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1.发明授权Hot-formable and recyclable epoxy anhydride thermosetting resins and thermosetting composites 有权热成型和可回收环氧酐热固性树脂和热固性复合材料公开(公告)号：US09562132B2
公开(公告)日：2017-02-07
申请号：US13981401
申请日：2012-01-23
IPC分类号： C08L63/02 , C08L63/04 , C08G59/68 , B29B17/00 , B29B17/04 , C08G59/42 , C08L63/00 , B29K101/10
CPC分类号： C08G59/685 , B29B17/0042 , B29B17/0404 , B29K2101/10 , C08G59/42 , C08L63/00 , C08L63/04 , Y02W30/62 , Y02W30/625
摘要： Thermosetting resins and thermosetting composites comprising the thermosetting resins are hot-formable. The compositions result from contacting at least one thermosetting resin precursor with at least one hardener selected from acid anhydrides in the presence of at least one transesterification catalyst. The thermosetting resin precursor includes hydroxyl functions and/or epoxy groups, and optionally ester functions, and the total molar quantity of the transesterification catalyst is between 5 and 25% of the total molar quantity of hydroxyl and epoxy contained in the thermosetting resin precursor. Methods for manufacturing articles comprising the thermosetting resins and methods for recycling the thermosetting resins are also disclosed.
摘要翻译： 包含热固性树脂的热固性树脂和热固性复合材料是可热成型的。 组合物是由至少一种热固性树脂前体与至少一种选自酸酐的硬化剂在至少一种酯交换催化剂存在下接触而得到的。 热固性树脂前体包括羟基官能团和/或环氧基团以及任选的酯官能团，并且酯交换催化剂的总摩尔量在热固性树脂前体中所含的羟基和环氧化物的总摩尔量的5至25％之间。 还公开了制造包含热固性树脂的制品的方法和再循环热固性树脂的方法。
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2.发明申请HOT-FORMABLE AND RECYCLABLE EPOXY ANHYDRIDE THERMOSETTING RESINS AND THERMOSETTING COMPOSITES 有权热塑性环氧树脂和可回热的环氧树脂热固性树脂和热固性复合材料公开(公告)号：US20130300020A1
公开(公告)日：2013-11-14
申请号：US13981401
申请日：2012-01-23
IPC分类号： C08G59/68
CPC分类号： C08G59/685 , B29B17/0042 , B29B17/0404 , B29K2101/10 , C08G59/42 , C08L63/00 , C08L63/04 , Y02W30/62 , Y02W30/625
摘要： Thermosetting resins and thermosetting composites comprising the thermosetting resins are hot-formable. The compositions result from contacting at least one thermosetting resin precursor with at least one hardener selected from acid anhydrides in the presence of at least one transesterification catalyst. The thermosetting resin precursor includes hydroxyl functions and/or epoxy groups, and optionally ester functions, and the total molar quantity of the transesterification catalyst is between 5 and 25% of the total molar quantity of hydroxyl and epoxy contained in the thermosetting resin precursor. Methods for manufacturing articles comprising the thermosetting resins and methods for recycling the thermosetting resins are also disclosed.
摘要翻译： 包含热固性树脂的热固性树脂和热固性复合材料是可热成型的。 组合物是由至少一种热固性树脂前体与至少一种选自酸酐的硬化剂在至少一种酯交换催化剂存在下接触而得到的。 热固性树脂前体包括羟基官能团和/或环氧基团以及任选的酯官能团，并且酯交换催化剂的总摩尔量在热固性树脂前体中所含的羟基和环氧化物的总摩尔量的5至25％之间。 还公开了制造包含热固性树脂的制品的方法和再循环热固性树脂的方法。
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3.发明授权Thermoset/supramolecular hybrid composites and resins that can be hot-formed and recycled 有权热固性/超分子混合复合材料和树脂，可以热成型和回收利用公开(公告)号：US09359467B2
公开(公告)日：2016-06-07
申请号：US14116541
申请日：2012-05-10
IPC分类号： B29B17/04 , B29B17/00 , B29B13/10 , B29C67/24 , C08L67/00 , C08G59/42 , C08G83/00 , C08L63/00 , C08G59/14 , C08L67/08 , B29K63/00 , B29K105/24
CPC分类号： C08G59/1477 , B29B17/00 , B29C67/24 , B29K2063/00 , B29K2105/24 , C08G59/42 , C08G83/008 , C08L63/00 , C08L67/08 , Y02W30/62
摘要： Thermoset/supramolecular hybrid composites and resins, resulting from bringing at least one thermosetting resin precursor, this thermosetting resin precursor including hydroxyl functions and/or epoxy groups, and optionally ester functions, into contact with at least one hardener chosen from carboxylic acids and acid anhydrides, and with at least one compound including, on the one hand, at least one associative group, and on the other hand at least one function enabling the grafting thereof to the thermosetting resin precursor, to the hardener or to the product resulting from the reaction of the thermosetting resin precursor and the hardener, in the presence of at least one transesterification catalyst. Process for manufacturing these materials, process for transforming and process for recycling these materials. Novel solid forms of hybrid composites and resins which can be used in the implementation of these processes.
