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    6-(biphenyl-ester)-3H-naphtho[2,1-b]pyrans as photochromic dichroic dyes and optical article containing them
    3.
    发明授权
    6-(biphenyl-ester)-3H-naphtho[2,1-b]pyrans as photochromic dichroic dyes and optical article containing them 有权
    6-（联苯基酯）-3H-萘并[2,1-b]吡喃，为光致变色二色性染料，含有它们的光学制品

    公开(公告)号：US08436184B2

    公开(公告)日：2013-05-07

    申请号：US12439324

    申请日：2007-09-05

    申请人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron

    发明人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron

    IPC分类号： C07D401/00

    CPC分类号： C07D311/92 ,  C07D405/10 ,  C07D455/04

    摘要： A naphthopyran compound represented by the formula (I) wherein: n1, n2, p, m and q represent an integer; R1, R2 and R4, represent a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —NRbRc, —CO—Ra, —CO2Ra1, —OC(O)—Rd, —X—(Re)—Y, linear or branched (C1-C18) perfluoroalkyl group, wherein Ra, Ra1, Rb, Rc, X, Y, Re, and Rd are as defined in the description; Z represents a group selected from CO, CS, SO, SO2, CO2, C(O)S, CS2, C(O)NH, C(O)NRa, C(S)NH, C(S)NRa and C═NRa; R3 represents a group selected from halogen, —Ra, linear or branched (C1-18) perfluoroalkyl group —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1; R6 represents a group selected from —Ra which may be optionally substituted, linear or branched (C1-18) perfluoroalkyl, cycloalkyl, heterocycloalkyl, aryl, and heteroaryl, which may be optionally substituted; R5 represents a group selected from: halogen, —Ra, linear or branched (C1-18) perfluoroalkyl group, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —CO—Ra, —O—C(O)—Ra and —CO2Ra1; or when q is equal to 2, then two R5 together represents further a group —O—(CH2)q1—O— wherein q1 represents an integer comprised from 1 to 3 inclusive.

    摘要翻译： 由式（I）表示的萘并吡喃化合物，其中：n1，n2，p，m和q表示整数; R1，R2和R4表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-NRbRc，-CO-Ra，-CO2Ra1，-OC（O） -Rd，-X-（Re）-Y，直链或支链（C1-C18）全氟烷基，其中Ra，Ra1，Rb，Rc，X，Y，Re和Rd如说明书中所定义; Z表示选自CO，CS，SO，SO 2，CO 2，C（O）S，CS 2，C（O）NH，C（O）NR a，C（S）NH，C（S）NR a和C = NRa; R 3表示选自卤素，-R a，直链或支链（C1-18）全氟烷基-OH，-ORa，-SH，-SRa，-NH2和-NRaRa1的基团; R 6表示选自-R a的基团，其可以是任选取代的，可以被任选取代的直链或支链（C1-18）全氟烷基，环烷基，杂环烷基，芳基和杂芳基; R5代表选自：卤素，-Ra，直链或支链（C1-18）全氟烷基，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-CO-Ra，-OC（O ）-Ra和-CO2Ra1; 或当q等于2时，则两个R 5一起进一步表示-O-（CH 2）q1-O-基团，其中q1表示包含1至3的整数。

    3H-naphtho [2,1-B] pyrans as photochromic dichroic dyes and optical article containing them
    5.
    发明授权
    3H-naphtho [2,1-B] pyrans as photochromic dichroic dyes and optical article containing them 有权
    3H-萘并[2,1-B]吡喃作为光致变色二色性染料和含有它们的光学制品

    公开(公告)号：US09249136B2

    公开(公告)日：2016-02-02

    申请号：US12439738

    申请日：2006-09-06

    申请人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron ,  Tamas Kosa ,  Linli Su ,  Ludmila Sukhomlinova ,  Bahman Taheri

    发明人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron ,  Tamas Kosa ,  Linli Su ,  Ludmila Sukhomlinova ,  Bahman Taheri

