公开(公告)号：US07759677B2

公开(公告)日：2010-07-20

申请号：US11760872

申请日：2007-06-11

申请人： Hyoyoung Lee ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Junghyun Lee ,  Nak Jin Choi ,  Ja Ryong Koo

发明人： Hyoyoung Lee ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Junghyun Lee ,  Nak Jin Choi ,  Ja Ryong Koo

IPC分类号： H01L35/24 ,  H01L51/00

CPC分类号： H01L27/285 ,  B82Y10/00 ,  G11C11/14 ,  H01L51/0073 ,  H01L51/0595

摘要： Provided are a molecular electronic device and a method of fabricating the molecular electronic device. The molecular electronic device includes a substrate, an organic dielectric thin film formed over the substrate, a molecular active layer formed on the organic dielectric thin film and having a charge trap site, and an electrode formed on the molecular active layer. The organic dielectric thin film may be immobilized on the electrode or a Si layer by a self-assembled method. The organic dielectric thin film may include first and second molecular layers bound together through hydrogen bonds. An organic compound may be self-assembled over the substrate to form the organic dielectric thin film. The organic compound may include an M′-R-T structure, where M′, R and T represent a thiol or silane derivative, a saturated or unsaturated C1 to C20 hydrocarbon group which is substituted or unsubstituted with fluorine (F), and an amino(—NH2) or carboxyl (—COOH) group, respectively.

摘要翻译： 提供分子电子器件和制造分子电子器件的方法。 分子电子器件包括衬底，在衬底上形成的有机电介质薄膜，形成在有机电介质薄膜上并具有电荷陷阱位置的分子活性层和形成在分子活性层上的电极。 可以通过自组装方法将有机电介质薄膜固定在电极或Si层上。 有机电介质薄膜可以包括通过氢键结合在一起的第一和第二分子层。 有机化合物可以在衬底上自组装形成有机介电薄膜。 有机化合物可以包括M'-RT结构，其中M'，R和T表示硫醇或硅烷衍生物，被氟（F）取代或未取代的饱和或不饱和的C1至C20烃基和氨基（ -NH 2）或羧基（-COOH）基团。

公开(公告)号：US20100090210A1

公开(公告)日：2010-04-15

申请号：US12638839

申请日：2009-12-15

申请人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

发明人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

IPC分类号： H01L51/30

CPC分类号： C07D417/12 ,  C07D333/42

摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

摘要翻译： 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

公开(公告)号：US20100297808A1

公开(公告)日：2010-11-25

申请号：US12814742

申请日：2010-06-14

申请人： Hyoyoung LEE ,  Gyeong Sook BANG ,  Jonghyurk PARK ,  Junghyun LEE ,  Nak Jin CHOI ,  Ja Ryong KOO

发明人： Hyoyoung LEE ,  Gyeong Sook BANG ,  Jonghyurk PARK ,  Junghyun LEE ,  Nak Jin CHOI ,  Ja Ryong KOO

IPC分类号： H01L51/40

CPC分类号： H01L27/285 ,  B82Y10/00 ,  G11C11/14 ,  H01L51/0073 ,  H01L51/0595

摘要： Provided are a molecular electronic device and a method of fabricating the molecular electronic device. The molecular electronic device includes a substrate, an organic dielectric thin film formed over the substrate, a molecular active layer formed on the organic dielectric thin film and having a charge trap site, and an electrode formed on the molecular active layer. The organic dielectric thin film may be immobilized on the electrode or a Si layer by a self-assembled method. The organic dielectric thin film may include first and second molecular layers bound together through hydrogen bonds. An organic compound may be self-assembled over the substrate to form the organic dielectric thin film. The organic compound may include an M′-R-T structure, where M′, R and T represent a thiol or silane derivative, a saturated or unsaturated C1 to C20 hydrocarbon group which is substituted or unsubstituted with fluorine (F), and an amino(—NH2) or carboxyl (—COOH) group, respectively.

