Abstract:
The present invention relates to supported metallocene catalysts and to new processes for preparing them and olefin polymerization therewith. Specifically, this invention relates to supported catalyst benefiting from the penetration and homogeneous distribution of catalyst components containing one or more metallocenes and activators within porous support particles. A new process for preparing the catalyst of the invention provides for a supported metallocene catalyst, wherein one or more metallocenes and activator, a solvent capable of dissolving them and a porous support are mutually contacted to form a slurry and a sonic wave or vibrating wave in the frequency range of 1-10,000 kHz is applied to the slurry and the solvent is removed and the resultants are dried. The catalyst are useful for olefin polymerization in a slurry and gas phase polymerization process.
Abstract:
There are disclosed new metallocene compounds and catalysts for olefin polymerization. The metallocene compound is a complex of transition metal and cyclopentadienyl-type ligands substituted with silacycloalkyl group. The metallocene catalyst comprises the above metallocene compound and at least one activator such as aluminoxanes, aromatic boron compounds substituted with fluoride, and modified clays. The metallocene catalyst can be used for polymerization of olefin in liquid phase, slurry phase or gas phase process.
Abstract:
The preset invention relates to a solid oxide fuel cell stack capable of producing electricity, in which unit cell modules are connected in series and in parallel, and to a manufacturing method thereof. The solid oxide fuel cell stack is manufactured by: making a unit cell module comprising at least one unit cell formed on the outer surfaces of a flat tubular support, a first electrical interconnector formed on the front end of the support and at least a portion of the outer surfaces so as to be connected to a first electrode of the unit cell, and a second electrical interconnector formed on the rear end of the support and at least a portion of the outer surfaces so as to be connected to a second electrode of the unit cell; and stacking the unit cell modules such that the electrical interconnectors come into contact with each other.
Abstract:
The preset invention relates to a solid oxide fuel cell stack capable of producing electricity, in which unit cell modules are connected in series and in parallel, and to a manufacturing method thereof. The solid oxide fuel cell stack is manufactured by: making a unit cell module comprising at least one unit cell formed on the outer surfaces of a flat tubular support, a first electrical interconnector formed on the front end of the support and at least a portion of the outer surfaces so as to be connected to a first electrode of the unit cell, and a second electrical interconnector formed on the rear end of the support and at least a portion of the outer surfaces so as to be connected to a second electrode of the unit cell; and stacking the unit cell modules such that the electrical interconnectors come into contact with each other.
Abstract:
A fuel oil detergent which efficiently constricts precipitate formation and octane number requirement increase in a carburetor, injector, and inlet system of an internal combustion engine, i.e., a hydropoly(oxyalkylene) oxyalkyl amine based compound, a process for preparing the compound, and a fuel oil composition including the compound.