Copolymers of an N-vinyl lactam and an unsaturated lactone
    1.
    发明授权
    Copolymers of an N-vinyl lactam and an unsaturated lactone 失效
    N-乙烯基内酰胺和不饱和内酯的共聚物

    公开(公告)号:US3929735A

    公开(公告)日:1975-12-30

    申请号:US32210973

    申请日:1973-01-09

    申请人: GAF CORP

    发明人: BARABAS EUGENE S

    摘要: WHEREIN K and l are integers representing the number of monomer units in the polymer, R3 is hydrogen or alkoxy; alkyl of 1 to about 6 carbon atoms, each R1 is hydrogen, methyl or ethyl, R2 is hydrogen or alkyl of 1 to 4 carbon atoms and n is an integer of 2 to 4; methods of making same and products made therefrom.

    There is disclosed a copolymer having the formula

    摘要翻译: 公开了具有下列通式的共聚物:CH 2 -CH 2 CH- CH - ||| N角度R2-HC角度C = OR3OO(CHR1)n K1 其中K和l是表示聚合物中单体单元数的整数,R 3是氢或烷氧基; 1至约6个碳原子的烷基,每个R 1为氢,甲基或乙基,R 2为氢或1至4个碳原子的烷基,n为2至4的整数; 制造方法和由其制成的产品。

    N-substituted-p-(2-chloroethyl)-phosphonamidates as yield improvers
    2.
    发明授权
    N-substituted-p-(2-chloroethyl)-phosphonamidates as yield improvers 失效
    N-取代对 - (2-氯乙基) - 膦酰胺化物作为产率改进剂

    公开(公告)号:US3928018A

    公开(公告)日:1975-12-23

    申请号:US44131774

    申请日:1974-02-11

    申请人: GAF CORP

    IPC分类号: C07F9/44 A01N9/36

    CPC分类号: C07F9/44

    摘要: wherein R1 is halophenyl and R2 is alkyl or haloalkyl. They are prepared by the reaction of 2-chloroethylphosphonohalidic esters with the appropriate haloaniline.

    Plant growth regulating compounds are N-substituted-P-(2chloroethyl)-phosphonamidic esters of the formula:

    摘要翻译: 植物生长调节化合物是下式的N-取代的P-(2-氯乙基) - 膦酰胺基酯:O PARALLEL Cl-CH 2 CH 2 -P-NH-R 1 | OR 2,其中R 1是卤代苯基,R 2是烷基或卤代烷基。 它们通过2-氯乙基膦酰基酯与适当的卤代苯胺的反应制备。

    2-Chloroethylphosphonothioic acids and esters for regulation of plant growth
    3.
    发明授权
    2-Chloroethylphosphonothioic acids and esters for regulation of plant growth 失效
    用于调节植物生长的2-氯乙基亚硫酸和酯

    公开(公告)号:US3920439A

    公开(公告)日:1975-11-18

    申请号:US32451673

    申请日:1973-01-17

    申请人: GAF CORP

    IPC分类号: C07F9/38 C07F9/42 A01N9/36

    CPC分类号: C07F9/42 C07F9/3808

    摘要: wherein X is oxygen or sulfur and R is hydrogen, alkyl, aryl, alkaryl or aralkyl, are useful as plant growth regulators when administered to plants in association with a carrier. The compounds are prepared by reaction of the 2-chloroethylphosphonic acid chloride with phosphorus pentasulfide to form 2chloroethylphosphonothioic acid chloride and reaction of this material with water to form the acid, hydrogen sulfide to form the trithioic acid, and reaction with an alcohol or thioalcohol to form the esters.
    Compounds of the following formula:

    摘要翻译: 下式的化合物:S PARALLEL Cl CH2CH2-P-XR | XR其中X是氧或硫,R是氢,烷基,芳基,烷芳基或芳烷基,当与载体结合施用于植物时可用作植物生长调节剂 。 该化合物是通过2-氯乙基膦酸氯化物与五硫化二磷反应制得2-氯乙基膦酰氯,并将该物质与水反应形成酸,硫化氢以形成三硫代酸,并与醇或硫醇反应 以形成酯。

    2-Chloroethylphosphonodithioate esters
    4.
    发明授权
    2-Chloroethylphosphonodithioate esters 失效
    2-氯乙基二硫代磷酸酯

    公开(公告)号:US3905799A

    公开(公告)日:1975-09-16

    申请号:US21852772

    申请日:1972-01-17

    申请人: GAF CORP

    IPC分类号: C07F9/40 A01N9/12

    CPC分类号: C07F9/4006

    摘要: 2-Chloroethylphosphonodithioate esters, useful as plant growth regulators for increasing fruiting having the following formula:

    wherein R is alkyl of one to two carbon atoms, halo-substituted alkyl of one to two carbon atoms, aryl of six to 12 carbon atoms, halo-substituted aryl of six to 12 carbon atoms or aralkyl produced by the reaction of a 2-chloroethylphosphonyl halide with a mercaptan of the formula RSH in the presence of an acid acceptor compositions containing the same and methods for using the compositions.

