公开(公告)号：US08557399B2

公开(公告)日：2013-10-15

申请号：US12265375

申请日：2008-11-05

申请人： Brian D'Andrade ,  Peter B. Mackenzie ,  Michael S. Weaver ,  Julia J. Brown

发明人： Brian D'Andrade ,  Peter B. Mackenzie ,  Michael S. Weaver ,  Julia J. Brown

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0002 ,  H01L51/0025 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/552

摘要： Novel combination of materials and device architectures for organic light emitting devices are provided. In some aspects, specific charge carriers and solid state considerations are features that may result in a device having an unexpectedly long lifetime. In some aspects, emitter purity is a feature that may result in devices having unexpectedly long lifetime. In some aspects, structural and optical considerations are features that may result in a device having an unexpectedly long lifetime. In some aspects, an emissive layer including an organic phosphorescent emissive dopant and an organic carbazole host material results in devices having an unexpectedly long lifetime.

摘要翻译： 提供了有机发光器件的材料和器件结构的新颖组合。 在一些方面，特定的电荷载体和固态考虑是可能导致器件具有意想不到的长寿命的特征。 在一些方面，发射体纯度是可能导致器件意外长寿命的特征。 在一些方面，结构和光学考虑是可能导致设备具有意想不到的长寿命的特征。 在一些方面，包括有机磷光发射掺杂剂和有机咔唑主体材料的发射层导致具有意想不到的长寿命的器件。

公开(公告)号：US20110248250A1

公开(公告)日：2011-10-13

申请号：US13124991

申请日：2008-10-23

申请人： Brian D'Andrade ,  Julia J. Brown ,  Michael S. Weaver ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito

发明人： Brian D'Andrade ,  Julia J. Brown ,  Michael S. Weaver ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito

IPC分类号： H01L51/54

CPC分类号： H01L51/5016 ,  C07C15/28 ,  C07C15/30 ,  C07C15/38 ,  C07C2603/26 ,  C07C2603/42 ,  C07C2603/48 ,  C07C2603/52 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0058 ,  H01L51/0085 ,  H01L51/0094

摘要： The present invention provides an OLED in which an organic thin film layer comprising a single layer or plural layers is provided between a cathode and an anode, where the organic thin film layer comprises at least one light emitting layer, and the at least one light emitting layer comprises (a) a host material represented by the following Formula (1): Ra—Ar1—Ar2—Rb (1) where Ar1, Ar2, Ra and Rb represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon group selected from a substituted or unsubstituted naphthalene ring, chrysene ring, a substituted or unsubstituted fluoranthene ring, triphenylene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzotriphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted picene ring and a substituted or unsubstituted benzofluoranthene ring; and (b) at least one phosphorescent material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formulas: wherein each R is independently hydrogen or an alkyl substituent having 1-3 carbon atoms, and wherein at least one ring of the formula has one or more of said alkyl substituent.

摘要翻译： 本发明提供了一种OLED，其中在阴极和阳极之间设置包括单层或多层的有机薄膜层，其中有机薄膜层包括至少一个发光层，并且所述至少一个发光 层包含（a）由下式（1）表示的主体材料：Ra-Ar1-Ar2-Rb（1）其中Ar1，Ar2，Ra和Rb表示取代或未取代的苯环或稠合芳族烃基， 取代或未取代的萘环，环，取代或未取代的荧蒽环，三亚苯环，取代或未取代的菲环，取代或未取代的苯并菲环，取代或未取代的二苯并菲环，取代或未取代的苯并亚苯基环， 或未取代的苯并环，取代或未取代的吡啶环和取代或未取代的苯并环 香叶烯环 和（b）至少一种磷光材料包含具有由下式表示的以下部分化学结构之一表示的取代的化学结构的磷光有机金属络合物：其中每个R独立地是氢或具有1-3个碳原子的烷基取代基， 并且其中至少一个下式的环具有一个或多个所述烷基取代基。

