and mechanical strength of the polymer electrolyte used, and, therefore, can suitably be used in the fields of medical instruments, micro-machines, industrial robot, personal robot, etc.

摘要翻译： 一种包含离子液体（A）和嵌段共聚物（B）作为必要成分的聚合物电解质，该嵌段共聚物（B）包含一种或多种与（A）相容的聚合物嵌段（P），和 更多的聚合物嵌段（Q）与（A）不相容。 （A）和（P）相互溶解形成一相（X），（Q）形成与相（X）不相容的相（Y），相（X）和相（Y） 相分离。 本发明的高分子电解质显示出实用的离子传导性，离子液体的保留性优异，耐热性和机械强度也优异。 此外，本发明的电化学装置和致动器元件根据电压的施加而迅速地移位，并且由于所使用的聚合物电解质的液体保持性和机械强度而可长期稳定地致动，因此 可适用于医疗器械，微机械，工业机器人，个人机器人等领域。

公开(公告)号：US08263286B2

公开(公告)日：2012-09-11

申请号：US12812901

申请日：2009-01-28

申请人： Shinji Nakai ,  Keiji Kubo ,  Tomohiro Ono ,  Hiroyuki Ohgi

发明人： Shinji Nakai ,  Keiji Kubo ,  Tomohiro Ono ,  Hiroyuki Ohgi

IPC分类号： H01M8/10

CPC分类号： H01M8/1004 ,  H01M8/1023 ,  H01M8/1053 ,  H01M2008/1095 ,  H01M2300/0082

摘要： A membrane-electrode assembly for polymer electrolyte fuel cells comprising a polymer electrolyte membrane and two gas diffusion electrodes being bonded to the membrane so that the membrane can be between them, in which assembly each gas diffusion electrode is comprised of an electrode catalyst layer and a gas diffusion layer, intermediate layer(s) being an ion conductor is/are arranged between the electrode catalyst layer(s) and the membrane, the ion conductor mainly comprises a block copolymer comprising a polymer block (A) having ion-conductive groups and a polymer block (B) having no ion-conductive group, both blocks phase-separate from each other, (A) forms a continuous phase, and the contact part(s) of the intermediate layer(s) with the polymer electrolyte membrane and the contact part(s) of the intermediate layer(s) with the electrode catalyst layer(s) are comprised of polymer block (A) having ion-conductive groups; and a polymer electrolyte fuel cell wherein the assembly is used. By the invention, a membrane-electrode assembly and a fuel cell are provided which are economical, environment-friendly, good in moldability, and small in interface resistance and excellent in power generation efficiency.

摘要翻译： 一种用于聚合物电解质燃料电池的膜 - 电极组件，包括聚合物电解质膜和两个气体扩散电极，所述两个气体扩散电极结合到膜上，使得膜可以在它们之间，其中每个气体扩散电极由电极催化剂层和 气体扩散层，作为离子导体的中间层设置在电极催化剂层和膜之间，离子导体主要包含含有具有离子传导性基团的聚合物嵌段（A）和 不具有离子传导性基团的聚合物嵌段（B）彼此相分离，（A）形成连续相，中间层与高分子电解质膜的接触部分和 中间层与电极催化剂层的接触部分由具有离子传导性基团的聚合物嵌段（A）组成; 以及其中使用所述组件的聚合物电解质燃料电池。 通过本发明，提供了经济，环保，成型性好，界面电阻小，发电效率优异的膜 - 电极组件和燃料电池。