Method for the production of functionalized partially hydrolyzed polyvinyl acetate

    公开(公告)号:US11498988B2

    公开(公告)日:2022-11-15

    申请号:US16768149

    申请日:2018-11-29

    摘要: A method for the production of functionalized partially hydrolyzed polyvinyl acetate comprising vinyl alcohol, vinylacetate and functionalized vinyl alcohol units by reacting in a melt a partially hydrolyzed polyvinyl acetate as component A with a reactive compound carrying at least one ethylenically unsaturated group and at least one reactive group reactive with hydroxyl or acetate groups as component B, in the presence of at least one stabilizer as component C and in the presence of at least one catalyst selected from the group consisting of tertiary amines and nitrogen-containing heterocycles as component D, the method comprising the steps: feeding the components into a mixing device capable of heating, melting and mixing components A, B, C and D, heating, melting and mixing components A, B, C and D in the device to give a melt and reacting components A and B in the melt.

    Method for producing pictorial relief structures

    公开(公告)号:US11325368B2

    公开(公告)日:2022-05-10

    申请号:US16498039

    申请日:2017-03-27

    摘要: The invention relates to a method for producing pictorial relief structures on a layer construction. The method comprises the provision of a layer construction having a substrate layer. After this, at least one fluid containing at least one first reactive component is applied pictorially to the substrate, wherein the pictorial application takes place in the form of a plurality of droplets with a droplet volume of less than 2 μl, and wherein the droplets are positioned pictorially. After this, there is an at least partial diffusing of the at least one first reactive component into the substrate layer for a predefined exposure time and/or an at least partial diffusing of at least one second reactive component into the pictorially positioned droplets of fluid for a predefined exposure time, wherein the substrate layer comprises the at least one second reactive component. The created relief is then fixed under the influence of heat and/or radiation via a reaction involving the first reactive component and/or the second reactive component.
    Further aspects of the invention relate to a pictorial relief structure produced according to the method and to the use of the pictorial relief structure as a printing form, as a microfluidic component, as a microreactor, as a phoretic cell, as a light-controlling element for color representation, as photonic crystals or as flexible parts of items of clothing.

    CYLINDER WITH MOVABLE PIN, AND MOUNTING AND DISMOUNTING METHOD

    公开(公告)号:US20210354440A1

    公开(公告)日:2021-11-18

    申请号:US17282011

    申请日:2019-10-15

    摘要: A cylinder is arranged to receive one or more hollow cylinders on an outer surface of the cylinder. The cylinder has at least one movable stop with at least one movable element. In an idle position the at least one movable element does not protrude beyond the outer surface of the cylinder and allows hollow cylinders to be slid over the cylinder, and in an active position it protrudes beyond the outer surface of the cylinder and acts as a mechanical stop for hollow cylinders. The at least one movable element can be moved from the idle position to the active position, and vice versa, by means of a rotary movement. A method for positioning a hollow cylinder on a cylinder of this kind.

    Method for producing flexographic printing plates using UV-LED irradiation

    公开(公告)号:US10730283B2

    公开(公告)日:2020-08-04

    申请号:US16142225

    申请日:2018-09-26

    摘要: A method for producing flexographic printing plates, using a photopolymerizable flexographic printing element having, arranged one atop another, a dimensionally stable support, a photopolymerizable, relief-forming layer, an elastomeric binder, an ethylenically unsaturated compound, and a photoinitiator, and optionally a rough, UV-transparent layer, a particulate substance, and digitally imagable layer. The method includes: (a) producing a mask by imaging the digitally imagable layer, (b) exposing the photopolymerizable, relief-forming layer through the mask with actinic light, and photopolymerizing the image regions of the layer, and (c) developing the photpolymerized layer by washing out the unphotopolymerized regions of the relief-forming layer with an organic solvent, or by thermal development. Step (b) includes (1) exposure with actinic light with an intensity of ≥100 mW/cm2 from a plurality of UV-LEDs and (2) exposure with actinic light with an intensity of

    Method for producing a flexographic printing frame through multiple exposures using UV LEDS

    公开(公告)号:US10175580B2

    公开(公告)日:2019-01-08

    申请号:US15536565

    申请日:2015-12-16

    摘要: A method for producing flexographic printing plates. The method has the following steps: (a) producing a mask by imaging the digitally imagable layer, (b) exposing the photopolymerizable, relief-forming layer through the mask with actinic light, and photopolymerizing the image regions of the layer, and (c) developing the photopolymerized layer by washing out the unphotopolymerized regions of the relief-forming layer with an organic solvent, or by thermal development, wherein step (b) contains at least two exposure cycles with actinic light with an intensity of 100 to 5000 mW/cm2 from a plurality of UV-LEDs, the energy input into the photopolymerizable, relief-forming layer per exposure cycle being 0.1 to 5 J/cm2.

    METHOD FOR GENERATIVE PRODUCTION OF RELIEF PRINTING PLATES BY MONOMER DIFFUSION THROUGH AN INTEGRAL MASK LAYER

    公开(公告)号:US20180373142A1

    公开(公告)日:2018-12-27

    申请号:US16064092

    申请日:2016-12-19

    IPC分类号: G03F7/00 G03F7/033 G03F7/12

    摘要: The invention relates to a method for generative production of relief printing plates, wherein a support with a polymeric substrate layer and a laser-ablatable mask layer is provided, the polymeric substrate layer containing a first binder. A mask with openings corresponding to pixels is produced by imagewise laser ablation of the mask layer. A liquid containing a reactive monomer is then applied over the surface of the mask-covered polymeric substrate layer, and the liquid or the reactive monomer diffuses through the openings of the mask into the polymeric substrate layer for a defined exposure time so as to form a relief. The excess liquid or the excess monomer and optionally the mask are removed from the surface, and the resulting relief is fixed by crosslinking.

    AUTOMATED UV-LED EXPOSURE OF FLEXOGRAPHIC PRINTING PLATES

    公开(公告)号:US20180126721A1

    公开(公告)日:2018-05-10

    申请号:US15860795

    申请日:2018-01-03

    发明人: FRANK BOYKSEN

    IPC分类号: B41C1/10 G03F7/20

    摘要: Method for producing flexographic printing plates, using as starting material a photopolymerizable flexographic printing plate which at least comprises, arranged one above another, a dimensionally stable support, at least one photopolymerizable, relief-forming layer, at least comprising an elastomeric binder, an ethylenically unsaturated compound and a photoinitiator, a digitally imagable layer, comprising at least the following steps: (a) producing a mask by imaging the digitally imagable layer, (b) exposing the flexographic printing plate through the mask with actinic light, and photopolymerizing the image regions of the layer, the exposing taking place with a plurality of UV-LEDs which are arranged on at least one UV-LED strip which is moved relative to the surface of the flexographic printing plate, and (c) developing the photopolymerized layer by washing out and drying or by thermal development, characterized in that in the UV-LED strip or in a separate strip, at least one ultrasonic sensor is arranged, at least the thickness of the flexographic printing plate for exposure is determined with the at least one ultrasonic sensor, depending on the measured thickness of the flexographic printing plate, the exposing of the flexographic printing plate is controlled in respect of at least one of the following parameters: (i) number of exposure steps, (ii) exposure intensity, (iii) energy input per exposure step, (iv) duration of the individual exposure steps, (v) overall duration of exposure.