公开(公告)号：US07776456B2

公开(公告)日：2010-08-17

申请号：US11002260

申请日：2004-12-03

申请人： Brian D'Andrade ,  Theodore Zhou

发明人： Brian D'Andrade ,  Theodore Zhou

IPC分类号： H01L51/54

CPC分类号： H01L51/5016 ,  H01L51/5278 ,  H01L51/56 ,  Y10S428/917 ,  Y10T428/24851 ,  Y10T428/24942

摘要： The present invention provides an OLED with an emissive region comprising a plurality of sets of organic layers, each set comprising a non-continuous emissive layer and a neat non-emissive layer. The present invention also provides an OLED with an emissive region comprising a plurality of sets of organic layers, each set comprising an emissive layer and a neat non-emissive layer, wherein the energy gaps of the emissive layer and the non-emissive layer are not nested. The present invention also provides a method for making OLEDs by depositing on a substrate an anode, a plurality of sets of organic layers, each set comprising an emissive layer and a non-emissive layer wherein each layer is deposited sequentially, and a cathode.

摘要翻译： 本发明提供一种具有发射区域的OLED，该发射区域包括多组有机层，每一组包括非连续的发射层和整齐的非发射层。 本发明还提供一种具有发射区域的发光区域，该发射区域包括多组有机层，每一组包括发射层和整齐的非发射层，其中发射层和非发射层的能隙不是 嵌套 本发明还提供了一种制造OLED的方法，该方法通过在衬底上沉积阳极，多组有机层，每组包括发射层和非发射层，其中每层依次沉积，阴极。

公开(公告)号：US20100090241A1

公开(公告)日：2010-04-15

申请号：US12577482

申请日：2009-10-12

申请人： Brian D'Andrade ,  Michael S. Weaver ,  Julia J. Brown

发明人： Brian D'Andrade ,  Michael S. Weaver ,  Julia J. Brown

IPC分类号： H01L51/52 ,  H01L51/56

CPC分类号： H01L51/5036 ,  H01L27/3211 ,  H01L51/5203

摘要： An organic light emitting device is provided. The device includes an anode, a cathode, and an organic emissive stack disposed between the anode and the cathode. The device may be a “pixel” in a display, capable of emitting a wide variety of colors through the use of independently addressable “sub-pixels,” each subpixel emitting a different spectrum of light. In the most general sense, the device includes a first subpixel and a second subpixel, and at least one of the anode and the cathode has independently addressable first and second regions corresponding to the first and second subpixels. The device includes an emissive stack disposed between the anode and the cathode. The emissive stack includes a first organic emissive layer and a second organic emissive layer. The first organic emissive layer is disposed between the anode and the cathode, and extends throughout the first and second regions. The second organic emissive layer is disposed between the anode and the cathode, and extends throughout the second region but not the first region. The second organic emissive layer is disposed closer to the cathode than the first organic emissive layer. The first organic emissive layer is emissive in the first region, and the second organic emissive layer is emissive in the second region.

摘要翻译： 提供有机发光装置。 该装置包括阳极，阴极和设置在阳极和阴极之间的有机发射叠层。 该装置可以是显示器中的“像素”，能够通过使用可独立寻址的“子像素”发射各种颜色，每个子像素发射不同光谱。 在最通常的意义上，该装置包括第一子像素和第二子像素，并且阳极和阴极中的至少一个具有对应于第一和第二子像素的独立可寻址的第一和第二区域。 该装置包括设置在阳极和阴极之间的发射叠层。 发射堆叠包括第一有机发射层和第二有机发射层。 第一有机发射层设置在阳极和阴极之间，并延伸遍及第一和第二区域。 第二有机发射层设置在阳极和阴极之间，并且延伸遍及第二区域而不是第一区域。 第二有机发光层设置成比第一有机发光层更靠近阴极。 第一有机发射层在第一区域中发射，并且第二有机发射层在第二区域中发光。

公开(公告)号：US20070103066A1

公开(公告)日：2007-05-10

申请号：US11266181

申请日：2005-11-04

申请人： Brian D'Andrade ,  Richard Hewitt ,  Kamala Rajan ,  Vadim Adamovich

发明人： Brian D'Andrade ,  Richard Hewitt ,  Kamala Rajan ,  Vadim Adamovich

IPC分类号： H01J1/62

CPC分类号： H01L27/3209 ,  H01L25/048 ,  H01L27/3202 ,  H01L27/3204 ,  H01L27/3267 ,  H01L27/3286 ,  H01L51/0059 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5218 ,  H01L51/5278 ,  H01L2924/0002 ,  H01L2924/00

摘要： The present invention provides an OLED comprising two or more organic emissive layers electrically connected with a reflective conductive layer.

