公开(公告)号：US20070100169A1

公开(公告)日：2007-05-03

申请号：US10562602

申请日：2004-06-28

申请人： John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

发明人： John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

IPC分类号： C07F9/02 ,  C07C45/49

CPC分类号： C07F9/5022 ,  C07C29/16 ,  C07C45/50 ,  C07C45/62 ,  C07C67/38 ,  C07C33/03 ,  C07C69/738 ,  C07C47/21 ,  C07C47/02

摘要： A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an αelectronwithdrawing group, such as, an α,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).

摘要翻译： 一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭 具有与α-电子牵伸基团例如α，β-不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。 最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。 此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转 其混合物在足以再生三有机膦配体的条件下进行。

公开(公告)号：US20060193802A1

公开(公告)日：2006-08-31

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

发明人： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

IPC分类号： C07C29/14

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或脂肪酸酯的混合物，所述羟甲基取代的脂肪酸或脂肪酸酯具有以下重量组成：大于约10至小于约95％的一元醇{单（羟甲基，大于 约1至小于约65％的二醇{二（羟甲基，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯;优选大于约3至小于约35％ 饱和物;优选小于约10％的不饱和度。醇组合物可以转化为用于制备聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US20080114191A1

公开(公告)日：2008-05-15

申请号：US12018841

申请日：2008-01-24

申请人： John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

发明人： John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

IPC分类号： C07C45/49

CPC分类号： C07F9/5022 ,  C07C29/16 ,  C07C45/50 ,  C07C45/62 ,  C07C67/38 ,  C07C33/03 ,  C07C69/738 ,  C07C47/21 ,  C07C47/02

摘要： A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an α-electron-withdrawing group, such as, an α,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).

摘要翻译： 一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭 具有与α-吸电子基团例如α，β-不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。 最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。 此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转 其混合物在足以再生三有机膦配体的条件下进行。