公开(公告)号：US20120286257A1

公开(公告)日：2012-11-15

申请号：US13557884

申请日：2012-07-25

申请人： Satoko SHITAGAKI ,  Atsushi TOKUDA ,  Hiroko ABE ,  Ryoji NOMURA ,  Satoshi SEO

发明人： Satoko SHITAGAKI ,  Atsushi TOKUDA ,  Hiroko ABE ,  Ryoji NOMURA ,  Satoshi SEO

IPC分类号： H01L51/54

CPC分类号： C07D403/14 ,  C07D241/42 ,  C07D401/10 ,  C07D401/14 ,  C09K11/06 ,  C09K2211/1044 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

摘要： Target is to provide an organic compound material having a bipolar character.A quinoxaline derivative represented by a general formula (1) is provided. In the formula, R1-R12 each independently represents a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group, or a heterocyclic residue group. R9 and R10, R10 and R11, and R11 and R12 are each independent or respectively mutually bonded to form an aromatic ring. Ar1-Ar4 each independently represents an aryl group or a heterocyclic residue group. Ar1, Ar2, Ar3 and Ar4 are each independent or Ar1 and Ar2, and Ar3 and Ar4 are respectively mutually bonded directly, or Ar1 and Ar3, and Ar3 and Ar4 are bonded via oxygen (O), sulfur (S) or a carbonyl group.

摘要翻译： 目标是提供具有双极性的有机化合物。 提供由通式（1）表示的喹喔啉衍生物。 式中，R 1 -R 12各自独立地表示氢原子，卤素原子，低级烷基，烷氧基，酰基，硝基，氰基，氨基，二烷基氨基，二芳基氨基 ，乙烯基，芳基或杂环残基。 R9和R10，R10和R11，以及R11和R12各自独立地或分别相互结合形成芳香环。 Ar1-Ar4各自独立地表示芳基或杂环残基。 Ar1，Ar2，Ar3和Ar4各自独立，Ar1和Ar2，Ar3和Ar4分别直接相互键合，或Ar1和Ar3，Ar3和Ar4通过氧（O），硫（S）或羰基 。

公开(公告)号：US20100237342A1

公开(公告)日：2010-09-23

申请号：US12793735

申请日：2010-06-04

申请人： Hiroko YAMAZAKI ,  Atsushi TOKUDA ,  Tetsuo TSUTSUI

发明人： Hiroko YAMAZAKI ,  Atsushi TOKUDA ,  Tetsuo TSUTSUI

IPC分类号： H01L51/54

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子的组合 运输材料和掺杂剂材料被优化。

公开(公告)号：US07485375B2

公开(公告)日：2009-02-03

申请号：US10735732

申请日：2003-12-16

申请人： Atsushi Tokuda ,  Takako Takasu ,  Satoshi Seo ,  Ryoji Nomura

发明人： Atsushi Tokuda ,  Takako Takasu ,  Satoshi Seo ,  Ryoji Nomura

IPC分类号： H01L51/50

CPC分类号： H01L51/002 ,  H01L51/0036 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0077 ,  H01L51/5088 ,  H01L51/5096 ,  Y10S428/917

摘要： An EL element is provided in which a conjugate polymer that has a polythiophene derivative, a polyaniline derivative, a polypyrrole derivative or a polyfuran derivative as a fundamental skeleton and is soluble in an organic solvent is oxidized in its main chain with a dopant of an electron-accepting organic molecule that does not contain an acid component, and the doped conjugate polymer is used as a material to form a hole injecting layer. The polymer, being soluble in an organic solvent, can be formed in film even on a substrate high in the water repellency; that is, it can be easily formed in film on a TFT substrate and the like indispensable for an active matrix display device. Furthermore, since a dopant that does not contain an acid component is used, influence on an organic thin film and an electrode that are in contact with the hole injecting layer can be suppressed to the minimum level.

