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1.发明授权Novel polyether polycarbonate block copolymers and polyurethanes prepared therefrom 失效由其制备的新型聚醚聚碳酸酯嵌段共聚物和聚氨酯
公开(公告)号：US4634743A
公开(公告)日：1987-01-06
申请号：US731176
申请日：1985-05-06
申请人： Donald G. Prier
发明人： Donald G. Prier
CPC分类号： C08G18/44 , C08G64/183 , C08G2101/0008
摘要： The invention is a block copolymer useful in the preparation of polyurethanes. The polyether polycarbonate block copolymer comprises(a) the residue of a hydrocarbon or a hydrocarbyloxy hydrocarbon compound containing 3 or more functional groups with active hydrogens;(b) an alkylene polyether, polyamine, polyamide, polyaromatic carbonate, polyester, aromatic polyether, polyimide, polysulfide, polysulfone or polysaccharide block wherein such block is bonded to the residue of each active hydrogen-containing functional group; and(c) a polyether polycarbonate block which comprises ether and carbonate ether units arranged in random order, wherein the polyether polycarbonate blocks are bonded to the blocks defined in (b).
摘要翻译： 本发明是一种可用于制备聚氨酯的嵌段共聚物。 聚醚聚碳酸酯嵌段共聚物包含（a）含有3个或更多个具有活性氢的官能团的烃或烃氧基烃化合物的残基; （b）亚烷基聚醚，聚胺，聚酰胺，聚芳香族碳酸酯，聚酯，芳香族聚醚，聚酰亚胺，多硫化物，聚砜或多糖嵌段，其中该嵌段键合到每个含活性氢的官能团的残基; 和（c）聚醚聚碳酸酯嵌段，其包含随机排列的醚和碳酸酯单元，其中聚醚聚碳酸酯嵌段键合到（b）中定义的嵌段上。
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2.发明授权
公开(公告)号：US4298758A
公开(公告)日：1981-11-03
申请号：US120438
申请日：1980-02-11
申请人： Frank T. Cook , Donald G. Prier
发明人： Frank T. Cook , Donald G. Prier
摘要： Propylene glycol and dipropylene glycol diesters are prepared by reacting dichloropropyl ethers with a carboxylic acid salt, e.g., sodium acetate, and the corresponding carboxlyic acid, e.g., acetic acid. The by-product sodium chloride is insoluble in the acetic acid and easily separated from the reaction mixture. The diesters can be hydrolyzed to their respective glycols.
摘要翻译： 丙二醇和二丙二醇二酯通过使二氯丙基醚与羧酸盐例如乙酸钠和相应的羧酸如乙酸反应来制备。 副产物氯化钠不溶于乙酸，容易与反应混合物分离。 二酯可以水解成它们各自的二醇。
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3.发明授权Process for preparing anti-static polyisocyanate-based polymers via incorporating a polyalkylene carbonate-salt mixture 失效通过加入聚亚烷基碳酸盐 - 盐混合物制备抗静电多异氰酸酯基聚合物的方法
公开(公告)号：US4914150A
公开(公告)日：1990-04-03
申请号：US279468
申请日：1988-12-02
申请人： Donald G. Prier
发明人： Donald G. Prier
CPC分类号： C08K3/0066 , C08G18/44 , C08K3/10
摘要： This invention relates to a process for preparing polyisocyanate-based polymers which have the ability to dissipate static electrical charge. The polymers are rendered semi-conductive by having incorporated into them an anti-static additive which comprises an ionizable metal salt dispersed in a polyalkylene carbonate polyol.
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4.发明授权Removal of alkaline catalysts from polyether polyols and polyalkylene carbonate polyols 失效从聚醚多元醇和聚亚烷基碳酸酯多元醇中除去碱性催化剂
公开(公告)号：US4528364A
公开(公告)日：1985-07-09
申请号：US601877
申请日：1984-04-19
申请人： Donald G. Prier
发明人： Donald G. Prier
摘要： This invention is a method of removing alkaline catalysts from polyether polyols and polyalkylene carbonate polyols which comprises(a) dissolving a polyether polyol or a polyalkylene carbonate polyol in a polar aprotic solvent;(b) contacting the polyether polyol or polyalkylene carbonate polyol solution with a sufficient amount of an adsorbent which adsorbs alkaline catalysts to adsorb the alkaline catalysts, at a temperature of between about -30.degree. C. and 110.degree. C. under conditions such that the adsorbent adsorbs the alkaline catalysts; and(c) physically separating the adsorbent from the polyol solution.
