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1.发明授权Process for preparing polyamides comprising fluoroether functionalized aromatic moieties 失效包含氟醚官能化芳族部分的聚酰胺的制备方法公开(公告)号：US08697831B2
公开(公告)日：2014-04-15
申请号：US13166052
申请日：2011-06-22
CPC分类号： C08G69/42
摘要： The invention is directed to a process for preparing polyamide polymers, particularly nylon 6, 6 and nylon 6, comprising fluoroether functionalized aromatic repeat units. In one embodiment, 1,6 diaminohexane, adipic acid, and fluoroether functionalized terephthallic or isophthallic acid or diester are reacted to form a polymer. The polymers so formed are useful for imparting soil resistance to polyamides, particularly in the form of films, molded parts, fibers, fabrics, and carpets.
摘要翻译： 本发明涉及一种制备聚酰胺聚合物，特别是尼龙6和尼龙6的方法，其包括氟醚官能化芳族重复单元。 在一个实施方案中，使1,6二氨基己烷，己二酸和氟代醚官能化的对苯二酚或异酞酸或二酯反应形成聚合物。 如此形成的聚合物可用于赋予聚酰胺的耐污性，特别是以薄膜，模制件，纤维，织物和地毯的形式。
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2.发明授权Shaped articles fabricated from polyamides comprising fluoroether functionalized aromatic moieties 有权由包含氟醚官能化芳族部分的聚酰胺制成的成型制品公开(公告)号：US08247519B1
公开(公告)日：2012-08-21
申请号：US13166069
申请日：2011-06-22
CPC分类号： C08G69/26 , C08L77/06 , Y10T428/28 , Y10T428/2978
摘要： The invention is directed to shaped articles fabricated from polyamides comprising fluoroether functionalized aromatic moieties. Particular polyamides include nylon 6, 6 and nylon 6 copolyamides that comprise fluoroether functionalized aromatic amide repeat units. The shaped articles hereof are characterized by reduced surface tension and are useful for imparting soil resistant films, molded parts, fibers, fabrics, and carpets.
摘要翻译： 本发明涉及由包含氟醚官能化芳族部分的聚酰胺制成的成型制品。 特殊的聚酰胺包括包含氟醚官能化芳族酰胺重复单元的尼龙6,6和尼龙6共聚酰胺。 本发明的成形制品的特征在于表面张力降低，可用于赋予防污膜，模制件，纤维，织物和地毯。
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公开(公告)号：US07592413B2
公开(公告)日：2009-09-22
申请号：US11517848
申请日：2006-09-08
IPC分类号： C08G63/00
CPC分类号： C08G63/78 , C08G63/19 , C08G63/605 , C08G63/785
摘要： Aromatic polyesters are made in a continuous process in an extruder or extruder-like apparatus by reacting at elevated temperatures dicarboxylic acids, aliphatic esters of aromatic diols, and optionally aliphatic esters of aromatic hydroxyacids in an extruder while removing byproduct aliphatic carboxylic acid. The resulting aromatic polyesters, especially thermotropic liquid crystalline aromatic polyesters, are useful as molding resins for a variety of uses, for example electronic and electrical parts.
摘要翻译： 芳族聚酯在挤出机或类似挤出机的设备中通过在挤出机中在升高的温度下使二羧酸，芳族二醇的脂肪族酯和任选的芳族羟基酸的脂肪族酯反应，同时除去副产物脂肪族羧酸而在连续方法中制备。 得到的芳族聚酯，特别是热致液晶芳族聚酯，可用作各种用途的模制树脂，例如电子和电气部件。
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4.发明授权Method for manufacturing poly(hexamethylene adipamide) from monomethyladipate and hexamethylenediamine 失效从己二酸单己酯和己二胺制造聚（己二酰己二胺）的方法
公开(公告)号：US6011134A
公开(公告)日：2000-01-04
申请号：US16385
申请日：1998-01-30
摘要： An improved method for manufacturing poly(hexamethylene adipamide), i.e. nylon 6,6, by reacting monomethyl adipate with hexamethylenediamine in an approximately equimolar ratio in the presence of water at a temperature of 100 to 165.degree. C. while simultaneous distilling off of a stoichiometric amount of methanol. The resulting aqueous intermediate product is then heated to 200 to 260.degree. C. while distilling off substantially all water at a pressure of 150 to 250 psig (1.03 .times.10.sup.6 to 1.72 .times.10.sup.6 Pa) followed by reducing the pressure to atmospheric pressure and increasing the temperature to 270 to 280.degree. C. to polycondense the distillate residue. Such a process is useful in producing high purity commercial grade poly(hexamethylene adipamide) that advantageously avoids problems caused by N-methylation of the polyamide.