摘要翻译： 提供了一种EL元件，其中具有聚噻吩衍生物，聚苯胺衍生物，聚吡咯衍生物或聚呋喃衍生物作为基本骨架并且可溶于有机溶剂的共轭聚合物在其主链中被电子的掺杂剂氧化 不含有酸成分的接受有机分子，掺杂的共轭聚合物用作形成空穴注入层的材料。 可溶于有机溶剂的聚合物即使在防水性高的基材上也可以形成膜; 也就是说，可以容易地在有源矩阵显示装置不可或缺的TFT基板等上形成薄膜。 此外，由于使用不含有酸成分的掺杂剂，因此可以将对与空穴注入层接触的有机薄膜和电极的影响抑制到最小程度。

公开(公告)号：US07473575B2

公开(公告)日：2009-01-06

申请号：US10737569

申请日：2003-12-16

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L51/40

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子的组合 运输材料和掺杂剂材料被优化。

公开(公告)号：US07413816B2

公开(公告)日：2008-08-19

申请号：US10736679

申请日：2003-12-17

申请人： Hideko Inoue ,  Satoshi Seo ,  Atsushi Tokuda ,  Ryoji Nomura

发明人： Hideko Inoue ,  Satoshi Seo ,  Atsushi Tokuda ,  Ryoji Nomura

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： C07C251/24 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/185 ,  Y10S428/917

摘要： A white or whitish luminescent material for phosphorescence is provided by synthesizing an organometallic complex that is able to convert a triplet excited state into light emission. In particular, a white electroluminescent device that has a high luminous efficiency and can be manufactured easily is provided by using the organometallic complex to manufacture a white or whitish electroluminescent device. The electroluminescent device is used to provide a light-emitting device with low power consumption. A fluorescent and phosphorescent material represented by a general formula (2) is synthesized. Since this material can emit both components of fluorescence and phosphorescence in the region of visible light, white or whitish luminescence can be achieved, which is applied to an electroluminescent device or a light-emitting device

摘要翻译： 通过合成能够将三线态激发态转化为发光的有机金属络合物，提供了用于磷光的白色或发白的发光材料。 特别地，通过使用有机金属络合物制造白色或发白的电致发光器件，提供了具有高发光效率并且可容易地制造的白色电致发光器件。 电致发光器件用于提供具有低功耗的发光器件。 合成由通式（2）表示的荧光和磷光材料。 由于这种材料可以在可见光区域中发射荧光和磷光的两个成分，所以可以实现白色或白色的发光，其被施加到电致发光器件或发光器件

公开(公告)号：US07252895B2

公开(公告)日：2007-08-07

申请号：US11342424

申请日：2006-01-30

申请人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

发明人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC分类号： H01L51/54

CPC分类号： C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

摘要： The present invention is directed to a novel phosphorescent compound formed by synthesizing an orthometallated complex by using easily-synthesized ligands. The invention is further directed to an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention is also directed to a light-emitting device operating at a low voltage by using the electroluminescent device. According to the present invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission more efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the below general formula [formula 1] is iridium or platinum

摘要翻译： 本发明涉及通过使用容易合成的配体合成邻位金属络合物形成的新型磷光化合物。 本发明还涉及通过使用磷光化合物具有高发光效率的电致发光器件。 此外，本发明还涉及通过使用电致发光器件在低电压下工作的发光器件。 根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了更有效地产生磷光发射，从重原子效应的观点出发，优选使用重金属作为中心金属。 因此，本发明的一个特征是下述通式[式1]中的中心金属M是铱或铂

公开(公告)号：US20060128974A1

公开(公告)日：2006-06-15

申请号：US11342424

申请日：2006-01-30

申请人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

发明人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC分类号： C07D333/04 ,  C09K11/06 ,  H01L51/54 ,  H05B33/14

CPC分类号： C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

摘要： The present invention is directed to a novel phosphorescent compound formed by synthesizing an orthometallated complex by using easily-synthesized ligands. The invention is further directed to an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention is also directed to a light-emitting device operating at a low voltage by using the electroluminescent device. According to the present invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission more efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the below general formula [formula 1] is iridium or platinum.

摘要翻译： 本发明涉及通过使用容易合成的配体合成邻位金属络合物形成的新型磷光化合物。 本发明还涉及通过使用磷光化合物具有高发光效率的电致发光器件。 此外，本发明还涉及通过使用电致发光器件在低电压下工作的发光器件。 根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了更有效地产生磷光发射，从重原子效应的观点出发，优选使用重金属作为中心金属。 因此，本发明的一个特征是下述通式[式1]中的中心金属M是铱或铂。

公开(公告)号：US20050186446A1

公开(公告)日：2005-08-25

申请号：US10826838

申请日：2004-04-16

申请人： Satoko Shitagaki ,  Atsushi Tokuda ,  Hiroko Abe ,  Ryoji Nomura ,  Satoshi Seo

发明人： Satoko Shitagaki ,  Atsushi Tokuda ,  Hiroko Abe ,  Ryoji Nomura ,  Satoshi Seo

