Separation of lithium chloride from impurities
    3.
    发明授权
    Separation of lithium chloride from impurities 失效
    氯化锂与杂质的分离

    公开(公告)号:US4588565A

    公开(公告)日:1986-05-13

    申请号:US636765

    申请日:1984-08-01

    IPC分类号: C01D15/04

    CPC分类号: C01D15/04

    摘要: Lithium chloride is separated from its mixtures with calcium chloride by preferentially dissolving the lithium chloride in tetrahydrofuran. The separation is achieved since the lithium chloride is soluble in tetrahydrofuran, while the calcium chloride is not. The process is particularly applicable to geothermal brines.

    摘要翻译: 通过优选将氯化锂溶解在四氢呋喃中,将氯化锂与氯化钙的混合物分离。 分离是因为氯化锂可溶于四氢呋喃而氯化钙不溶解。 该方法特别适用于地热盐水。

    Removal of impurites from clay
    6.
    发明授权
    Removal of impurites from clay 失效
    从粘土中去除杂质

    公开(公告)号:US4239735A

    公开(公告)日:1980-12-16

    申请号:US72957

    申请日:1979-09-06

    IPC分类号: C01F7/22

    CPC分类号: C01F7/22

    摘要: A method for producing substantially pure alumina from kaolin clay by removing in a soluble form impurities which contaminate the alumina while the aluminum is maintained in an insoluble form. This is accomplished by leaching calcined kaolin clay with at least 36 weight percent hydrochloric acid to dissolve the impurities and convert the aluminum to insoluble aluminum chloride and maintaining the hydrochloric acid concentration in the leach liquor at at least 36 weight percent by the injection of hydrochloric acid gas. The insoluble aluminum chloride is then separated from the dissolved impurities and subjected to a second leaching step to solubilize and separate it from the silica gangue. Substantially pure AlCl.sub.3.sup.. 6H.sub.2 O crystals are recovered from solution and converted to alumina by conventional means. In an alternate embodiment, the process may be practiced on uncalcined clay and includes the addition of a source of fluoride ions, such as H.sub.2 SiF.sub.6, to the at least 36 weight percent hydrochloric acid leach liquor. An optional preleaching step utilizing 2N to 6N mineral acid is also disclosed.

    摘要翻译: 一种从高岭土生产基本上纯的氧化铝的方法,通过以可溶形式除去在铝保持不溶形式时污染氧化铝的杂质。 这是通过用至少36重量%盐酸的煅烧高岭土浸出来溶解杂质并将铝转化成不溶性氯化铝并通过注入盐酸将浸出液中的盐酸浓度保持在至少36重量%来实现的 加油站。 然后将不溶性氯化铝与溶解的杂质分离,并进行第二浸出步骤以溶解并将其与二氧化硅g石分离。 从溶液中回收基本纯的AlCl3.6H2O晶体,并通过常规方法转化为氧化铝。 在一个替代实施方案中,该方法可以在未煅烧的粘土上实施,并且包括向至少36重量%的盐酸浸出液中加入氟离子源,例如H 2 SiF 6。 还公开了使用2N至6N无机酸的任选的预漂洗步骤。

    Production of alumina from aluminum nitrate solutions
    8.
    发明授权
    Production of alumina from aluminum nitrate solutions 失效
    由硝酸铝溶液生产氧化铝

    公开(公告)号:US4260589A

    公开(公告)日:1981-04-07

    申请号:US56151

    申请日:1979-07-10

    IPC分类号: C01F7/34 C01F7/24 C01F7/30

    CPC分类号: C01F7/34

    摘要: Aluminum nitrate solutions are subjected to hydrolysis at elevated temperature and pressure, with the pressure being kept relatively low by continual bleeding of reactant gases from the reaction vessel. The resultant product is a noncrystalline alumina that may be readily converted to crystalline alumina by roasting.In addition, the discharged reactant gases are employed for leaching of clay to provide aluminum nitrate feed solution.

    摘要翻译: 硝酸铝溶液在升高的温度和压力下进行水解,通过来自反应容器的反应物气体的持续渗出,压力保持相对较低。 所得产物是非结晶氧化铝,其可以通过焙烧容易地转化为结晶氧化铝。 此外,排出的反应气体用于浸出粘土以提供硝酸铝进料溶液。