摘要翻译： 本发明是从聚醚多元醇和聚亚烷基碳酸酯多元醇中除去碱性催化剂的方法，其包括（a）将聚醚多元醇或聚亚烷基碳酸酯多元醇溶解在极性非质子溶剂中; （b）在约-30℃至110℃的温度下，使聚醚多元醇或聚亚烷基碳酸酯多元醇溶液与足量的吸附碱性催化剂以吸附碱性催化剂的吸附剂接触， 吸附剂吸附碱性催化剂; 和（c）从多元醇溶液物理分离吸附剂。
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5.发明授权Mixtures of poly(alkylene carbonate) polyols and polymers of ethylenically unsaturated esters 失效聚（碳酸亚烷基酯）多元醇和烯属不饱和酯的聚合物的混合物
公开(公告)号：US4910256A
公开(公告)日：1990-03-20
申请号：US279393
申请日：1988-12-02
申请人： Donald G. Prier
发明人： Donald G. Prier
IPC分类号： C08L33/04 , C08G18/42 , C08G18/44 , C08G18/64 , C08G64/00 , C08G64/02 , C08G64/18 , C08L69/00
CPC分类号： C08L69/00
摘要： Modified mixtures of poly(alkylene carbonate) polyols and polymers of certain unsaturated esters are prepared by (A) forming a mixture of a polymer of an ethylenically unsaturated ester and a polyalkylene carbonate polyol and (B) subjecting such mixture to conditions sufficient to induce a transesterification reaction between the polymer of an acrylic ester and a polyalkylene carbonate polyol.
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6.发明授权Flexible polyurethane foams prepared from poly(alkylene carbonate) polyols 失效由聚（碳酸亚烷基酯）多元醇制备的柔性聚氨酯泡沫
公开(公告)号：US4713399A
公开(公告)日：1987-12-15
申请号：US814850
申请日：1985-12-30
申请人： Daniel D. Webb , Donald G. Prier
发明人： Daniel D. Webb , Donald G. Prier
CPC分类号： C08G18/44 , C08G2101/0008
摘要： In one aspect, this invention is a polyurethane foam which is the reaction product of a reaction mixture comprising a poly(alkylene carbonate) polyol, a silicone surfactant, a blowing agent, and a polyisocyanate.In another aspect, this invention is an active hydrogen-containing composition comprising a poly(alkylene carbonate) polyol having an equivalent weight from about 100 to about 3000, a blowing agent and a silicone surfactant.
摘要翻译： 一方面，本发明是聚氨酯泡沫体，其是包含聚（碳酸亚烷基酯）多元醇，硅氧烷表面活性剂，发泡剂和多异氰酸酯的反应混合物的反应产物。 另一方面，本发明是包含当量重量为约100至约3000的聚（碳酸亚烷基酯）多元醇，发泡剂和硅氧烷表面活性剂的含活性氢的组合物。
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公开(公告)号：US4686274A
公开(公告)日：1987-08-11
申请号：US809675
申请日：1985-12-16
申请人： Robert F. Harris , Donald G. Prier
发明人： Robert F. Harris , Donald G. Prier
CPC分类号： C08G64/00
摘要： A process for modifying a poly(alkylene carbonate) polyahl, which comprises reacting the poly(alkylene carbonate) polyahl, with at least one modifier having at least one active hydrogen moiety or cyclic anhydride, optionally in the presence of a catalyst under transesterification conditions to form a modified poly(alkylene carbonate) polyahl wherein the modifier is chemically bonded to the backbone of the poly(alkylene carbonate) polyahl.
摘要翻译： 一种改性聚（碳酸亚烷基酯）多元醇的方法，其包括使聚（碳酸亚烷基酯）多元醇与至少一种具有至少一个活性氢部分的改性剂或环状酸酐反应，任选在催化剂存在下，在酯交换条件下， 形成改性的聚（碳酸亚烷基酯）多烯烃，其中改性剂与聚（碳酸亚烷基酯）多烯烃的主链化学键合。
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