摘要:
This invention relates to a process for producing an oligomeric product by the oligomerization of at least one olefinic compound by contacting the at least one olefinic compound with an oligomerization catalyst in an aliphatic liquid medium at a reaction temperature of at least 50° C. The catalyst comprises the combination of a source of a transition metal; and a ligating compound of the formula (R1)m X1 (Y) X2 (R2)m.
摘要:
This invention relates to a process for producing an oligomeric product by the oligomerisation of at least one olefinic compound by contacting the at least one olefinic compound with an oligomerisation catalyst in an aliphatic liquid medium at a reaction temperature of at least 50° C. The catalyst comprises the combination of a source of a transition metal; and a ligating compound of the formula (R1)mX1(Y)X2(R2)n.
摘要:
The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.
摘要:
This invention relates to a process for producing a polymeric product by the polymerisation of at least one olefinic compound in the form of an olefin or a compound including an olefinic moiety by contacting the at least one olefinic compound with a polymerisation catalyst. The catalyst comprises the combination of a source of a Group IV to VI transition metal; and a ligating compound of the formula (R1)mX1(Y)X2(R2)n. The process is characterised therein that when R1 and R2 are independently a hydrocarbyl group or a heterohydrocarbyl group which contains at least one non-polar substituent, the olefinic compound is contacted with the polymerisation catalyst at a reaction temperature from and above 70° C.; and where R1 and R2 are independently a hydrocarbyl group or a heterohydrocarbyl group which contains no substituent, the olefinic compound is contacted with the polymerisation catalyst at a reaction temperature from and above 90° C.
摘要:
According to the present invention there is provided a process for producing an oligomeric product by the oligomerisation of at least one olefinic compound including: A) providing an activated oligomerisation catalyst comprising the combination of: i) a source of a transition metal; ii) a ligating compound of the formula (R1)mX1(Y)X2(R2)n iii) a metal containing activator; and (iv) at least one olefinic compound; B) diluting the activated oligomerisation catalyst of A with an introduced liquid medium; and C) contacting the at least one olefinic compound to be oligomerised with the diluted activated catalyst of B to produce an oligomeric product.
摘要:
According to the present invention there is provided a process for producing an oligomeric product by the oligomerisation of at least one olefinic compound including: A) providing an activated oligomerisation catalyst comprising the combination of: i) a source of a transition metal; ii) a ligating compound of the formula (R1)mX1(Y)X2(R2)n iii) a metal containing activator; and (iv) at least one olefinic compound; B) diluting the activated oligomerisation catalyst of A with an introduced liquid medium; and C) contacting the at least one olefinic compound to be oligomerised with the diluted activated catalyst of B to produce an oligomeric product.
摘要:
The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.
摘要:
This invention relates to a process for producing a polymeric product by the polymerisation of at least one olefinic compound in the form of an olefin or a compound including an olefinic moiety by contacting the at least one olefinic compound with a polymerisation catalyst. The catalyst comprises the combination of a source of a Group IV to VI transition metal; and a ligating compound of the formula (R1)mX1(Y)X2(R2)n. The process is characterised therein that when R1 and R2 are independently a hydrocarbyl group or a heterohydrocarbyl group which contains at least one non-polar substituent, the olefinic compound is contacted with the polymerisation catalyst at a reaction temperature from and above 70° C.; and where R1 and R2 are independently a hydrocarbyl group or a heterohydrocarbyl group which contains no substituent, the olefinic compound is contacted with the polymerisation catalyst at a reaction temperature from and above 90° C.
摘要:
The invention describes a process for trimerisation olefins, which process includes the step of contacting an olefinic feedstream with a catalyst system which includes a transition metal compound and a heteroatomic ligand and wherein the trimer is an olefin and wherein the heteroatomic ligand is described by the following general formula (R)nA-B-C(R)m.
摘要:
The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.