摘要翻译： 在100至165℃的温度存在下，通过使己二酸单甲酯与己二胺以大约等摩尔比反应制备聚（己二酰己二胺）（即尼龙6,6）的改进方法，同时蒸馏出化学计量 甲醇量。 然后将所得水性中间产物加热至200至260℃，同时在150至250psig（1.03×10 6至1.72×10 6 Pa）的压力下蒸馏出基本上所有的水，然后将压力降至大气压并将温度升至 270〜280℃，使馏出物残渣缩聚。 这种方法可用于生产高纯度商业级聚（己二酰己二胺），其有利地避免了由聚酰胺的N-甲基化引起的问题。
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公开(公告)号：US6103863A
公开(公告)日：2000-08-15
申请号：US217797
申请日：1998-12-22
摘要： A two-step process for the production of polyamides from .alpha.,.omega.-dinitriles and .alpha.,.omega.-diamines involving the catalytic hydrolysis of the .alpha.,.omega.-dinitrile by addition of water with simultaneous purging of the reactor (i.e., venting of ammonia and water vapor) in the first step followed by polymerization by addition of the .alpha.,.omega.-diamine to the hydrolysate in the second step. Such a process is particularly useful in the production of poly(hexamethylene adipamide), i.e., nylon 6,6, from adiponitrile and hexamethylene diamine using lower catalyst levels during hydrolysis and resulting in reduced levels of bis(hexamethylene)triamine, BHMT, in the polymer.
摘要翻译： 用于从α，ω-二腈和α，ω-二胺生产聚酰胺的两步法，其涉及通过加入水同时净化反应器来催化水解α，ω-二腈（即，排出氨和 水蒸气），然后通过在第二步中向水解产物中加入α，ω-二胺进行聚合。 这样的方法特别可用于在水解期间使用较低催化剂水平从己二腈和六亚甲基二胺生产聚（己二酰己二胺），即尼龙6,6，并导致双（六亚甲基）三胺BHMT的水平降低 聚合物。
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公开(公告)号：US20100102467A1
公开(公告)日：2010-04-29
申请号：US12582741
申请日：2009-10-21
IPC分类号： B29B9/10
CPC分类号： B29B9/065
摘要： In an improved polymer melt cutter a gas is added to the cooling liquid before the cooling liquid enters the cutting chamber, or is added directly through the cutting chamber wall. This forms a cooling liquid/gas mixture in the cutting chamber, which has the advantage of providing easier startups, lower operating costs, and other advantages. Processes associated with the improved polymer melt cutter are also disclosed.
摘要翻译： 在改进的聚合物熔融切割机中，在冷却液进入切割室之前，将气体加入到冷却液中，或直接通过切割室壁加入。 这在切割室中形成冷却液/气体混合物，这具有提供更容易的启动，降低运行成本和其它优点的优点。 还公开了与改进的聚合物熔体切割机相关的工艺。
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公开(公告)号：US5955569A
公开(公告)日：1999-09-21
申请号：US757310
申请日：1996-11-27
CPC分类号： C08G69/30 , Y02P20/584
摘要： An improved method for increasing the relative viscosity and molecular weight of a polyamide polymer (such as nylon 6,6, nylon 6, and the like) while in the solid state involving the use of a phosphorus-containing catalyst (such as 2(2'-pyridyl) ethyl phosphonic acid or the like) in combination with an oxygen free gas characterized by a low dew point (typically below 30.degree. C. and preferably below -30.degree. C.). The combination of affording commercial operation at greater through put at lower temperature. Such a process is of particular value during the production of terpolyamide and multipolyamide polymer intended for use in colored nylon fiber manufacture.