摘要翻译： 本发明提供一种OLED，其包含与反射导电层电连接的两个或更多个有机发光层。

公开(公告)号：US06869695B2

公开(公告)日：2005-03-22

申请号：US10112257

申请日：2002-03-29

申请人： Mark E. Thompson ,  Jason Brooks ,  Vadim Adamovich ,  Stephen R. Forrest ,  Brian D'Andrade

发明人： Mark E. Thompson ,  Jason Brooks ,  Vadim Adamovich ,  Stephen R. Forrest ,  Brian D'Andrade

IPC分类号： H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14 ,  C09K11/06

CPC分类号： H01L51/5016 ,  H01L51/0037 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5036 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917 ,  Y10T428/24942

摘要： The present invention relates to efficient organic light emitting devices (OLEDs). More specifically, the present invention relates to white-emitting OLEDs, or WOLEDs. The devices of the present invention employ two emitters in a single emissive region to sufficiently cover the visible spectrum. White emission is achieved from two emitters in a single emissive region through the formation of an aggregate by one of the emissive centers. This allows the construction of simple, bright and efficient WOLEDs that exhibit a high color rendering index.

公开(公告)号：US08053770B2

公开(公告)日：2011-11-08

申请号：US12577482

申请日：2009-10-12

申请人： Brian D'Andrade ,  Michael S. Weaver ,  Julia J. Brown

发明人： Brian D'Andrade ,  Michael S. Weaver ,  Julia J. Brown

IPC分类号： H01L29/08 ,  H01L35/24 ,  H01L51/00

CPC分类号： H01L51/5036 ,  H01L27/3211 ,  H01L51/5203

摘要： An organic light emitting device is provided. The device includes an anode, a cathode, and an organic emissive stack disposed between the anode and the cathode. The device may be a “pixel” in a display, capable of emitting a wide variety of colors through the use of independently addressable “sub-pixels,” each subpixel emitting a different spectrum of light. In the most general sense, the device includes a first subpixel and a second subpixel, and at least one of the anode and the cathode has independently addressable first and second regions corresponding to the first and second subpixels. The device includes an emissive stack disposed between the anode and the cathode. The emissive stack includes a first organic emissive layer and a second organic emissive layer. The first organic emissive layer is disposed between the anode and the cathode, and extends throughout the first and second regions. The second organic emissive layer is disposed between the anode and the cathode, and extends throughout the second region but not the first region. The second organic emissive layer is disposed closer to the cathode than the first organic emissive layer. The first organic emissive layer is emissive in the first region, and the second organic emissive layer is emissive in the second region.

摘要翻译： 提供有机发光装置。 该装置包括阳极，阴极和设置在阳极和阴极之间的有机发射叠层。 该装置可以是显示器中的“像素”，能够通过使用可独立寻址的“子像素”发射各种颜色，每个子像素发射不同光谱。 在最通常的意义上，该装置包括第一子像素和第二子像素，并且阳极和阴极中的至少一个具有对应于第一和第二子像素的独立可寻址的第一和第二区域。 该装置包括设置在阳极和阴极之间的发射叠层。 发射堆叠包括第一有机发射层和第二有机发射层。 第一有机发射层设置在阳极和阴极之间，并延伸遍及第一和第二区域。 第二有机发射层设置在阳极和阴极之间，并且延伸遍及第二区域而不是第一区域。 第二有机发光层设置成比第一有机发光层更靠近阴极。 第一有机发射层在第一区域中发射，并且第二有机发射层在第二区域中发光。

