Isotropic negative thermal expansion cermics and process for making
    1.
    发明授权
    Isotropic negative thermal expansion cermics and process for making 有权
    各向同性负热膨胀皮质及其制造工艺

    公开(公告)号:US06258743B1

    公开(公告)日:2001-07-10

    申请号:US09146518

    申请日:1998-09-03

    IPC分类号: C04B3548

    摘要: Ceramic monoliths are described which exhibit tunable coefficients of thermal expansion from about −5 to −11×10−6° C.−1 near ambient temperatures. These two-phase ceramics, which are fabricated, for example, by reactive sintering of WO3 and ZrO2, consists of a matrix of ZrW2O8 with inclusions of ZrO2 having diameters less than 10 &mgr;m. Additives may increase the density of the monoliths to greater than 98% of the calculated density. Green body densities, pre-sintered particle size distribution, sintering atmosphere, microstructure, and mechanical properties are discussed. These ceramics may be used as substrates for thermally compensating fiber Bragg gratings.

    摘要翻译: 描述了陶瓷整料,其在环境温度附近表现出约-5至-11×10 -6℃-1的可调热膨胀系数。 这些由WO 3和ZrO 2的反应烧结制成的两相陶瓷由ZrW 2 O 8基体和直径小于10um的ZrO2夹杂物构成。 添加剂可将整料的密度提高到计算密度的98%以上。 讨论了绿体密度,预烧结粒度分布,烧结气氛,微观结构和力学性能。 这些陶瓷可以用作热补偿光纤布拉格光栅的基板。

    Process for making isotropic negative thermal expansion ceramics
    4.
    发明授权
    Process for making isotropic negative thermal expansion ceramics 有权
    制造各向同性负热膨胀陶瓷的方法

    公开(公告)号:US06403511B2

    公开(公告)日:2002-06-11

    申请号:US09835570

    申请日:2001-04-17

    IPC分类号: C04B3548

    摘要: Ceramic monoliths are described which exhibit tunable coefficients of thermal expansion from about −5 to −11×10−6° C.−1 near ambient temperatures. These two-phase ceramics, which are fabricated, for example, by reactive sintering of WO3 and ZrO2, consists of a matrix of ZrW2O8 with inclusions of ZrO2 having diameters less than 10 &mgr;m. Additives may increase the density of the monoliths to greater than 98% of the calculated density. Green body densities, pre-sintered particle size distribution, sintering atmosphere, microstructure, and mechanical properties are discussed. These ceramics may be used as substrates for thermally compensating fiber Bragg gratings.

    摘要翻译: 描述了陶瓷整料,其在环境温度附近表现出约-5至-11×10 -6℃-1的可调热膨胀系数。 这些由WO 3和ZrO 2的反应烧结制成的两相陶瓷由ZrW 2 O 8基体和直径小于10um的ZrO2夹杂物构成。 添加剂可将整料的密度提高到计算密度的98%以上。 讨论了绿体密度,预烧结粒度分布,烧结气氛,微观结构和力学性能。 这些陶瓷可以用作热补偿光纤布拉格光栅的基板。