IPC分类号： C07D241/42 ,  C07D401/10 ,  C07D401/14 ,  C07D403/14 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14 ,  C07D241/36 ,  C07D413/00 ,  C07D417/00 ,  C07D43/00

CPC分类号： C07D403/14 ,  C07D241/42 ,  C07D401/10 ,  C07D401/14 ,  C09K11/06 ,  C09K2211/1044 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

摘要： Target is to provide an organic compound material having a bipolar character. A quinoxaline derivative represented by a general formula (1) is provided. In the formula, R1-R12 each independently represents a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group, or a heterocyclic residue group. R9 and R10, R10 and R11, and R11 and R12 are each independent or respectively mutually bonded to form an aromatic ring. Ar1-Ar4 each independently represents an aryl group or a heterocyclic residue group. Ar1, Ar2, Ar3 and Ar4 are each independent or Ar1 and Ar2, and Ar3 and Ar4 are respectively mutually bonded directly, or Ar1 and Ar3, and Ar3 and Ar4 are bonded via oxygen (O), sulfur (S) or a carbonyl group.

摘要翻译： 目标是提供具有双极性的有机化合物。 提供由通式（1）表示的喹喔啉衍生物。 在该式中，R 1 -R 12各自独立地表示氢原子，卤素原子，低级烷基，烷氧基，酰基，硝基 ，氰基，氨基，二烷基氨基，二芳基氨基，乙烯基，芳基或杂环残基。 R 9和R 10，R 10和R 11和R 11和R 11， 和R 12各自独立地或分别相互结合形成芳香环。 Ar 1〜Ar 4各自独立地表示芳基或杂环残基。 Ar 1，Ar 2，Ar 3和Ar 4各自独立地为Ar 1或Ar 1， SUP>和Ar 2，以及Ar 3和Ar 4分别相互直接连接，或者Ar 1和/ Ar 3和Ar 3和Ar 4通过氧（O），硫（S）或羰基键合。

公开(公告)号：US20050112400A1

公开(公告)日：2005-05-26

申请号：US10719808

申请日：2003-11-21

申请人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

发明人： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC分类号： C07C49/92 ,  C07C251/24 ,  C07D207/16 ,  C07F15/00 ,  C09K11/06 ,  H05B33/14 ,  C07D333/02

CPC分类号： C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

摘要： (Object) The present invention provides a novel phosphorescent compound by synthesizing an orthometallated complex by using easy-synthesized ligands. Further, the invention provides an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention provides a light-emitting device operating at a low voltage by using the electroluminescent device. (Solution Method) According to the invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission further efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the foregoing general formula [formula 1] is iridium or platinum.

摘要翻译： （对象）本发明通过使用容易合成的配体合成邻位金属配合物来提供新的磷光化合物。 此外，本发明通过使用磷光化合物提供具有高发光效率的电致发光器件。 此外，本发明提供了通过使用电致发光器件在低电压下工作的发光器件。 （溶液法）根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了进一步有效地生成磷光发射，从重原子效应的角度来看，优选使用重金属作为中心金属。 因此，本发明的一个特征是上述通式[式1]中的中心金属M是铱或铂。

公开(公告)号：US07951470B2

公开(公告)日：2011-05-31

申请号：US11632593

申请日：2005-08-12

申请人： Atsushi Tokuda ,  Masakazu Egawa

发明人： Atsushi Tokuda ,  Masakazu Egawa

IPC分类号： H01L51/54

CPC分类号： H01L51/0054 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  H01L51/0072 ,  H01L51/5012 ,  H01L2251/5338 ,  H01L2251/5361 ,  H05B33/14 ,  Y10S428/917

摘要： According to the present invention, a light-emitting element, a light-emitting device, and a lighting system, each of which has a broad spectrum like sunlight and has high color rendering properties, can be obtained. One embodiment of the present invention has a light-emitting device which includes at least two kinds of luminescence center materials, and at least one kind of the luminescence center materials is a quinoxaline derivative represented by the following general formula (1): wherein R1 to R4 are individually hydrogen or an alkyl group having 4 carbon atoms (a straight-chain structure or a branch structure).

摘要翻译： 根据本发明，可以获得具有像太阳光这样的宽光谱并且具有高显色性的发光元件，发光元件和照明系统。 本发明的一个实施方案具有包含至少两种发光中心材料的发光装置，并且至少一种发光中心材料是由以下通式（1）表示的喹喔啉衍生物：其中R1至 R4独立地为氢或具有4个碳原子的烷基（直链结构或分支结构）。