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1.发明授权公开(公告)号：US07186400B2
公开(公告)日：2007-03-06
申请号：US10484111
申请日：2002-07-10
Applicant: Giovanni Battista Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi
Inventor： Giovanni Battista Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi
IPC: A61B5/055
CPC classification number: C07D243/08 , A61K49/0002 , A61K49/101
Abstract: Compounds of general formula (I): in which: R1 is hydrogen, C1–C20 alkyl, C3–C10 cycloalkyl, C4–C20 cycloalkylalkyl, aryl, arylalkyl, or two R1, taken together, form a straight or cyclic C2–C10 alkylene group or an ortho disubstituted arylene; R2 is hydrogen, C1–C20 alkyl, C3–C10 cycloalkyl, C4–C20 cycloalkylalkyl, aryl or aryl alkyl optionally substituted with functional groups which allow conjugation with a suitable molecule able to interact with physiological systems; R3, R4 and R5 are hydrogen, C1–C20 alkyl, C3–C10 cycloalkyl, C4–C20 cycloalkylalkyl, aryl, arylalkyl; and their chelates with bi-trivalent ions of the metal elements having atomic number ranging between 20 and 31, 39, 42, 43, 44, 49, and between 57 and 83, and radioisotopes chosen among 203Pb 67Ga 68Ga 72As 111In 113In 90Y 97Ru 62Cu 64Cu 52Fe 52mMn 140La 175Yb 153Sm 166Ho 149Pm 177Lu 142Pr 159Gd 212Bi 47Sc 149Pm 67Cu, 111Ag, 199Au, 161Tb and 51Cr as well as the salts thereof with physiologically compatible bases or acids
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2.发明申请PRODUCTION OF ALDEHYDES BY OXIDATION IN AQUEOUS MEDIUM WITH SELECTIVE RECOVERY OF THE PRODUCT BY MEANS OF PERVAPORATION 有权通过氧气在水性介质中生产氧化铝，通过蒸气选择性地恢复产品公开(公告)号：US20130123546A1
公开(公告)日：2013-05-16
申请号：US13703618
申请日：2011-06-10
Applicant: Giovanni Camer Roda , Vincenzo Augugliaro , Vittorio Loddo , Giovanni Palmisano , Leonardo Palmisano
Inventor： Giovanni Camer Roda , Vincenzo Augugliaro , Vittorio Loddo , Giovanni Palmisano , Leonardo Palmisano
CPC classification number: C07C45/27 , C07C45/29 , C07C45/36 , C07C45/38 , C07C45/78 , C07C47/54 , C07C47/565 , C07C47/228 , C07C47/542 , C07C47/55 , C07C47/575
Abstract: A process for the preparation of an aromatic aldehyde by means of the oxidation of the corresponding starting compound in aqueous medium, and separation of said aldehyde from said medium by pervaporation is disclosed together a plant for its carrying out. Advantageously, the process of the present invention allows control of oxidation reaction and recovery of the product with high selectivity and purity. Among others, benzaldehyde, anisaldehyde and vanillin can advantageously be prepared by this process.
Abstract translation: 通过在水性介质中氧化相应起始化合物并通过全蒸发从所述介质中分离醛的方法公开在一起用于其进行的设备。 有利地，本发明的方法允许以高选择性和纯度控制氧化反应和回收产物。 其中，苯甲醛，茴香醛和香草醛可有利地通过该方法制备。
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Patent Agency Ranking
3.发明授权Multidentate AZA ligands able to complex metal ions and the use thereof in diagnostics and therapy 有权能够复合金属离子的多齿AZA配体及其在诊断和治疗中的应用公开(公告)号：US07893223B2
公开(公告)日：2011-02-22
申请号：US11165793
申请日：2005-06-24
Applicant: Giovanni Battista Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi , Rolf Swenson , Ramalingam Kondareddiar , Luciano Lattuada , Pierfrancesco Morosini
Inventor： Giovanni Battista Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi , Rolf Swenson , Ramalingam Kondareddiar , Luciano Lattuada , Pierfrancesco Morosini
IPC: C07F13/00
CPC classification number: C07C209/62 , A61K49/0002 , A61K49/085 , A61K49/106 , A61K49/122 , A61K49/14 , A61K51/088 , C07D243/08 , C07D243/14 , C07F9/301 , C07F9/3808 , C07F9/4816 , C07F9/645 , C07C211/50
Abstract: Compounds of general formula (I): with substituents as defined herein and their chelates with bi-trivalent ions of the metal elements of atomic numbers 20 to 31, 39, 42, 43, 44, 49, and 57 to 83, and radioisotopes chosen among 203Pb, 67Ga, 68Ga, 72As, 111In, 113In, 90Y, 97Ru, 62Cu, 64Cu, 52Fe, 52mMn, 140La, 175Yb, 153Sm, 166Ho, 149Pm, 177Lu, 142Pr, 159Gd, 212Bi, 47Sc, 149Pm, 67Cu, 111Ag, 199Au, 161Tb, 51Cr, 167Tm, 141Ce, 168Yb, 88Y, 165Dy, 166Dy, 97Ru, 103Ru, 186Re, 99mTc, 211Bi, 213Bi, 214Bi, 105Rh, 109Pd, 177mSn, 177Sn and 199Au, as well as the salts thereof with physiologically compatible bases or acids.