    IPC分类号： G02B5/23 ,  C07D471/04 ,  C07D311/92 ,  C07D405/10 ,  C07D455/04 ,  G02F1/03 ,  G02F1/07 ,  C07D401/00

    CPC分类号： C07D471/04 ,  C07D311/92 ,  C07D405/10 ,  C07D455/04

    摘要： A naphthopyran compound represented by the formula (I): wherein: n1, n2, p, q is an integer comprised from 0 to 5 inclusive; m is an integer comprised from 0 to 4 inclusive; R1 and R2 represent a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —NRbRc, —CO—Ra, and —CO2Ra1, wherein Ra, Ra1, Rb and Rc, are as defined in the description; R3 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1; R4 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —CO—Ra, and —CO2Ra1; R5 represents a group selected from: halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1, wherein Ra and Ra1 are as defined hereinbefore, or when q is equal to 2, then two R5 together represent further a group —O—(CH2)q1—O— wherein q1 represents an integer comprised from 1 to 3 inclusive.

    摘要翻译： 由式（I）表示的萘并吡喃化合物：其中：n1，n2，p，q为0〜5的整数， m为0〜4的整数， R1和R2表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-NRbRc，-CO-Ra和-CO2Ra1的基团，其中Ra，Ra1，Rb和 Rc，如说明书中所定义; R 3表示选自卤素，-R a，-OH，-OR a，-SH，-SR a，-NH 2和-NR a R 1a的基团; R4表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-CO-Ra和-CO2Ra1的基团; R5表示选自：卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2和-NRaRa1的基团，其中Ra和Ra1如上所定义，或当q等于2时，则两个 R5一起进一步表示-O-（CH 2）q1-O-基团，其中q1表示包含1至3的整数。

    Grey coloring photochromic fused pyrans
    6.
    发明授权
    Grey coloring photochromic fused pyrans 失效
    灰色着色光致变色融合pyrans

    公开(公告)号：US06387512B1

    公开(公告)日：2002-05-14

    申请号：US09787362

    申请日：2001-03-16

    申请人： David Allan Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    发明人： David Allan Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    IPC分类号： C07D31182

    CPC分类号： C07D491/04 ,  C07D311/78 ,  C07D311/92 ,  C07D493/04 ,  C07D495/04 ,  Y10S428/913 ,  Y10T428/31855

    摘要： A photochromic grey coloring 2H-naphtho[1,2-b]pyran of formula (1) wherein R1 is selected from mono-, di- or poly-substituted aryl groups, mono-, di- or poly-substituted naphthyl groups and mono-, di- or poly-substituted heteroaryl groups, wherein at least one substituent is a nitrogen containing group, including amino, C1-C20 and C6-C20 alkylamino, C1-C20 and C6-C20 dialkylamino, C2-C20 dialkenylamino, C2-C20 or C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, tetra (C1-C10 linear or branched alkyl) guanidino and cyclic-amino groups and at least one of R7 and R9, which may be the same or different, is selected from C1-C20 N alkylamino C1-C20 N-alkylamido, C1-C20 N,N-dialkylamido, amido, nitro, amino, C1-C20 alkylamino, C1-C20 dialkylamino, C2-C20 dialkenylamino, C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, or cyclicamino groups. The compounds may be combined with a polymeric host material such as plastic or glass to make a sunglass lens, an ophthalmic lens or a window. The compounds may also be included in an ink or a fuel.

    摘要翻译： 式（1）的光致变色灰色着色2H-萘并[1,2-b]吡喃，其中R1选自单取代，二取代或多取代的芳基，单取代，二取代或多取代的萘​​基和单 其中至少一个取代基是含氮基团，包括氨基，C 1 -C 20和C 6 -C 20烷基氨基，C 1 -C 20和C 6 -C 20二烷基氨基，C 2 -C 20二烯基氨基，C 2 -C 20烷基氨基， C20或C4-C20二（聚链烯基）氨基，芳基氨基，二芳基氨基，C1-C20烷基芳基氨基，四（C1-C10直链或支链烷基）胍基和环氨基以及R7和R9中至少一个可以相同 选自C 1 -C 20 N烷基氨基C 1 -C 20 N-烷基酰氨基，C 1 -C 20 N，N-二烷基酰氨基，酰氨基，硝基，氨基，C 1 -C 20烷基氨基，C 1 -C 20二烷基氨基，C 2 -C 20二烯基氨基， C20二（多烯基）氨基，芳基氨基，二芳基氨基，C 1 -C 20烷基芳基氨基或环氨基。 化合物可以与诸如塑料或玻璃的聚合物主体材料组合以制备太阳镜，眼镜或窗。 化合物也可以包括在油墨或燃料中。

