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1.发明授权Ethanol manufacturing process over catalyst having improved radial crush strength 有权催化剂上的乙醇制造工艺具有改善的径向压碎强度公开(公告)号：US08927786B2
公开(公告)日：2015-01-06
申请号：US13418755
申请日：2012-03-13
Applicant: Zhenhua Zhou , Emily Duff , Dheeraj Kumar , Heiko Weiner
Inventor： Zhenhua Zhou , Emily Duff , Dheeraj Kumar , Heiko Weiner
IPC: C07C29/149
CPC classification number: B01J23/626 , B01J21/04 , B01J21/08 , B01J23/14 , B01J23/42 , B01J23/44 , B01J23/745 , B01J23/75 , B01J23/8906 , B01J23/8913 , B01J23/8993 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0207 , B01J37/10 , C07C29/149 , C07C31/08
Abstract: Acetic acid is hydrogenation in the presence of a catalyst comprising one or more active metals on a silica support, wherein the catalyst has a radial crush strength of at least 4 N/mm. The one or more active metals may include cobalt, copper, gold, iron, nickel, palladium, platinum, iridium, osmium, rhenium, rhodium, ruthenium, tin, zinc, lanthanum, cerium, manganese, chromium, vanadium, molybdenum and mixtures thereof. Radial crush strength may be improved by steam treating the catalyst support prior to the loading of the one or more active metals.
Abstract translation: 乙酸在含有一种或多种活性金属的催化剂存在下在二氧化硅载体上氢化，其中催化剂具有至少4N / mm的径向抗压强度。 一种或多种活性金属可以包括钴，铜，金，铁，镍，钯，铂，铱，锇，铼，铑，钌，锡，锌，镧，铈，锰，铬，钒，钼及其混合物 。 通过在装载一种或多种活性金属之前对催化剂载体进行蒸汽处理可以改善径向抗压强度。
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2.发明申请公开(公告)号：US20120277497A1
公开(公告)日：2012-11-01
申请号：US13457280
申请日：2012-04-26
Applicant: David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
IPC: C07C29/149
CPC classification number: C07C29/149 , C07C29/76 , C07C29/80 , C07C29/84 , C07C51/12 , C07C67/08 , C07C67/54 , C10L1/02 , C10L2200/04 , C10L2290/543 , C10L2290/548 , C07C31/08 , C07C53/08 , C07C69/14
Abstract: A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
Abstract translation: 一种从乙酸氢化中回收乙醇的方法。 将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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3.发明申请Recovering Ethanol Sidedraw By Separating Crude Product From Hydrogenation Process 有权通过将粗产物与氢化过程分开来回收乙醇公开(公告)号：US20120245396A1
公开(公告)日：2012-09-27
申请号：US13456651
申请日：2012-04-26
Applicant: Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
Inventor： Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
IPC: C07C29/80
Abstract: A process for producing ethanol is disclosed, comprising the steps of hydrogenating acetic acid in a reactor in the presence of a catalyst to form a crude ethanol product, separating at least a portion of the crude ethanol product in a column into a first distillate comprising ethanol and a first residue comprising acetic acid and water, wherein a substantial portion of the water in the crude ethanol product that is fed to the column is removed in the first residue, and separating a portion of the ethanol mixture stream to the second distillation column to yield an ethanol product sidedraw, second residue comprising water and a second distillate comprising ethyl acetate. The water content of the ethanol product sidedraw may be further reduced to yield a stream having reduced water content.
Abstract translation: 公开了一种生产乙醇的方法，包括在催化剂存在下在反应器中氢化乙酸以形成粗乙醇产物的步骤，将塔中的至少一部分粗乙醇产物分离成包含乙醇的第一馏出物 和包含乙酸和水的第一残余物，其中在第一残余物中除去进料到塔中的粗乙醇产物中的大部分水，并将一部分乙醇混合物物流分离成第二蒸馏塔至 产生乙醇产物，副产物，第二残余物包含水和包含乙酸乙酯的第二馏出物。 可以进一步降低乙醇产品侧面的水含量以产生具有降低的水含量的料流。
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4.发明授权Reducing ethyl acetate concentration in recycle streams for ethanol production processes 有权在乙醇生产过程中减少循环流中的乙酸乙酯浓度公开(公告)号：US09073816B2
公开(公告)日：2015-07-07
申请号：US13339872
申请日：2011-12-29
Applicant: R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco
Inventor： R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco
IPC: C07C27/04 , C07C29/80 , C07C29/149 , C07C29/88
CPC classification number: C07C29/80 , C07C29/149 , C07C29/88 , Y02P20/127 , C07C31/08
Abstract: Recycle streams in an ethanol production process are hydrolyzed to reduce ethyl acetate concentration. In the process, acetic acid is hydrogenated to form a crude ethanol product, which undergoes a separation or purification process. Ethyl acetate is formed as a byproduct of the hydrogenation of acetic acid. The hydrolysis of recycle steams from the separation process can reduce the concentration of ethyl acetate, converting some or all of the ethyl acetate to acetic acid and ethanol.