Abstract translation: 通式（I）的化合物：具有如本文所定义的取代基及其与原子序数为20至31,39,42,43,44,49和57至83的金属元素的双三价离子的螯合物和选择的放射性同位素 在203Pb，67Ga，68Ga，72As，111In，113In，90Y，97Ru，62Cu，64Cu，52Fe，52mMn，140La，175Yb，153Sm，166Ho，149Pm，177Lu，142Pr，159Gd，212Bi，47Sc，149Pm，67Cu，111Ag ，199Au，161Tb，51Cr，167Tm，141Ce，168Yb，88Y，165Dy，166Dy，97Ru，103Ru，186Re，99mTc，211Bi，213Bi，214Bi，105Rh，109Pd，177mSn，177Sn和199Au， 生理相容的碱或酸。
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4.发明申请METAL-CONTAINING ORGANOSILICA CATALYST; PROCESS OF PREPARATION AND USE THEREOF 审中-公开含金属有机硅催化剂; 制备方法及其用途公开(公告)号：US20110190115A1
公开(公告)日：2011-08-04
申请号：US13057521
申请日：2009-08-04
Applicant: Rosaria Ciriminna , Mario Pagliaro , Giovanni Palmisano , Valerica Pandarus , Lynda Tremblay , Francois Béland , Mathieu Simard
Inventor： Rosaria Ciriminna , Mario Pagliaro , Giovanni Palmisano , Valerica Pandarus , Lynda Tremblay , Francois Béland , Mathieu Simard
CPC classification number: B01J31/124 , B01J21/08 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/755 , B01J37/16 , B01J2231/4211 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2231/62 , B01J2231/641 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/16 , B01J2531/17 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07B37/04
Abstract: The invention relates to a metal-containing organosilica catalyst, and use thereof in metal-catalyzed reactions. The invention relates to a process of preparation of the metal-containing organosilica catalyst comprising i) mixing a silicon source with an hydrolytic solvent; ii) adding one or more metal catalyst or a precursor thereof; iii) treating the mixture of step ii) with a condensation catalyst and iv) optionally treating the mixture resulting from step iii) with one or more reducing or oxydating agent such as to provide the required oxidation level to the metal catalyst.
Abstract translation: 本发明涉及含金属的有机二氧化硅催化剂及其在金属催化反应中的应用。 本发明涉及一种制备含金属有机硅催化剂的方法，包括：i）将硅源与水解溶剂混合; ii）加入一种或多种金属催化剂或其前体; iii）用缩合催化剂处理步骤ii）的混合物，和iv）任选地用一种或多种还原或氧化剂处理由步骤iii）得到的混合物，以便为金属催化剂提供所需的氧化水平。
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5.发明申请公开(公告)号：US20110082280A1
公开(公告)日：2011-04-07
申请号：US12949306
申请日：2010-11-18
Applicant: Giovanni Battista GIOVENZANA , Giovanni PALMISANO , Massimo SISTI , Camilla CAVALLOTTI , Silvio AIME , Luisella CALABI , Rolf SWENSON , Kondareddiar RAMALINGAM , Luciano LATTUADA , Pierfrancesco MOROSINI
Inventor： Giovanni Battista GIOVENZANA , Giovanni PALMISANO , Massimo SISTI , Camilla CAVALLOTTI , Silvio AIME , Luisella CALABI , Rolf SWENSON , Kondareddiar RAMALINGAM , Luciano LATTUADA , Pierfrancesco MOROSINI
IPC: C07K7/08 , C07D243/12 , C07K7/06 , C07D403/06 , C07D243/08
CPC classification number: C07C209/62 , A61K49/0002 , A61K49/085 , A61K49/106 , A61K49/122 , A61K49/14 , A61K51/088 , C07D243/08 , C07D243/14 , C07F9/301 , C07F9/3808 , C07F9/4816 , C07F9/645 , C07C211/50
Abstract: Methods of coupling targeting molecules to multidentate aza ligands of general formula (I): in which: R1 through R5 and FG are as defined in the specification are presented. The aza ligands and/or the resulting conjugates may be labeled with bi-trivalent ions of the metal elements having atomic number ranging between 20 and 31, 39, 42, 43, 44, 49, and between 57 and 83, and radioisotopes chosen among 203Pb, 67Ga, 68Ga, 72As, 111In, 113In, 90Y, 97Ru, 62Cu, 64Cu, 52Fe, 52mMn, 140La, 175Yb, 153Sm, 166Ho, 149Pm, 177Lu, 142Pr, 159Gd, 212Bi, 47Sc, 149Pm, 67Cu, 111Ag, 199Au, 161Tb, 51Cr, 167Tm, 141Ce, 168Yb, 88Y, 165Dy, 166Dy, 97Ru, 103Ru, 186Re, 188Re, 99mTc, 211Bi, 212Bi, 213Bi, 214Bi, 105Rh, 109Pd, 117mSn, 177Sn and 199Au.