    摘要翻译: 2-氯乙基二硫代磷酸酯,可用作用于增加果实的植物生长调节剂,具有下列结构:其中R为1至2个碳原子的烷基,1至2个碳原子的卤素取代的烷基的O-PARALLEL C1-CH2CH2-P-SR | SR ,6至12个碳原子的芳基,6至12个碳原子的卤素取代的芳基或通过2-氯乙基膦酰卤与式RSH的硫醇在含有它们的酸受体组合物的存在下反应产生的芳烷基;以及 使用组合物的方法。

    Copolymers of an N-vinyl lactam and a branched chain aliphatic carboxylic acid ester
    5.
    发明授权
    Copolymers of an N-vinyl lactam and a branched chain aliphatic carboxylic acid ester 失效
    N-乙烯基内酰胺和支链脂族羧酸酯的共聚物

    公开(公告)号:US3899461A

    公开(公告)日:1975-08-12

    申请号:US32710673

    申请日:1973-01-26

    申请人: GAF CORP

    摘要: There is disclosed a copolymer composition derived from monomeric units comprising (a) an N-vinyl lactam corresponding to the formula:

    wherein R represents a divalent alkylene bridge having sufficient carbon atoms to form a five, six or seven member heterocyclic ring system and R1 is a member selected from the group consisting of hydrogen and lower alkyl and (b) a branched chain aliphatic carboxylic acid ester corresponding to the formula:

    wherein R1, R2 and R3 are saturated alkyl groups. The polymers of the invention may be made into homogeneous solutions when the amount of (a) is 1:99% and the amount of (b) is 99:1% of the total weight of the polymer or suspensions; or they may be made as stable aqueous emulsions when the ratio of (a) and (b) is 10: 60% and 90:40%, respectively.

    摘要翻译: 公开了一种衍生自单体单元的共聚物组合物,其包含(a)对应于下式的N-乙烯基内酰胺:R R1-CH型角度C = O。 N | CH并行CH2其中R表示具有足够碳原子以形成5,6或7元杂环系的二价亚烷基桥,R 1为选自氢和低级烷基的成员,(b)支链 对应于下式的R 1 | R 2 -C-COOH = CH 2 | R 3的脂族羧酸酯,其中R 1,R 2和R 3是饱和烷基。 当(a)的量为1:99%且(b)的量为聚合物或悬浮液的总重量的99:1%时,本发明的聚合物可制成均匀溶液; 或者当(a)和(b)的比例分别为10:60%和90:40%时,它们可以制成稳定的水性乳液。

    Anthraquinone dyes
    6.
    发明授权
    Anthraquinone dyes 失效
    ANTHRAQUINONE染发剂

    公开(公告)号:US3883534A

    公开(公告)日:1975-05-13

    申请号:US31247672

    申请日:1972-12-06

    申请人: GAF CORP

    发明人: CHANG CHARLES H

    IPC分类号: C09B1/514 C07D27/52

    CPC分类号: C09B1/514

    摘要: Anthraquinone derivatives of the formula

    IN WHICH A is hydrogen, chlorine, bromine or lower alkyl; R is alkylene of from 2 to 4 carbon atoms, vinylene, 1,2-benzene, 1,2cyclohexane, 1,8-naphthalene, or 1,2-cyclohex-4-ene; R'' is lower alkyl; and Y is hydrogen, hydroxy, chlorine, bromine, lower alkyl or lower alkoxy, are useful for dyeing synthetic, especially polyester, fibers.

    摘要翻译: 蒽醌衍生物,其中A为氢,氯,溴或低级烷基; R是2至4个碳原子的亚烷基,亚乙烯基,1,2-苯,1,2-环己烷,1,8-萘或1,2-环己-4-烯; R'是低级烷基; Y为氢,羟基,氯,溴,低级烷基或低级烷氧基,可用于染色合成纤维,特别是聚酯纤维。

    Sun-screening compounds I
    7.
    发明授权
    Sun-screening compounds I 失效
    防晒化合物I

    公开(公告)号:US3875198A

    公开(公告)日:1975-04-01

    申请号:US46524774

    申请日:1974-04-29

    申请人: GAF CORP

    CPC分类号: A61Q17/04 A61K8/445

    摘要: WHERE R1 and R2 are independently straight or branched chain lower alkyl; Y is C2-C6 alkylene; X is R3-COO , HOOC-R4-COO or OOC-R4-COO , where R3 is alkyl of 1 to 18 carbon atoms and R4 is alkylene of 1 to 18 carbon atoms; and n is 1 when X is R3-COO or HOOC-R4-COO or n is 2 when X is OOC-R4-COO . Sun-screening compositions containing such compounds and a cosmetically acceptable diluent or carrier, and methods of using such compositions, are also disclosed.