公开(公告)号：US20090200927A1

公开(公告)日：2009-08-13

申请号：US12332945

申请日：2008-12-11

申请人： Brian D'Andrade ,  James Esler

发明人： Brian D'Andrade ,  James Esler

IPC分类号： H01J1/62

CPC分类号： H01L51/5036

摘要： An organic light emitting device is provided. The device includes an anode and a cathode. A first emissive layer is disposed between the anode and the cathode. The first emissive layer includes a first non-emitting organic material, which is an organometallic material present in the first emissive layer in a concentration of at least 50 wt %. The first emissive layer also includes a first emitting organic material. A second emissive layer is disposed between the first emissive layer and the cathode, preferably, in direct contact with the first emissive layer. The second emissive material includes a second non-emitting organic material and a second emitting organic material. The first and second non-emitting materials, and the first and second emitting materials, are all different materials. A first non-emissive layer is disposed between the first emissive layer and the anode, and in direct contact with the first emissive layer. The first non-emissive layer comprises the first non-emissive organic material.

摘要翻译： 提供有机发光装置。 该装置包括阳极和阴极。 第一发射层设置在阳极和阴极之间。 第一发射层包括第一非发射有机材料，其是以至少50重量％的浓度存在于第一发射层中的有机金属材料。 第一发射层还包括第一发射有机材料。 第二发射层设置在第一发射层和阴极之间，优选地与第一发射层直接接触。 第二发射材料包括第二不发射有机材料和第二发射有机材料。 第一和第二非发射材料以及第一和第二发射材料都是不同的材料。 第一非发射层设置在第一发射层和阳极之间，并且与第一发射层直接接触。 第一非发射层包括第一非发射有机材料。

公开(公告)号：US20090121621A1

公开(公告)日：2009-05-14

申请号：US12257648

申请日：2008-10-24

申请人： Brian D'Andrade

发明人： Brian D'Andrade

IPC分类号： H01J1/63

CPC分类号： H01L51/0002 ,  H01L51/0025 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/552

摘要： An organic light emitting device is provided. The device has a first electrode, a second electrode, and an emissive layer disposed between the first and second electrodes. The emissive layer includes an emissive material with an intrinsic emission spectrum having a peak emission wavelength in the visible spectrum less than 500 nm. The device includes a color saturation enhancement layer in direct contact with the first electrode. The color saturation enhancement layer consists essentially of one or more metals or conductive doped inorganic semiconductors, and has an index of refraction at least 0.2 different from that of the organic layers. The color saturation enhancement layer has a thickness of 1-10 nm. The reflectivity of the color saturation enhancement layer is in the range 5% to 30% for the peak wavelength in the intrinsic emission spectrum of the emissive material. Preferably, the color saturation enhancement layer is disposed between the first and second electrodes.

摘要翻译： 提供有机发光装置。 该器件具有第一电极，第二电极和布置在第一和第二电极之间的发射层。 发射层包括具有在可见光谱中小于500nm的峰值发射波长的本征发射光谱的发射材料。 该装置包括与第一电极直接接触的色彩饱和度增强层。 色彩饱和度增强层基本上由一种或多种金属或导电掺杂的无机半导体组成，并且折射率与有机层的折射率至少为0.2。 色饱和度增强层的厚度为1-10nm。 对于发射材料的本征发射光谱中的峰值波长，色彩饱和度增强层的反射率在5％至30％的范围内。 优选地，色彩饱和度增强层设置在第一和第二电极之间。

公开(公告)号：US20080061680A1

公开(公告)日：2008-03-13

申请号：US11517513

申请日：2006-09-08

申请人： Brian D'Andrade ,  Vadim Adamovich

发明人： Brian D'Andrade ,  Vadim Adamovich

IPC分类号： H01J1/62

CPC分类号： H01L51/5265 ,  H01L2251/5323

摘要： An organic light emitting device having a microcavity is provided. The device may be transparent to the resonant wavelength of the microcavity, allowing for saturated emission at the wavelength or wavelengths of light transmitted by the microcavity.

摘要翻译： 提供了具有微腔的有机发光器件。 该器件对于微腔的谐振波长可以是透明的，允许在由微腔传输的光的波长或波长处的饱和发射。