摘要翻译： 通过使至少一种热固性树脂前体，包含羟基官能团和/或环氧基的热固性树脂前体和任选的酯官能团与至少一种选自羧酸和酸酐的固化剂接触而得到的热固性/超分子复合材料和树脂 和至少一种化合物，一方面包括至少一个缔合基团，另一方面包括至少一种能够将其接枝到热固性树脂前体上的功能，由固化剂或由反应产生的产物 的热固性树脂前体和硬化剂，在至少一种酯交换催化剂的存在下。 制造这些材料的方法，用于转化和处理这些材料的方法。 混合复合材料和树脂的新型固体形式可用于实施这些工艺。
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4.发明申请THERMOSET/SUPRAMOLECULAR HYBRID COMPOSITES AND RESINS THAT CAN BE HOT-FORMED AND RECYCLED 有权热固性/分子混合复合材料和树脂可以被成型和回收公开(公告)号：US20140088223A1
公开(公告)日：2014-03-27
申请号：US14116541
申请日：2012-05-10
CPC分类号： C08G59/1477 , B29B17/00 , B29C67/24 , B29K2063/00 , B29K2105/24 , C08G59/42 , C08G83/008 , C08L63/00 , C08L67/08 , Y02W30/62
摘要： Thermoset/supramolecular hybrid composites and resins, resulting from bringing at least one thermosetting resin precursor, this thermosetting resin precursor comprising hydroxyl functions and/or epoxy groups, and optionally ester functions, into contact with at least one hardener chosen from carboxylic acids and acid anhydrides, and with at least one compound comprising, on the one hand, at least one associative group, and on the other hand at least one function enabling the grafting thereof to the thermosetting resin precursor, to the hardener or to the product resulting from the reaction of the thermosetting resin precursor and the hardener, in the presence of at least one transesterification catalyst. Process for manufacturing these materials, process for transforming and process for recycling these materials. Novel solid forms of hybrid composites and resins which can be used in the implementation of these processes.
摘要翻译： 由将至少一种热固性树脂前体引入的热固性/超分子混合复合材料和树脂，该热固性树脂前体包含羟基官能团和/或环氧基团以及任选的酯官能团与至少一种选自羧酸和酸酐的固化剂接触 和至少一种化合物，一方面包含至少一个缔合基团，另一方面包括至少一种能够将其接枝到热固性树脂前体上的功能，由固化剂或由反应产生的产物 的热固性树脂前体和硬化剂，在至少一种酯交换催化剂的存在下。 制造这些材料的方法，用于转化和处理这些材料的方法。 混合复合材料和树脂的新型固体形式可用于实施这些工艺。
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5.发明授权Epoxy acid thermoset resins and composites that can be hot-fashioned and recycled 有权环氧酸热固性树脂和可热塑回收的复合材料公开(公告)号：US09266292B2
公开(公告)日：2016-02-23
申请号：US13118536
申请日：2011-05-30
CPC分类号： B29C73/02 , B29C73/163 , B29K2063/00 , C08G59/4207 , C08L63/00 , C09D163/00
摘要： Resins and thermoset composites comprising them, these materials being able to be hot-fashioned. These compositions resulting from placing at least one thermosetting resin precursor, this thermosetting resin precursor comprising hydroxyl functions and/or epoxy groups, and optionally ester functions, in contact with at least one hardener chosen from carboxylic acids, in the presence of at least one transesterification catalyst whose total molar amount is between 5% and 25% of the total molar amount of hydroxyl and epoxy contained in the thermosetting resin precursor. Process for manufacturing these materials, process for transforming and process for recycling these materials. New solid forms of resins and of thermoset composites that may be used in the implementation of these processes.
