公开(公告)号：US10071510B2

公开(公告)日：2018-09-11

申请号：US14774395

申请日：2014-02-26

申请人： Emmanouil Spyrou ,  Guenter Schmitt ,  Friedrich Georg Schmidt ,  Sandra Reemers ,  Birte Olland ,  Michael Spittler ,  Holger Loesch

发明人： Emmanouil Spyrou ,  Guenter Schmitt ,  Friedrich Georg Schmidt ,  Sandra Reemers ,  Birte Olland ,  Michael Spittler ,  Holger Loesch

IPC分类号： B29C43/00 ,  B29C70/50 ,  C08G18/67 ,  C08J5/24 ,  C08G18/79 ,  C08G18/80 ,  C08F290/06 ,  C08F297/06 ,  C08J3/24 ,  C08J3/28 ,  C08J5/04 ,  B29K33/00

CPC分类号： B29C43/003 ,  B29C70/50 ,  B29K2033/08 ,  B29K2033/12 ,  C08F220/18 ,  C08F220/28 ,  C08F290/067 ,  C08F297/06 ,  C08G18/672 ,  C08G18/798 ,  C08G18/8025 ,  C08J3/24 ,  C08J3/28 ,  C08J5/043 ,  C08J5/24 ,  C08J2375/04 ,  C08J2375/06

摘要： The invention relates to a process for producing storage-stable polyurethane prepregs and to moldings (composite components) produced therefrom. The prepregs and, respectively, components are produced by mixing (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalized (meth)acrylate monomers and/or hydroxy-functionalized (meth)acrylate polymers with uretdione materials. Photoinitiators can also optionally be added. This mixture or solution is applied by known processes to fiber material, e.g. carbon fibers, glass fibers or polymer fibers, and is polymerized with the aid of radiation or of plasma methods. Polymerization, e.g. at room temperature or at up to 80° C., gives thermoplastics or thermoplastic prepregs, and these can subsequently also be subjected to forming processes. The hydroxy-functionalized (meth)acrylate constituents can then be crosslinked with the uretdiones already present within the system, by use of elevated temperature. It is thus possible to produce dimensionally stable thermosets or dimensionally stable crosslinked composite components.

公开(公告)号：US20160023384A1

公开(公告)日：2016-01-28

申请号：US14774395

申请日：2014-02-26

申请人： Emmanouil SPYROU ,  Günter SCHMITT ,  Friedrich Georg SCHMIDT ,  Sandra REEMERS ,  Birte OLLAND ,  Michael SPITTLER ,  Holger LOESCH

发明人： Emmanouil SPYROU ,  Guenter SCHMITT ,  Friedrich Georg SCHMIDT ,  Sandra REEMERS ,  Birte OLLAND ,  Michael SPITTLER ,  Holger LOESCH

IPC分类号： B29C43/00 ,  C08J3/24 ,  C08J3/28 ,  C08J5/24 ,  C08J5/04

CPC分类号： B29C43/003 ,  B29C70/50 ,  B29K2033/08 ,  B29K2033/12 ,  C08F220/18 ,  C08F220/28 ,  C08F290/067 ,  C08F297/06 ,  C08G18/672 ,  C08G18/798 ,  C08G18/8025 ,  C08J3/24 ,  C08J3/28 ,  C08J5/043 ,  C08J5/24 ,  C08J2375/04 ,  C08J2375/06

摘要： The invention relates to a process for producing storage-stable polyurethane prepregs and to mouldings (composite components) produced therefrom. The prepregs and, respectively, components are produced by mixing (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalised (meth)acrylate monomers and/or hydroxy-functionalised (meth)acrylate polymers with uretdione materials. Photoinitiators can also optionally be added. This mixture or solution is applied by known processes to fibre material, e.g. carbon fibres, glass fibres or polymer fibres, and is polymerised with the aid of radiation or of plasma methods. Polymerisation, e.g. at room temperature or at up to 80° C., gives thermoplastics or thermoplastic prepregs, and these can subsequently also be subjected to forming processes. The hydroxy-functionalised (meth)acrylate constituents can then be crosslinked with the uretdiones already present within the system, by use of elevated temperature. It is thus possible to produce dimensionally stable thermosets or dimensionally stable crosslinked composite components.

摘要翻译： 本发明涉及一种用于制备储存稳定的聚氨酯预浸料的方法和由其制备的模制品（复合组分）。 通过将（甲基）丙烯酸酯单体，（甲基）丙烯酸酯聚合物，羟基官能化的（甲基）丙烯酸酯单体和/或羟基官能化的（甲基）丙烯酸酯）聚合物与脲二酮材料混合，分别制备预浸料。 也可以加入光引发剂。 该混合物或溶液通过已知方法施用于纤维材料，例如 碳纤维，玻璃纤维或聚合物纤维，并借助辐射或等离子体方法聚合。 聚合，例如 在室温或高达80℃下，得到热塑性塑料或热塑性预浸料，随后也可以进行成型工艺。 羟基官能化的（甲基）丙烯酸酯组分然后可以通过使用升高的温度与已经存在于体系内的脲化合物交联。 因此可以制备尺寸稳定的热固性材料或尺寸稳定的交联复合材料组件。