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13 条记录 (耗时 0.025 秒)

    Stabilized radiation curable compositions based on unsaturated ester and vinyl ether compounds
    1.
    发明授权
    Stabilized radiation curable compositions based on unsaturated ester and vinyl ether compounds 失效
    基于不饱和酯和乙烯基醚化合物的稳定的可辐射固化组合物

    公开(公告)号：US5942556A

    公开(公告)日：1999-08-24

    申请号：US757271

    申请日：1996-11-27

    申请人： Charles B. Friedlander ,  Ronald R. Ambrose ,  David A. Diehl ,  Alan B. Weissberg ,  Carolyn A. Novak

    发明人： Charles B. Friedlander ,  Ronald R. Ambrose ,  David A. Diehl ,  Alan B. Weissberg ,  Carolyn A. Novak

    IPC分类号： C08F2/50 ,  C08K5/06 ,  C08L67/06 ,  C09D175/06 ,  C08K5/524 ,  C08L67/07

    CPC分类号： C08L67/06 ,  C08K5/06 ,  C09D175/06

    摘要： Disclosed is a radiation curable composition which includes: (a) an unsaturated ester compound, and (b) a pulverizable vinyl ether compound. The unsaturated ester compound is characterized as having a plurality of unsaturated ester groups per molecule. The pulverizable vinyl ether compound is characterized as including at least one of the following: (a) a compound having an average of greater than 1.0 reactive vinyl ether groups per molecule, and (b) a vinyl ether-containing group bonded to the unsaturated ester compound such that there is an average of at least 1.0 reactive vinyl ether group per molecule. The unsaturated ester compound, the vinyl ether compound and/or a mixture thereof is treated with a reducing agent so as to decompose destabilizing agents present therein that would initiate premature polymerization of the vinyl ether compound. Accordingly, in the stabilized radiation curable coating compositions of this invention, polymerization of the vinyl ether compound is substantially avoided until blended with the unsaturated ester compound and exposed to radiation.

    摘要翻译： 公开了一种可辐射固化组合物，其包括：（a）不饱和酯化合物和（b）可粉化的乙烯基醚化合物。 不饱和酯化合物的特征在于每分子具有多个不饱和酯基。 可粉碎的乙烯基醚化合物的特征在于包括以下至少一种：（a）每分子平均具有大于1.0个反应性乙烯基醚基团的化合物，和（b）与不饱和酯键合的含乙烯基醚基团 化合物，使得每个分子平均具有至少1.0个反应性乙烯基醚基团。 用还原剂处理不饱和酯化合物，乙烯基醚化合物和/或它们的混合物，以分解其中存在乙烯基醚化合物过早聚合的不稳定剂。 因此，在本发明的稳定的可辐射固化涂料组合物中，基本上避免了乙烯基醚化合物的聚合，直到与不饱和酯化合物共混并暴露于辐射。

    Polyester and vinyl ether radiation curable compositions with reactive diluent
    2.
    发明授权
    Polyester and vinyl ether radiation curable compositions with reactive diluent 失效
    具有反应性稀释剂的聚酯和乙烯基醚可辐射固化组合物

    公开(公告)号：US6001892A

    公开(公告)日：1999-12-14

    申请号：US999685

    申请日：1996-02-16

    申请人： Alan B. Weissberg ,  Edward E. McEntire ,  Charles B. Friedlander

    发明人： Alan B. Weissberg ,  Edward E. McEntire ,  Charles B. Friedlander

    IPC分类号： C08F2/46 ,  C08F2/50 ,  C08F283/01 ,  C08F290/06 ,  C09D4/00 ,  C09D4/06 ,  C09D5/00 ,  C09D167/06 ,  C08F16/16 ,  C08G63/52 ,  C08L67/06

    CPC分类号： C08F283/01 ,  C09D4/06

    摘要： A liquid, radiation curable composition is disclosed that includes a reactive diluent to lower initial application viscosity without substantial reduction of cure rate. The composition of the present invention comprises: (a) an unsaturated polyester polymer; (b) a non-polymerized, cocurable polyfunctional vinyl ether component; and (c) a reactive diluent which is an unsaturated dioic acid ester having the following structural formula: ##STR1## wherein at least one of R.sup.1 and R.sup.2 is a group that includes an oxygen with a carbon adlacent thereto and an abstractable hydrogen attached to the carbon.

