公开(公告)号：US4246169A

公开(公告)日：1981-01-20

申请号：US897614

申请日：1978-04-19

申请人： Robert D. Norris ,  E. Robert Fretz, Jr. ,  Harry H. Beacham

发明人： Robert D. Norris ,  E. Robert Fretz, Jr. ,  Harry H. Beacham

IPC分类号： C09K21/12 ,  C07F9/12 ,  C08G61/00 ,  C08G79/00 ,  C08G79/02 ,  C08G79/04 ,  C08L33/00 ,  C08L33/02 ,  C08L65/00 ,  C08L67/00 ,  C08L85/02 ,  C08L101/00 ,  C09K21/14 ,  C08K5/13 ,  C07F9/09

CPC分类号： C07F9/12 ,  C08G79/04 ,  C08L101/00 ,  C08L85/02

摘要： This invention relates to flame-retardant phosphorus-containing materials, particularly suitable for use as an additive, having little or no plasticizing effect, in flammable organic plastics. One such material may be made by reacting methallyl chloride with phenol or phenol-isopropylphenol blend and then phosphorylating. Another such material may be made by halogenating isopropyl groups of an isopropylphenyl phosphate blend and then dehydrohalogenating to make an isopropenyl-containing product, which may be oligomerized as by heating with a catalyst. The isopropenyl-containing product may also be employed as a flame-retarding comonomer.

摘要翻译： 本发明涉及在易燃有机塑料中特别适合用作添加剂的阻燃含磷材料，具有很少或不具有增塑作用。 一种这样的材料可以通过使甲代烯丙基氯与苯酚或苯酚 - 异丙基苯酚共混物反应，然后磷酸化来制备。 另一种这样的材料可以通过将异丙基苯基磷酸酯共混物的异丙基卤化，然后脱卤化氢来制备含异丙烯基的产物，其可以通过用催化剂加热而被低聚来制备。 含异丙烯基的产物也可用作阻燃共聚单体。

公开(公告)号：US5312689A

公开(公告)日：1994-05-17

申请号：US20424

申请日：1993-02-22

申请人： David Dasher ,  E. Robert Fretz, Jr. ,  Mark S. Friske ,  Ronald E. Johnson

发明人： David Dasher ,  E. Robert Fretz, Jr. ,  Mark S. Friske ,  Ronald E. Johnson

IPC分类号： B32B27/38 ,  G02C7/02

CPC分类号： G02C7/02 ,  B32B27/38 ,  Y10T428/31511 ,  Y10T428/31573 ,  Y10T428/31855

摘要： An improved, laminated, ophthalmic lens structure, and method of producing the structure. The structure comprises two adjacent layers of dissimilar, organic plastic materials, either or both of which contain matter that tends to migrate. The improvement comprises a barrier layer that is intermediate the adjacent organic plastic layers; that is impermeable to migrating matter; and that is composed of a polyolefin polymeric material modified by the presence of acid or anhydride functional groups.

摘要翻译： 改进的层压眼镜片结构及其制造方法。 该结构包括两层相互不同的有机塑料材料，其中一种或两种含有易于迁移的物质。 该改进包括位于相邻有机塑料层之间的阻挡层; 迁移物质是不可渗透的; 并且由通过存在酸或酸酐官能团改性的聚烯烃聚合物构成。

公开(公告)号：US5223862A

公开(公告)日：1993-06-29

申请号：US682479

申请日：1991-04-08

申请人： David Dasher ,  E. Robert Fretz, Jr. ,  John W. Nelson ,  Anthony R. Olszewski

发明人： David Dasher ,  E. Robert Fretz, Jr. ,  John W. Nelson ,  Anthony R. Olszewski

IPC分类号： B29D11/00 ,  G02B1/04 ,  G02C7/02 ,  G02C7/06

CPC分类号： B29D11/00028 ,  G02B1/043 ,  G02C7/02 ,  G02C7/06

摘要： An ophthalmic lens embodying an organic plastic lens member having a refractive index of at least 1.56 and being the cured product of a monomeric formulation. The formulation contains a resin monomer base, a curing agent selected from aromatic anhydrides, aromatic diamines, thioamides and thioamines, and a refractive index enhancing additive selected from alkyl or aromatic diols or thiols and transition metal alkoxides. The organic plastic lens member may be an integral, monofocal lens, or a segment embedded in a cavity in the front, convex surface of an organic plastic, major lens member having a lesser refractive index. The latter may have a thin, inorganic glass lens member adhered to its front, convex surface to produce a glass-plastic, laminated, multifocal lens structure.

公开(公告)号：US5064712A

公开(公告)日：1991-11-12

申请号：US325880

申请日：1989-03-20

申请人： E. Robert Fretz, Jr.

发明人： E. Robert Fretz, Jr.

IPC分类号： G02B1/04 ,  B29C65/48 ,  B29D11/00 ,  B32B17/06 ,  B32B17/10 ,  G02B1/10 ,  G02B3/00

CPC分类号： B32B17/10 ,  B29C65/48 ,  B29C65/485 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/31515 ,  Y10T428/31518 ,  Y10T428/31525 ,  Y10T428/31612 ,  Y10T428/31721

摘要： There is disclosed an improvement of the three layer laminated lens structure of U.S. Pat. No. 4,793,703 whereby the adhesive inerlayer is more tightly bonded to the outer plastic and glass layers by reactive groups on the surfaces of each layer. This controls a problem of delayed delamination.

公开(公告)号：US5232637A

公开(公告)日：1993-08-03

申请号：US822863

申请日：1992-01-21

申请人： David Dasher ,  E. Robert Fretz, Jr. ,  Mark S. Friske ,  Reba S. Herndon ,  Ronald E. Johnson ,  David J. Kerko ,  John W. Nelson ,  Frederick E. Noll ,  Anthony R. Olszewski ,  Nikki J. Russo

发明人： David Dasher ,  E. Robert Fretz, Jr. ,  Mark S. Friske ,  Reba S. Herndon ,  Ronald E. Johnson ,  David J. Kerko ,  John W. Nelson ,  Frederick E. Noll ,  Anthony R. Olszewski ,  Nikki J. Russo

IPC分类号： B29C33/00 ,  B29C37/00 ,  B29C39/10 ,  B29C70/78 ,  B29D11/00 ,  B29K105/32 ,  B29L11/00 ,  G02B1/04 ,  G02C7/02

CPC分类号： B29D11/00528 ,  B29C33/0038 ,  B29C37/0078 ,  B29C39/10 ,  B29C70/78 ,  B29D11/00009 ,  B29D11/00413 ,  B29D11/0073 ,  B29K2105/0002 ,  B29K2709/08 ,  B29K2995/0034 ,  B29L2011/0041 ,  Y10S425/808 ,  Y10T156/1028

摘要： A method of producing a glass-plastic, laminated, ophthalmic lens structure in a continuous operation. A thin, flexible, plastic adhesive layer is applied to a glass element to form a composite body that is inserted in a cylindrical gasket in such manner as to fit snugly and be sealed from the ambient. A monomeric formulation is flowed onto the adhesive layer and cured to form a laminated lens blank.