Abstract translation: 在乙醇生产过程中回收料流被水解以减少乙酸乙酯浓度。 在该过程中，将乙酸氢化以形成粗乙醇产物，其经历分离或纯化过程。 乙酸乙酯作为乙酸氢化的副产物形成。 从分离过程中再循环蒸汽的水解可以降低乙酸乙酯的浓度，将部分或全部乙酸乙酯转化为乙酸和乙醇。
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5.发明申请Process For Controlling A Reboiler During Alcohol Recovery and Reduced Ester Formation 有权在酒精回收和减少酯形成过程中控制再沸器的过程公开(公告)号：US20120277495A1
公开(公告)日：2012-11-01
申请号：US13457100
申请日：2012-04-26
Applicant: R. Jay Warner , Emily Duff , Victor J. Johnston , David Lee , Adam Orosco
Inventor： R. Jay Warner , Emily Duff , Victor J. Johnston , David Lee , Adam Orosco
IPC: C07C27/04
CPC classification number: C07C51/12 , C07C29/149 , C07C29/80 , C07C31/08 , C07C53/08
Abstract: The present invention is related to processes for the separation of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in one or more columns. A reboiler is used following one or more of the columns for reducing ester formation.
Abstract translation: 本发明涉及从乙酸氢化获得的粗乙醇产物中分离乙醇的方法。 将粗乙醇产物在一个或多个塔中分离。 使用一种或多种用于还原酯形成的塔的再沸器。
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Patent Agency Ranking
公开(公告)号：US20120245395A1
公开(公告)日：2012-09-27
申请号：US13456529
申请日：2012-04-26
Applicant: Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
Inventor： Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
IPC: C07C29/149
Abstract: The present invention relates to the recovery of alcohols, in particular ethanol, from a crude ethanol product obtained from the hydrogenation of acetic acid using a reduced energy process. The crude ethanol product may be fed to a distillation column in which a substantial portion of the water is removed with the acetic acid in the residue. Additional water may be removed by using a pressure swing adsorption unit, molecular sieve, and/or membrane. Ethanol extraction may also be used to reduce the ethanol concentration in the recycle streams.
Abstract translation: 本发明涉及从使用减少能量的方法从乙酸氢化获得的粗乙醇产物中回收醇，特别是乙醇。 粗乙醇产物可以进料到蒸馏塔中，其中大部分水用残余物中的乙酸除去。 可以通过使用变压吸附单元，分子筛和/或膜来除去附加的水。 乙醇提取也可用于降低再循环物流中的乙醇浓度。
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7.发明授权公开(公告)号：US08927788B2
公开(公告)日：2015-01-06
申请号：US13457280
申请日：2012-04-26
Applicant: David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
CPC classification number: C07C29/149 , C07C29/76 , C07C29/80 , C07C29/84 , C07C51/12 , C07C67/08 , C07C67/54 , C10L1/02 , C10L2200/04 , C10L2290/543 , C10L2290/548 , C07C31/08 , C07C53/08 , C07C69/14
Abstract: A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
Abstract translation: 一种从乙酸氢化中回收乙醇的方法。 将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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8.发明授权公开(公告)号：US08907141B2
公开(公告)日：2014-12-09
申请号：US13456594
申请日：2012-04-26
Applicant: David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
IPC: C07C29/12 , C07C51/12 , C07C67/08 , C07C29/149 , C07C29/80
CPC classification number: C07C29/80 , C07C29/149 , C07C51/12 , C07C67/08 , C07C31/08 , C07C53/08 , C07C69/14
Abstract: A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. Unreacted acetic acid can be reduced or removed through configurations of esterification secondary reactors. The ethanol product is recovered from the residue stream.
Abstract translation: 一种从乙酸氢化中回收乙醇的方法。 将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 未反应的乙酸可以通过酯化二级反应器的构型被还原或除去。 从残余物流中回收乙醇产物。
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9.发明授权Recovering ethanol sidedraw by separating crude product from hydrogenation process 有权通过将粗产物与氢化过程分离来回收乙醇公开(公告)号：US08536384B2
公开(公告)日：2013-09-17
申请号：US13456651
申请日：2012-04-26
Applicant: Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
Inventor： Victor J. Johnston , Radmila Jevtic , David Lee , Adam Orosco , R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff
IPC: C07C29/149
Abstract: A process for producing ethanol is disclosed, comprising the steps of hydrogenating acetic acid in a reactor in the presence of a catalyst to form a crude ethanol product, separating at least a portion of the crude ethanol product in a column into a first distillate comprising ethanol and a first residue comprising acetic acid and water, wherein a substantial portion of the water in the crude ethanol product that is fed to the column is removed in the first residue, and separating a portion of the ethanol mixture stream to the second distillation column to yield an ethanol product sidedraw, second residue comprising water and a second distillate comprising ethyl acetate. The water content of the ethanol product sidedraw may be further reduced to yield a stream having reduced water content.
Abstract translation: 公开了一种生产乙醇的方法，包括在催化剂存在下在反应器中氢化乙酸以形成粗乙醇产物的步骤，将塔中的至少一部分粗乙醇产物分离成包含乙醇的第一馏出物 和包含乙酸和水的第一残余物，其中在第一残余物中除去进料到塔中的粗乙醇产物中的大部分水，并将一部分乙醇混合物物流分离成第二蒸馏塔至 产生乙醇产物，副产物，第二残余物包含水和包含乙酸乙酯的第二馏出物。 可以进一步降低乙醇产品侧面的水含量以产生具有降低的水含量的料流。
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10.发明申请公开(公告)号：US20130109891A1
公开(公告)日：2013-05-02
申请号：US13456594
申请日：2012-04-26
Applicant: David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
IPC: C07C29/80
CPC classification number: C07C29/80 , C07C29/149 , C07C51/12 , C07C67/08 , C07C31/08 , C07C53/08 , C07C69/14
Abstract: A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. Unreacted acetic acid can be reduced or removed through configurations of esterification secondary reactors. The ethanol product is recovered from the residue stream.
Abstract translation: 一种从乙酸氢化中回收乙醇的方法。 将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 未反应的乙酸可以通过酯化二级反应器的构型被还原或除去。 从残余物流中回收乙醇产物。
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