    Sun-screening compounds, useful to protect the skin and hair against deleterious effects upon exposure to ultraviolet radiation, of the formula:

    摘要翻译: 防晒化合物,用于保护皮肤和毛发免受暴露于紫外线辐射下的有害影响,具有下式:

    Carboxylated graft copolymer and emulsion containing same
    8.
    发明授权
    Carboxylated graft copolymer and emulsion containing same 失效
    羧酸接枝共聚物和含有它的乳液

    公开(公告)号:US3869418A

    公开(公告)日:1975-03-04

    申请号:US37042073

    申请日:1973-06-15

    申请人: GAF CORP

    摘要: A graft copolymer of a monomer including at least one monomeric unsaturated aliphatic carboxylic acid and at least one additional monomer selected from the group consisting of aliphatic conjugated dienes and monoalkenyl aromatic compounds polymerized on a polymeric N-vinyl lactam substrate, stable aqueous emulsions containing same, and methods for producing such emulsions and graft copolymers useful as adhesives and other purposes.

    摘要翻译: 包含至少一种单体不饱和脂族羧酸的单体和至少一种选自由聚合N-乙烯基内酰胺基材聚合的脂族共轭二烯和单链烯基芳族化合物组成的组的单体的接枝共聚物,含有它们的稳定含水乳液, 以及用于制备这种乳液和用作粘合剂和其它目的的接枝共聚物的方法。

    Positive working quinone diazide lithographic plate compositions and articles having non-ionic surfactants
    9.
    发明授权
    Positive working quinone diazide lithographic plate compositions and articles having non-ionic surfactants 失效
    具有非离子表面活性剂的正极工作二氧化钛平版印刷板组合物和文章

    公开(公告)号:US3868254A

    公开(公告)日:1975-02-25

    申请号:US31032672

    申请日:1972-11-29

    申请人: GAF CORP

    发明人: WEMMERS ANTON

    IPC分类号: G03F7/022 G03F7/08 G03C1/54

    CPC分类号: G03F7/0226

    摘要: An improved positive working lithographic plate is provided by incorporating a developing additive into the plate coating which allows rapid development of the plate with excellent clarity and definition. Additionally, this additive increases both the storage and press life of such plate. The additive may be a nonionic surfactant such as an alkylphenoxy poly (ethylenoxy) ethanol, a quinone or a poly (lower alkyl vinyl ether) incorporated into a light sensitive coating made up of a novolak resin; for example, a novolak type condensation product of phenol and formaldehyde and a sensitizer; for example, a quinone diazide sensitizer.

    摘要翻译: 通过将显影添加剂结合到板涂层中来提供改进的正性平版印刷板,其允许以极好的清晰度和定义快速显影印版。 此外,该添加剂增加了这种板的储存和压榨寿命。 添加剂可以是非离子表面活性剂,例如烷基苯氧基聚(乙烯氧基)乙醇,醌或聚(低级烷基乙烯基醚),其结合到由酚醛清漆树脂组成的感光涂层中; 例如苯酚和甲醛的酚醛清漆型缩合产物和敏化剂; 例如,醌二叠氮化物敏化剂。

    Quaternized n-vinyl lactam polymeric compositions and mannich adducts thereof
    10.
    发明授权
    Quaternized n-vinyl lactam polymeric compositions and mannich adducts thereof 失效
    季戊四醇酯乳液聚合物及其制备方法

    公开(公告)号:US3862091A

    公开(公告)日:1975-01-21

    申请号:US23261272

    申请日:1972-03-07

    申请人: GAF CORP

    摘要: A composition comprising A. the polymeric reaction product of the polymerization of a mixture of monomers comprising 1. 20-80 MOLE PERCENT OF A QUATERNARY AMMONIUM COMPOUND REPRESENTED BY THE FORMULA

    WHEREIN R1 and R2 are selected from the group consisting of hydrogen, methyl and ethyl radicals; R3 and R4 each represent a C1-6 alkyl group, and X represents an anion, 2. 80-20 MOLE PERCENT OF AN N-vinyl lactam monomer, and 3. 0-20 MOLE PERCENT OF ANOTHER ETHYLENICALLY UNSATURATED MONOMER; A Mannich Adduct thereof and methods of preparation.

    摘要翻译: 一种组合物,其包含A.由式(1)表示的季铵盐化合物的单体混合物的聚合反应的聚合反应产物,其选自氢,甲基和乙基 自由基 R3和R4各自表示C1-6烷基,X表示阴离子,2.80〜20摩尔%的N-乙烯基内酰胺单体,和3. 0〜20摩尔%的其他乙烯基不饱和单体; 曼尼希加合物及其制备方法。