摘要翻译： 在涉及使用含磷催化剂的固体状态（例如2（2））中，提高聚酰胺聚合物（例如尼龙6,6，尼龙6等）的相对粘度和分子量的改进方法 乙基膦酸等）与无氧气体组合，其特征在于低露点（通常低于30℃，优选低于-30℃）。 通过在较低温度下提供商业运作的组合。 在制造用于着色尼龙纤维制造中的三聚酰胺和多聚酰胺聚合物的生产期间，这种方法是特别有价值的。
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8.发明授权Process for the hydrolysis of adiponitrile and the production of nylon 6,6 utilizing low catalyst levels 有权用于水解己二腈的方法和利用低催化剂水平生产尼龙6,66
公开(公告)号：US6084056A
公开(公告)日：2000-07-04
申请号：US217799
申请日：1998-12-22
摘要： A process for the hydrolysis of a dinitrile (e.g., adiponitrile) utilizing from 0.1 to 500 mmoles of catalyst (e.g., a mixture of phosphorous acid and calcium hypophosphite) per mole of the dinitrile and in the presence of from 0.01 to 0.5 moles of a dicarboxylic acid cocatalyst (e.g., adipic acid) followed by addition of a diamine (e.g., hexamethylenediamine) and heating to produce polymerization. Such a process is particularly useful in the production of nylon 6,6 having a low BHMT content and improved melt stability.
摘要翻译： 使用0.1至500mmol催化剂（例如，亚磷酸和次亚磷酸钙的混合物）/每摩尔二腈水解二腈（例如己二腈）并在0.01至0.5摩尔的 二羧酸助催化剂（如己二酸），然后加入二胺（如六亚甲基二胺）并加热以产生聚合反应。 这种方法在具有低BHMT含量和改进的熔体稳定性的尼龙6,6的生产中特别有用。
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公开(公告)号：US6069228A
公开(公告)日：2000-05-30
申请号：US135225
申请日：1998-08-17
申请人： Albert Walter Alsop , Elwood Neal Blanchard , Jeffrey D. Cohen , John Maurice Iwasyk , Clara Young Lin , David Neil Marks , Jan M. Stouffer
发明人： Albert Walter Alsop , Elwood Neal Blanchard , Jeffrey D. Cohen , John Maurice Iwasyk , Clara Young Lin , David Neil Marks , Jan M. Stouffer
摘要： Disclosed is a process for the preparation of polyamide polymers via prepolymer formation in a reactor system comprising a reactor, flasher and separator, crystallization of the prepolymer under controlled temperature conditions and the subsequent conversion of these crystallized prepolymers to high molecular weight polymer.
摘要翻译： 公开了一种在包含反应器，闪蒸器和分离器的反应器系统中通过预聚物形成制备聚酰胺聚合物的方法，预聚物在受控温度条件下结晶，随后将这些结晶的预聚物转化为高分子量聚合物。
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公开(公告)号：US5639819A
公开(公告)日：1997-06-17
申请号：US084246
申请日：1993-07-09
CPC分类号： C08G69/265
摘要： A mouldable reinforced polyamide composition comprising;(a) a polyamide consisting essentially of between about 0.5 and about 99.5 mol. % of aliphatic diamines having 4-12 carbon atoms and a complementary amount of 2-methyl-pentamethylene diamine copolymerized with aliphatic dicarboxylic acids having 6-12 carbon atoms; and(b) a filler in an amount of 0.5 to 200 parts by weight per 100 parts by weight of said polyamide. The polyamide has an RV greater than about 20. Related polyamides, especially in which the acid is 1,12-dodecanedioic acid, are also disclosed. The polyamides may be used in a wide variety of end-uses, including moulding, and exhibit excellent gloss compared with nylon 6,6.
摘要翻译： PCT No.PCT / CA92 / 00011 Sec。 371日期：1993年7月9日 102（e）日期1993年7月9日PCT提交1992年1月8日PCT公布。 第WO92 / 12194号公报 日期1992年7月23日一种可塑增强聚酰胺组合物，其包含： （a）基本上由约0.5至约99.5摩尔组成的聚酰胺。 ％的具有4-12个碳原子的脂肪族二胺和与具有6-12个碳原子的脂族二羧酸共聚的2-甲基 - 戊二胺的互补量; 和（b）相对于100重量份所述聚酰胺为0.5〜200重量份的填料。 聚酰胺的RV大于约20.相关聚酰胺，特别是其中酸是1,12-十二烷二酸，也被公开。 聚酰胺可以用于各种最终用途，包括模塑，并且与尼龙6,6相比表现出优异的光泽度。
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