摘要翻译： 树脂和包含它们的热固性复合材料，这些材料能够被热成型。 这些组合物是通过将至少一种热固性树脂前体，该羟基官能团和/或环氧基的热固性树脂前体以及任选的酯官能团与至少一种选自羧酸的硬化剂在至少一种酯交换 催化剂，其总摩尔量为热固性树脂前体中含有的羟基和环氧化物的总摩尔量的5％至25％。 制造这些材料的方法，用于转化和处理这些材料的方法。 新的固体形式的树脂和热固性复合材料可用于实施这些工艺。
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公开(公告)号：US08536281B2
公开(公告)日：2013-09-17
申请号：US12991181
申请日：2009-05-05
CPC分类号： C08G83/008 , C08G69/26 , C08G69/28 , C08G69/34
摘要： The present invention relates to a method for synthesizing a supramolecular material comprising: 1—the reaction of at least one carboxylic diacid, or ester or chloride of such a diacid, with, on the one hand, at least one modifier compound bearing both reactive functional groups capable of reacting with the carboxylic acid, ester or acid chloride functional groups and associative groups capable of associating with one another by hydrogen bonds, in a molar ratio of the reactive functional groups to the carboxylic acid, ester or acid chloride functional groups of between 0.10 and 0.50, and, on the other hand, at least one polyamine, said reactions being carried out successively or simultaneously, and 2—the reaction of the polyamide obtained at the end of step 1 with urea. The present invention also relates to the resulting material, and also to the uses thereof.
摘要翻译： 本发明涉及一种合成超分子材料的方法，其包括：1-至少一种羧酸二酸或这种二酸的酯或氯化物与至少一种具有反应性官能团 能够与羧酸，酯或酰氯官能团和能够通过氢键彼此结合的缔合基团反应的基团，反应性官能团与羧酸，酯或酰氯官能团的摩尔比在 0.10和0.50，另一方面是至少一种多胺，所述反应相继或同时进行，和2-步骤1结束时得到的聚酰胺与尿素的反应。 本发明还涉及所得到的材料，以及其用途。
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7.发明申请Epoxy Acid Thermoset Resins and Composites that Can Be Hot-Fashioned and Recycled 有权环氧酸热固性树脂和可复制的复合材料公开(公告)号：US20110319524A1
公开(公告)日：2011-12-29
申请号：US13118536
申请日：2011-05-30
CPC分类号： B29C73/02 , B29C73/163 , B29K2063/00 , C08G59/4207 , C08L63/00 , C09D163/00
摘要： Resins and thermoset composites comprising them, these materials being able to be hot-fashioned. These compositions resulting from placing at least one thermosetting resin precursor, this thermosetting resin precursor comprising hydroxyl functions and/or epoxy groups, and optionally ester functions, in contact with at least one hardener chosen from carboxylic acids, in the presence of at least one transesterification catalyst whose total molar amount is between 5% and 25% of the total molar amount of hydroxyl and epoxy contained in the thermosetting resin precursor. Process for manufacturing these materials, process for transforming and process for recycling these materials. New solid forms of resins and of thermoset composites that may be used in the implementation of these processes.
摘要翻译： 树脂和包含它们的热固性复合材料，这些材料能够被热成型。 这些组合物是通过将至少一种热固性树脂前体，该羟基官能团和/或环氧基的热固性树脂前体以及任选的酯官能团与至少一种选自羧酸的硬化剂在至少一种酯交换 催化剂，其总摩尔量为热固性树脂前体中含有的羟基和环氧化物的总摩尔量的5％至25％。 制造这些材料的方法，用于转化和处理这些材料的方法。 新的固体形式的树脂和热固性复合材料可用于实施这些工艺。
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公开(公告)号：US20110059280A1
公开(公告)日：2011-03-10
申请号：US12991181
申请日：2009-05-05
CPC分类号： C08G83/008 , C08G69/26 , C08G69/28 , C08G69/34
摘要： The present invention relates to a method for synthesizing a supramolecular material comprising: 1—the reaction of at least one carboxylic diacid, or ester or chloride of such a diacid, with, on the one hand, at least one modifier compound bearing both reactive functional groups capable of reacting with the carboxylic acid, ester or acid chloride functional groups and associative groups capable of associating with one another by hydrogen bonds, in a molar ratio of the reactive functional groups to the carboxylic acid, ester or acid chloride functional groups of between 0.10 and 0.50, and, on the other hand, at least one polyamine, said reactions being carried out successively or simultaneously, and 2—the reaction of the polyamide obtained at the end of step 1 with urea. The present invention also relates to the resulting material, and also to the uses thereof.
摘要翻译： 本发明涉及一种合成超分子材料的方法，其包括：1-至少一种羧酸二酸或这种二酸的酯或氯化物与至少一种具有反应性官能团 能够与羧酸，酯或酰氯官能团和能够通过氢键彼此结合的缔合基团反应的基团，反应性官能团与羧酸，酯或酰氯官能团的摩尔比在 0.10和0.50，另一方面是至少一种多胺，所述反应相继或同时进行，和2-步骤1结束时得到的聚酰胺与尿素的反应。 本发明还涉及所得到的材料，以及其用途。
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