公开(公告)号：US07736744B2

公开(公告)日：2010-06-15

申请号：US11533518

申请日：2006-09-20

申请人： Paul H. Lamers ,  Christopher A. Verardi ,  Michele L. Meli ,  Carolyn A. Novak

发明人： Paul H. Lamers ,  Christopher A. Verardi ,  Michele L. Meli ,  Carolyn A. Novak

IPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/30 ,  B32B27/36 ,  B32B27/38 ,  B32B27/40 ,  C08L33/00 ,  C08L63/00 ,  C08L67/00 ,  C08L75/04 ,  C08L75/12

CPC分类号： C09J4/06 ,  C08F283/01 ,  C08G71/04 ,  C08G2190/00 ,  C09D151/08 ,  Y10T428/31515 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L2666/02

摘要： Aqueous resinous binders comprising graft copolymers, water-dilutable urethane polyols and epoxy-phosphorus acid reaction products are disclosed. The binders are useful in primer formulations for automotive applications.

摘要翻译： 公开了含有接枝共聚物，水可稀释的聚氨酯多元醇和环氧 - 磷酸反应产物的水性树脂粘合剂。 粘合剂可用于汽车应用的底漆制剂。

公开(公告)号：US07709093B2

公开(公告)日：2010-05-04

申请号：US10982074

申请日：2004-11-05

申请人： Michael P. Makowski ,  Jonathan T. Martz ,  Carolyn A. Novak ,  Christopher A. Verardi

发明人： Michael P. Makowski ,  Jonathan T. Martz ,  Carolyn A. Novak ,  Christopher A. Verardi

IPC分类号： B32B27/40 ,  C08G18/00

CPC分类号： C08G18/0823 ,  C08G18/12 ,  C08G18/4018 ,  C08G18/4854 ,  C08G18/6625 ,  C08G18/6692 ,  C08K3/013 ,  C09D175/04 ,  C09D175/12 ,  Y10T428/31551 ,  C08G18/3834 ,  C08G18/2875 ,  C08L2666/02 ,  C08L2666/54

摘要： A coating composition, formed of a film-forming component comprising a functional group-containing resinous binder and, optionally, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the film-forming component, wherein, when the composition is applied and cured to form a cured coating, the cured coating is characterized as having a bicontinuous morphology. Methods of making the coating composition and coatings prepared therefrom are also provided. The coating composition can provide improved physical properties, such as chip resistance, when incorporated into a coating.

摘要翻译： 一种涂料组合物，其由含有官能团的树脂粘合剂和任选的具有至少两个与成膜组分的官能团反应的官能团的官能团的交联剂形成的成膜组分形成，其中，当 组合物被施加和固化以形成固化涂层，固化的涂层的特征在于具有双连续的形态。 还提供了制备涂料组合物和由其制备的涂料的方法。 涂料组合物当被掺入到涂层中时可以提供改进的物理性能，例如耐碎屑性。

公开(公告)号：US06624276B2

公开(公告)日：2003-09-23

申请号：US09960543

申请日：2001-09-21

申请人： Paul H. Lamers ,  Jonathan T. Martz ,  Lawrence D. Meyers ,  Carolyn A. Novak ,  Kurt G. Olson ,  James P. Rowley ,  Christopher A. Verardi

发明人： Paul H. Lamers ,  Jonathan T. Martz ,  Lawrence D. Meyers ,  Carolyn A. Novak ,  Kurt G. Olson ,  James P. Rowley ,  Christopher A. Verardi

IPC分类号： C08G1880

CPC分类号： C09D175/04 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/12 ,  C08G18/3206 ,  C08G18/4854 ,  C08G18/807 ,  Y10T428/31551 ,  C08G18/348 ,  C08G18/50 ,  C08G18/286 ,  C08G18/3228 ,  C08G18/3275

摘要： A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. An anionic self-crosslinkable polyurethane material has a weight average molecular weight of less than 15,000 grams per mole and, when cured, has a toughness of at least 20 MPa according to TOUGHNESS TEST METHOD at a temperature of 25° C.

公开(公告)号：US20080071011A1

公开(公告)日：2008-03-20

申请号：US11533518

申请日：2006-09-20

申请人： Paul H. Lamers ,  Christopher A. Verardi ,  Michele L. Meli ,  Carolyn A. Novak

发明人： Paul H. Lamers ,  Christopher A. Verardi ,  Michele L. Meli ,  Carolyn A. Novak

IPC分类号： C08K3/20

CPC分类号： C09J4/06 ,  C08F283/01 ,  C08G71/04 ,  C08G2190/00 ,  C09D151/08 ,  Y10T428/31515 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L2666/02

摘要： Aqueous resinous binders comprising graft copolymers, water-dilutable urethane polyols and epoxy-phosphorus acid reaction products are disclosed. The binders are useful in primer formulations for automotive applications.