    3H-NAPHTH0 [2,1-B] PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM
    7.
    发明申请
    3H-NAPHTH0 [2,1-B] PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM 有权
    3H-NAPHTH0 [2,1-B] PYRANS作为光致变色二色染料和含有它们的光学物品

    公开(公告)号：US20100202033A1

    公开(公告)日：2010-08-12

    申请号：US12439738

    申请日：2006-09-06

    申请人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron ,  Tamas Kosa ,  Linli Su ,  Ludmila Sukhomlinova ,  Bahman Taheri

    发明人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron ,  Tamas Kosa ,  Linli Su ,  Ludmila Sukhomlinova ,  Bahman Taheri

    IPC分类号： G02F1/03 ,  C07D405/10 ,  C07D471/04 ,  C07D413/10 ,  G02B5/23

    CPC分类号： C07D471/04 ,  C07D311/92 ,  C07D405/10 ,  C07D455/04

    摘要： A naphthopyran compound represented by the formula (I): wherein: n1, n2, p, q is an integer comprised from 0 to 5 inclusive; m is an integer comprised from 0 to 4 inclusive; R1 and R2 represent a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —NRbRc, —CO—Ra, and —CO2Ra1, wherein Ra, Ra1, Rb and Rc, are as defined in the description; R3 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1; R4 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —CO—Ra, and —CO2Ra1; R5 represents a group selected from: halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1, wherein Ra and Ra1 are as defined hereinbefore, or when q is equal to 2, then two R5 together represent further a group —O—(CH2)q1—O— wherein q1 represents an integer comprised from 1 to 3 inclusive.

    摘要翻译： 由式（I）表示的萘并吡喃化合物：其中：n1，n2，p，q为0〜5的整数， m为0〜4的整数， R1和R2表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-NRbRc，-CO-Ra和-CO2Ra1的基团，其中Ra，Ra1，Rb和 Rc，如说明书中所定义; R 3表示选自卤素，-R a，-OH，-OR a，-SH，-SR a，-NH 2和-NR a R 1a的基团; R4表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-CO-Ra和-CO2Ra1的基团; R5表示选自：卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2和-NRaRa1的基团，其中Ra和Ra1如上所定义，或当q等于2时，则两个 R5一起进一步表示-O-（CH 2）q1-O-基团，其中q1表示包含1至3的整数。

    6-(BIPHENYL-ESTER)-3H-NAPHTHO[2,1-B]PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM
    8.
    发明申请
    6-(BIPHENYL-ESTER)-3H-NAPHTHO[2,1-B]PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM 有权
    6-（BIPHENYL-ESTER）-3H-NAPHTHO [2,1-B] PYRANS作为光致变色二色性染料和含有它们的光学物品

    公开(公告)号：US20100039688A1

    公开(公告)日：2010-02-18

    申请号：US12439324

    申请日：2007-09-05

    申请人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron

    发明人： Stuart Aiken ,  Jean-Paul Cano ,  Christopher David Gabbutt ,  Bernard Mark Heron