Abstract translation: 将靶向分子与通式（I）的多齿氮杂配体偶联的方法：其中：R1至R5和FG如说明书中所定义。 氮杂配体和/或所得到的缀合物可以用原子序数在20,31,42,43,44,49和57和83之间的金属元素的二价离子标记，并且放射性同位素选自 203Pb，67Ga，68Ga，72As，111In，113In，90Y，97Ru，62Cu，64Cu，52Fe，52mMn，140La，175Yb，153Sm，166Ho，149Pm，177Lu，142Pr，159Gd，212Bi，47Sc，149Pm，67Cu，111Ag， 199Au，161Tb，51Cr，167Tm，141Ce，168Yb，88Y，165Dy，166Dy，97Ru，103Ru，186Re，188Re，99mTc，211Bi，212Bi，213Bi，214Bi，105Rh，109Pd，117mSn，177Sn和199Au。
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6.发明申请公开(公告)号：US20060034773A1
公开(公告)日：2006-02-16
申请号：US11165793
申请日：2005-06-24
Applicant: Giovanni Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi , Rolf Swenson , Ramalingam Kondareddiar , Luciano Lattuada , Pierfrancesco Morosini
Inventor： Giovanni Giovenzana , Giovanni Palmisano , Massimo Sisti , Camilla Cavallotti , Silvio Aime , Luisella Calabi , Rolf Swenson , Ramalingam Kondareddiar , Luciano Lattuada , Pierfrancesco Morosini
CPC classification number: C07C209/62 , A61K49/0002 , A61K49/085 , A61K49/106 , A61K49/122 , A61K49/14 , A61K51/088 , C07D243/08 , C07D243/14 , C07F9/301 , C07F9/3808 , C07F9/4816 , C07F9/645 , C07C211/50
Abstract: Compounds of general formula (I): in which: R1 through R5 are as defined in the specification FG, which can be the same or different, are carboxy, —PO3H2 or —RP(O)OH groups, wherein R is hydrogen, or an optionally substituted group selected from C1-C20 alkyl, C3-C10 cycloalkyl, C4-C20 cycloalkylalkyl, aryl, arylalkyl, a group bearing an acidic moiety, and a group bearing an amino moiety, each of which may be further optionally substituted with functional groups which allow conjugation with a suitable molecule able to interact with physiological systems; and their chelates with bi-trivalent ions of the metal elements having atomic number ranging between 20 and 31, 39, 42, 43, 44, 49, and between 57 and 83, and radioisotopes chosen among 203Pb, 67Ga, 68Ga, 72As, 111In, 113In, 90Y, 97Ru, 62Cu, 64Cu, 52Fe, 52mMn, 140La, 175Yb, 153Sm, 166Ho, 149Pm, 177Lu, 142Pr, 159Gd, 212Bi, 47Sc, 149Pm, 67Cu, 111Ag, 199Au, 161Tb, 51Cr, 167Tm, 141Ce, 168Yb, 88Y, 165Dy, 166Dy, 97Ru, 103Ru, 186Re, 188Re, 99mTc, 211Bi, 212Bi, 213Bi, 214Bi, 105Rh, 109Pd, 117mSn, 177Sn and 199Au, as well as the salts thereof with physiologically compatible bases or acids.
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7.发明授权Production of aldehydes by oxidation in aqueous medium with selective recovery of the product by means of pervaporation 有权通过在水介质中氧化生产醛，通过渗透蒸发选择性回收产物公开(公告)号：US08884069B2
公开(公告)日：2014-11-11
申请号：US13703618
申请日：2011-06-10
Applicant: Giovanni Camera Roda , Vincenzo Augugliaro , Vittorio Loddo , Giovanni Palmisano , Leonardo Palmisano
Inventor： Giovanni Camera Roda , Vincenzo Augugliaro , Vittorio Loddo , Giovanni Palmisano , Leonardo Palmisano
CPC classification number: C07C45/27 , C07C45/29 , C07C45/36 , C07C45/38 , C07C45/78 , C07C47/54 , C07C47/565 , C07C47/228 , C07C47/542 , C07C47/55 , C07C47/575
Abstract: A process for the preparation of an aromatic aldehyde by means of the oxidation of the corresponding starting compound in aqueous medium, and separation of said aldehyde from said medium by pervaporation is disclosed together a plant for its carrying out. Advantageously, the process of the present invention allows control of oxidation reaction and recovery of the product with high selectivity and purity. Among others, benzaldehyde, anisaldehyde and vanillin can advantageously be prepared by this process.
Abstract translation: 通过在水性介质中氧化相应起始化合物并通过全蒸发从所述介质中分离醛的方法公开在一起用于其进行的设备。 有利地，本发明的方法允许以高选择性和纯度控制氧化反应和回收产物。 其中，苯甲醛，茴香醛和香草醛可有利地通过该方法制备。
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