    摘要翻译： 公开了一种液体可辐射固化的组合物，其包括反应性稀释剂以降低初始施加粘度，而实质上不降低固化速率。 本发明的组合物包括：（a）不饱和聚酯聚合物; （b）未聚合的可共聚的多官能乙烯基醚组分; 和（c）具有以下结构式的不饱和二酸酯的反应性稀释剂：其中R 1和R 2中的至少一个是包含与其相邻的碳的氧和连接到碳上的可抽出氢的基团。

    Radiation curable compositions based on unsaturated polyesters and compounds having at least two vinyl ether groups
    4.
    发明授权
    Radiation curable compositions based on unsaturated polyesters and compounds having at least two vinyl ether groups 失效
    基于不饱和聚酯和具有至少两个乙烯基醚基团的化合物的可辐射固化组合物

    公开(公告)号：US5536760A

    公开(公告)日：1996-07-16

    申请号：US166665

    申请日：1993-12-10

    申请人： Charles B. Friedlander ,  David A. Diehl

    发明人： Charles B. Friedlander ,  David A. Diehl

    IPC分类号： C08F283/01 ,  C08F2/46 ,  C08F2/48 ,  C08F2/50 ,  C08F2/54 ,  C08F290/00 ,  C08F299/02 ,  C08F299/04 ,  C09D4/00 ,  C09D4/06 ,  C09D155/00 ,  C09D167/06

    CPC分类号： C08F299/0478 ,  C09D4/06

    摘要： Disclosed is a liquid, radiation curable composition comprising: (A) an unsaturated polyester component containing an unsaturated polyester polymer, an unsaturated polyester oligomer or a mixture thereof; and (B) a non-polymerized, cocurable vinyl ether component which may be separate from or structurally incorporated in the unsaturated polyester component, provided that the vinyl ether component contains an average of at least two vinyl ether groups per molecule of the vinyl ether component.Also disclosed is a method of coating comprising: applying to a substrate a film of a liquid, radiation curable composition of the invention, and curing the composition through its thickness to a tack-free state by exposing the film to ionizing radiation and/or ultraviolet light.

    摘要翻译： 本发明公开了一种液体可辐射固化组合物，其包含：（A）含有不饱和聚酯聚合物，不饱和聚酯低聚物或其混合物的不饱和聚酯组分; 和（B）未聚合的可共凝胶的乙烯基醚组分，其可以与不饱和聚酯组分分开或结构上并入不饱和聚酯组分中，条件是乙烯基醚组分每分子含有至少两个乙烯基醚基团的平均乙烯基醚组分 。 还公开了一种涂覆方法，其包括：向基材施加本发明的液体，可辐射固化组合物的膜，并通过将该膜暴露于电离辐射和/或紫外线而将组合物通过其厚度固化至无粘性状态 光。

    Radiation curable compositions based on radiation curable esters of polyfunctional hydroxyl-containing carboxylic acids
    6.
    发明授权
    Radiation curable compositions based on radiation curable esters of polyfunctional hydroxyl-containing carboxylic acids 失效
    基于多官能含羟基羧酸的辐射固化酯的可辐射固化组合物

    公开(公告)号：US4649082A

    公开(公告)日：1987-03-10

    申请号：US709147

    申请日：1985-03-07

    申请人： Charles B. Friedlander

    发明人： Charles B. Friedlander

    IPC分类号： C08L67/00 ,  C08F2/50 ,  C08F290/00 ,  C08F299/00 ,  C08F299/04 ,  C08G63/00 ,  C08G63/06 ,  C08G63/12 ,  C08G63/66 ,  C08G63/664 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/16 ,  C08L67/04 ,  C09D5/32 ,  C09D179/08 ,  B32B15/08 ,  B32B27/30 ,  C08F20/20