摘要翻译： 公开了含有接枝共聚物，水可稀释的聚氨酯多元醇和环氧 - 磷酸反应产物的水性树脂粘合剂。 粘合剂可用于汽车应用的底漆制剂。

公开(公告)号：US06559265B2

公开(公告)日：2003-05-06

申请号：US09961096

申请日：2001-09-21

申请人： Paul H. Lamers ,  Jonathan T. Martz ,  Lawrence D. Meyers ,  Carolyn A. Novak ,  Kurt G. Olson ,  James P. Rowley ,  Christopher A. Verardi

发明人： Paul H. Lamers ,  Jonathan T. Martz ,  Lawrence D. Meyers ,  Carolyn A. Novak ,  Kurt G. Olson ,  James P. Rowley ,  Christopher A. Verardi

IPC分类号： C08G1880

CPC分类号： C09D175/04 ,  C08G18/0823 ,  C08G18/0833 ,  C08G18/10 ,  C08G18/3206 ,  C08G18/345 ,  C08G18/4854 ,  C08G18/5024 ,  C08G18/6688 ,  C08G18/6692 ,  C08G18/8048 ,  C08G18/807 ,  C08G18/8077 ,  Y10T428/31551 ,  Y10T428/31554 ,  C08G18/286 ,  C08G18/50 ,  C08G18/2865 ,  C08G18/3275 ,  C08G18/348

摘要： A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. A polyurethane material may be formed from components comprising at least one polyisocyanate, at least one active hydrogen-containing material, at least one material having at least one primary or secondary amino group and at least one hydroxyl group, and at least one acid functional material or anhydride having a functional group reactive with isocyanate or hydroxyl groups of other components from which the polyurethane material is formed. The polyurethane can provide improved physical properties, such as chip resistance, when incorporated into a coating composition.

公开(公告)号：US5942556A

公开(公告)日：1999-08-24

申请号：US757271

申请日：1996-11-27

申请人： Charles B. Friedlander ,  Ronald R. Ambrose ,  David A. Diehl ,  Alan B. Weissberg ,  Carolyn A. Novak

发明人： Charles B. Friedlander ,  Ronald R. Ambrose ,  David A. Diehl ,  Alan B. Weissberg ,  Carolyn A. Novak

IPC分类号： C08F2/50 ,  C08K5/06 ,  C08L67/06 ,  C09D175/06 ,  C08K5/524 ,  C08L67/07

CPC分类号： C08L67/06 ,  C08K5/06 ,  C09D175/06

摘要： Disclosed is a radiation curable composition which includes: (a) an unsaturated ester compound, and (b) a pulverizable vinyl ether compound. The unsaturated ester compound is characterized as having a plurality of unsaturated ester groups per molecule. The pulverizable vinyl ether compound is characterized as including at least one of the following: (a) a compound having an average of greater than 1.0 reactive vinyl ether groups per molecule, and (b) a vinyl ether-containing group bonded to the unsaturated ester compound such that there is an average of at least 1.0 reactive vinyl ether group per molecule. The unsaturated ester compound, the vinyl ether compound and/or a mixture thereof is treated with a reducing agent so as to decompose destabilizing agents present therein that would initiate premature polymerization of the vinyl ether compound. Accordingly, in the stabilized radiation curable coating compositions of this invention, polymerization of the vinyl ether compound is substantially avoided until blended with the unsaturated ester compound and exposed to radiation.

摘要翻译： 公开了一种可辐射固化组合物，其包括：（a）不饱和酯化合物和（b）可粉化的乙烯基醚化合物。 不饱和酯化合物的特征在于每分子具有多个不饱和酯基。 可粉碎的乙烯基醚化合物的特征在于包括以下至少一种：（a）每分子平均具有大于1.0个反应性乙烯基醚基团的化合物，和（b）与不饱和酯键合的含乙烯基醚基团 化合物，使得每个分子平均具有至少1.0个反应性乙烯基醚基团。 用还原剂处理不饱和酯化合物，乙烯基醚化合物和/或它们的混合物，以分解其中存在乙烯基醚化合物过早聚合的不稳定剂。 因此，在本发明的稳定的可辐射固化涂料组合物中，基本上避免了乙烯基醚化合物的聚合，直到与不饱和酯化合物共混并暴露于辐射。