    IPC分类号： G02F1/17 ,  C07D311/92 ,  C07D405/10 ,  C07D453/00 ,  C08K5/3415 ,  C08K5/3432 ,  C08K5/1545

    CPC分类号： C07D311/92 ,  C07D405/10 ,  C07D455/04

    摘要： A naphthopyran compound represented by the formula (I) wherein: n1, n2, p, m and q represent an integer; R1, R2 and R4, represent a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —NRbRc, —CO—Ra, —CO2Ra1, —OC(O)—Rd, —X—(Re)—Y, linear or branched (C1-C18) perfluoroalkyl group, wherein Ra, Ra1, Rb, Rc, X, Y, Re, and Rd are as defined in the description; Z represents a group selected from CO, CS, SO, SO2, CO2, C(O)S, CS2, C(O)NH, C(O)NRa, C(S)NH, C(S)NRa and C═NRa; R3 represents a group selected from halogen, —Ra, linear or branched (C1-18) perfluoroalkyl group —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1; R6 represents a group selected from —Ra which may be optionally substituted, linear or branched (C1-18) perfluoroalkyl, cycloalkyl, heterocycloalkyl, aryl, and heteroaryl, which may be optionally substituted; R5 represents a group selected from: halogen, —Ra, linear or branched (C1-18) perfluoroalkyl group, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —CO—Ra, —O—C(O)—Ra and —CO2Ra1; or when q is equal to 2, then two R5 together represents further a group —O—(CH2)q1—O— wherein q1 represents an integer comprised from 1 to 3 inclusive.

    摘要翻译： 由式（I）表示的萘并吡喃化合物，其中：n1，n2，p，m和q表示整数; R1，R2和R4表示选自卤素，-Ra，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-NRbRc，-CO-Ra，-CO2Ra1，-OC（O） -Rd，-X-（Re）-Y，直链或支链（C1-C18）全氟烷基，其中Ra，Ra1，Rb，Rc，X，Y，Re和Rd如说明书中所定义; Z表示选自CO，CS，SO，SO 2，CO 2，C（O）S，CS 2，C（O）NH，C（O）NR a，C（S）NH，C（S）NR a和C = NRa; R 3表示选自卤素，-R a，直链或支链（C1-18）全氟烷基-OH，-ORa，-SH，-SRa，-NH2和-NRaRa1的基团; R 6表示选自-R a的基团，其可以是任选取代的，可以被任选取代的直链或支链（C1-18）全氟烷基，环烷基，杂环烷基，芳基和杂芳基; R5表示选自：卤素，-Ra，直链或支链（C1-18）全氟烷基，-OH，-ORa，-SH，-SRa，-NH2，-NRaRa1，-CO-Ra，-O-C （O）-R a和-CO 2 R 1a; 或当q等于2时，则两个R 5一起进一步表示-O-（CH 2）q1-O-基团，其中q1表示包含1至3的整数。

    Photochromic compounds
    9.
    发明授权
    Photochromic compounds 失效
    光致变色化合物

    公开(公告)号：US06303673B1

    公开(公告)日：2001-10-16

    申请号：US09529704

    申请日：2000-06-19

    申请人： David A. Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    发明人： David A. Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    IPC分类号： C07D49810

    CPC分类号： C07D295/135 ,  C07C251/44 ,  G03C1/685

    摘要： A photochromic compound has the formula (I) wherein R1 is selected from the group including substituted amino aryl moieties, substituted cyclic amino aryl moieties and substituted N-indolinoaryl or N-tetrahydroquinolino aryl groups, R3 is selected from the group including linear or branched C1-C20 alkyl, linear or branched C2-C20 alkenyl or polyalkenyl, C2-C20 alkynyl or polyalkynyl, aryl, heteroaryl, linear or branched C1-C20 alkyl aryl, linear or branched C1-C20 alkyl-cycloalkyl or -bicycloalkyl or -tricycloalkyl or substituted -cycloalkyl or -bicycloalkyl or -tricycloalkyl, linear or branched C1-C20 haloalkyl or perhaloalkyl, linear or branched C1-C20 alkoxyalkyl or peralkoxyalkyl, linear or branched C1-C20 alkylthioalkyl or peralkylthioalkyl, linear or branched C1-C20 amino alkyl or peraminoalkyl, C3-C20 cycloalkyl or substituted cycloalkyl, C4-C20 bicycloalkyl or substituted bicycloalkyl, C6-C20 tricycloalkyl or substituted tricycloalkl or linear or branched C1-C20 hydroxyalkyl or perhydroxyalkyl; R4 and R5 which may be the same or different are R3 or R4 and R5 are conjoined to form a spiro linked C3-C20 cyclic system or substituted cyclic system; and wherein R2 and R6 are each selected from R3 or hydrogen, halogen, nitro, nitroso, amino, acetamido, C2-C10 N-alkylamido, alkoxycarbonyl, nitrile, carboxy, hydroxy, aryloxy, C1-C10 alkoxy, a heteroatom which is O or N or S or P which in turn can be bonded either singly or multiply to carbon, oxygen, sulphur or nitrogen, C1-C5 alkoxy or alkylthio or aryl or aryloxy or multiples thereof.