    CPC分类号： C08F299/0485 ,  C08G63/664 ,  Y10T428/31692 ,  Y10T428/31696

    摘要： Disclosed is an ungelled radiation curable resin which is a reaction product of (a) a polyfunctional hydroxyl-containing carboxylic acid having a molecular weight less than or equal to 1,000 and having a total functionality of equal to or greater than 3; (b) an organic hydroxyl-functional compound; and (c) an alpha, beta-ethylenically unsaturated carboxylic acid. Also disclosed is a radiation curable composition containing the radiation curable resin in combination with a polymer having a glass transition temperature equal to or higher than minus 17 degrees Celsius selected from an acrylic polymer and a polyester polymer.The radiation curable resins are particularly useful for coatings over non-metallic substrates such as ABS plastics, etc., having an adherent, thin film of metal deposited by vacuum metallizing, sputtering, electroless deposition, electroplating, and the like.

    摘要翻译： 公开了一种未凝胶化的可辐射固化树脂，其是（a）分子量小于或等于1,000且总官能度等于或大于3的多官能含羟基羧酸的反应产物; （b）有机羟基官能化合物; 和（c）α，β-烯属不饱和羧酸。 还公开了含有可辐射固化树脂与具有等于或高于零摄氏度的玻璃化转变温度选自丙烯酸聚合物和聚酯聚合物的聚合物组合的可辐射固化组合物。 可辐射固化树脂特别适用于非金属基材例如ABS塑料等上的涂层，其具有通过真空金属化，溅射，无电沉积，电镀等沉积的粘附的薄膜。

    Amide-modified urethane acrylate radiation curable compounds and coating compositions and methods of making same
    10.
    发明授权
    Amide-modified urethane acrylate radiation curable compounds and coating compositions and methods of making same 失效
    酰胺改性的氨基甲酸酯丙烯酸酯可辐射固化化合物和涂料组合物及其制备方法

    公开(公告)号：US4153776A

    公开(公告)日：1979-05-08

    申请号：US890895

    申请日：1978-03-28

    申请人： Charles B. Friedlander ,  Gerald W. Gruber ,  Rostyslaw Dowbenko

    发明人： Charles B. Friedlander ,  Gerald W. Gruber ,  Rostyslaw Dowbenko

    IPC分类号： C08F2/00 ,  C08F2/48 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/67 ,  C08G18/68 ,  C09D175/14 ,  G03F7/038 ,  C08G18/04

    CPC分类号： G03F7/038 ,  C08F299/06 ,  C08G18/672 ,  Y10S525/92

    摘要： Radiation curable compounds are disclosed comprising an amide moiety, a urethane moiety and an ethylenically unsaturated functional group, typically an acrylate functional group. The compounds comprise the reaction products of an amide-containing compound having at least one hydroxy functional group, a polyisocyanate and a polyfunctional compound having a hydroxy functional group reactive with an isocyanato group of the polyisocyanate, which polyfunctional compound provides an ethylenic functional group in the reaction product. Coating compositions containing these radiation curable reaction products cure at relatively high rates to form films having high abrasion resistance and improved tensile strength and elongation properties as compared to conventional urethane acrylate coating compositions.

    摘要翻译： 公开了可辐射固化的化合物，其包含酰胺部分，氨基甲酸酯部分和烯键式不饱和官能团，通常为丙烯酸酯官能团。 该化合物包括具有至少一个羟基官能团的含酰胺化合物，多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的羟基官能团的多官能化合物的反应产物，该多官能化合物在其中提供烯属官能团 反应产物。 含有这些可辐射固化反应产物的涂料组合物相对于常规氨基甲酸酯丙烯酸酯涂料组合物相对较高的速率固化，以形成具有高耐磨性和改进的拉伸强度和伸长性能的薄膜。