    摘要翻译： 光致变色化合物具有式（I），其中R 1选自包括取代的氨基芳基部分，取代的环氨基芳基部分和取代的N-二吲哚酰基芳基或N-四氢喹啉基芳基，R3选自直链或支链C1 -C 20烷基，直链或支链C 2 -C 20烯基或聚烯基，C 2 -C 20炔基或多炔基，芳基，杂芳基，直链或支链C 1 -C 20烷基芳基，直链或支链C 1 -C 20烷基 - 环烷基或 - 双环烷基或 - 三环烷基或 直链或支链C 1 -C 20卤代烷基或全卤代烷基，直链或支链C 1 -C 20烷氧基烷基或全烷氧基烷基，直链或支链C 1 -C 20烷硫基烷基或全烷硫基烷基，直链或支链C 1 -C 20氨基烷基或全氨基烷基 C 3 -C 20环烷基或取代的环烷基，C 4 -C 20双环烷基或取代的双环烷基，C 6 -C 20三环烷基或取代的三环烷基或直链或支链的C 1 -C 20羟基烷基或 全羟基烷基; 可以相同或不同的R 4和R 5是R 3或R 4和R 5结合形成螺连接的C 3 -C 20环状体系或取代的环状体系; 并且其中R 2和R 6各自选自R 3或氢，卤素，硝基，亚硝基，氨基，乙酰氨基，C 2 -C 10 N-烷基酰氨基，烷氧基羰基，腈，羧基，羟基，芳氧基，C 1 -C 10烷氧基， 或N或S或P，其又可以单独或多重与碳，氧，硫或氮键合，C 1 -C 5烷氧基或烷硫基或芳基或芳氧基或其多个重复键。

    Red coloring hyperchromic 3H-naphtho[2,1-B]pyrans
    10.
    发明授权
    Red coloring hyperchromic 3H-naphtho[2,1-B]pyrans 失效
    红色着色超色3H-萘并[2,1-B]吡喃

    公开(公告)号：US06294112B1

    公开(公告)日：2001-09-25

    申请号：US09402355

    申请日：1999-12-16

    申请人： David A. Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    发明人： David A. Clarke ,  Bernard Mark Heron ,  Christopher David Gabbutt ,  John David Hepworth ,  Steven Michael Partington ,  Stephen Nigel Corns

    IPC分类号： G02B523

    CPC分类号： C07D405/10 ,  C07D311/92

    摘要： Red coloring hyperchromic compounds have the formula: where R1 is H, NR2R3, OR4, SR4 or R7 wherein R2 and R3 are alkyl or carbocyclic groups or together with the nitrogen to which they are attached form a heterocyclic ring; R4 is the same as R1 or is alkyl, perhaloallyl, aryl or heteroaryl; R7 is alkyl, haloalkyl, alkylthio, aryl, arylthio, heteroaryl, halogen, nitrile, carboxylate, ester, nitro, or a carbocyclic or heterocyclic ring fused to faces f, gh, i, j or k; and R5 is a cyclic aminoaryl group, an indolinoaryl group, a tricyclic nitrogen heterocycle, or an unsaturated cyclic aminoaryl group.

    摘要翻译： 红色着色增色化合物具有下式：其中R 1是H，NR 2 R 3，OR 4，SR 4或R 7，其中R 2和R 3是烷基或碳环基或与它们所连接的氮一起形成杂环; R4与R1相同或为烷基，全卤代烯丙基，芳基或杂芳基; R 7为与f，gh，i，j或k面融合的烷基，卤代烷基，烷硫基，芳基，芳硫基，杂芳基，卤素，腈，羧酸酯，酯，硝基或碳环或杂环; 并且R 5是环状氨基芳基，二氢吲哚基，三环氮杂环或不饱和环氨基芳基。