摘要翻译： 提供分子电子器件和制造分子电子器件的方法。 分子电子器件包括衬底，在衬底上形成的有机电介质薄膜，形成在有机电介质薄膜上并具有电荷陷阱位置的分子活性层和形成在分子活性层上的电极。 可以通过自组装方法将有机电介质薄膜固定在电极或Si层上。 有机电介质薄膜可以包括通过氢键结合在一起的第一和第二分子层。 有机化合物可以在衬底上自组装形成有机介电薄膜。 有机化合物可以包括M'-RT结构，其中M'，R和T表示硫醇或硅烷衍生物，被氟（F）取代或未取代的饱和或不饱和的C1至C20烃基和氨基（ -NH 2）或羧基（-COOH）基团。

公开(公告)号：US07420058B2

公开(公告)日：2008-09-02

申请号：US11602982

申请日：2006-11-22

申请人： Hyo Young Lee ,  Jung Hyun Lee ,  Gyeong Sook Bang ,  Nak Jin Choi ,  Jong Hyurk Park

发明人： Hyo Young Lee ,  Jung Hyun Lee ,  Gyeong Sook Bang ,  Nak Jin Choi ,  Jong Hyurk Park

IPC分类号： C07D401/14 ,  C07F15/00 ,  H05B33/14

CPC分类号： H01L51/0086 ,  G11C13/0014 ,  H01L27/285 ,  Y10S428/917

摘要： Provided are a compound for a molecular electronic device which includes a terpyridine-ruthenium organic metal compound including a thiol anchoring group of the formula below, a method of synthesizing the compound and a molecular electronic device including a molecular active layer obtained from the compound. In the formula, R1 and R2 are each a thioacetyl group or a hydrogen atom, at least one of R1 and R2 is a thioacetyl group, and m and n are each integers from 0 to 20. The molecular active layer, which is formed by self-assembling the compound on an electrode surface, composes a switching element and a memory element.

摘要翻译： 本发明提供一种分子电子器件的化合物，其包括三联吡啶 - 钌有机金属化合物，其包含下式的硫醇锚定基团，合成该化合物的方法和包含由该化合物获得的分子活性层的分子电子器件。 在该式中，R 1和R 2各自为硫代乙酰基或氢原子，R 1和R 2中的至少一个 > 2是硫代乙酰基，m和n各自为0〜20的整数。通过在电极表面上自组装化合物形成的分子活性层构成开关元件和存储元件 。

公开(公告)号：US20080054256A1

公开(公告)日：2008-03-06

申请号：US11760872

申请日：2007-06-11

申请人： Hyoyoung LEE ,  Gyeong Sook BANG ,  Jonghyurk PARK ,  Junghyun LEE ,  Nak Jin CHOI ,  Ja Ryong KOO

发明人： Hyoyoung LEE ,  Gyeong Sook BANG ,  Jonghyurk PARK ,  Junghyun LEE ,  Nak Jin CHOI ,  Ja Ryong KOO

IPC分类号： H01L51/30 ,  H01L51/40

CPC分类号： H01L27/285 ,  B82Y10/00 ,  G11C11/14 ,  H01L51/0073 ,  H01L51/0595

摘要： Provided are a molecular electronic device and a method of fabricating the molecular electronic device. The molecular electronic device includes a substrate, an organic dielectric thin film formed over the substrate, a molecular active layer formed on the organic dielectric thin film and having a charge trap site, and an electrode formed on the molecular active layer. The organic dielectric thin film may be immobilized on the electrode or a Si layer by a self-assembled method. The organic dielectric thin film may include first and second molecular layers bound together through hydrogen bonds. An organic compound may be self-assembled over the substrate to form the organic dielectric thin film. The organic compound may include an M′-R-T structure, where M′, R and T represent a thiol or silane derivative, a saturated or unsaturated C1 to C20 hydrocarbon group which is substituted or unsubstituted with fluorine (F), and an amino(—NH2) or carboxyl (—COOH) group, respectively.

摘要翻译： 提供分子电子器件和制造分子电子器件的方法。 分子电子器件包括衬底，在衬底上形成的有机电介质薄膜，形成在有机电介质薄膜上并具有电荷陷阱位置的分子活性层和形成在分子活性层上的电极。 可以通过自组装方法将有机电介质薄膜固定在电极或Si层上。 有机电介质薄膜可以包括通过氢键结合在一起的第一和第二分子层。 有机化合物可以在衬底上自组装形成有机介电薄膜。 有机化合物可以包括M'-RT结构，其中M'，R和T表示硫醇或硅烷衍生物，饱和或不饱和C 1至C 20烃 分别被氟（F）取代或未取代的基团和氨基（-NH 2/2）或羧基（-COOH）基团。

公开(公告)号：US07897735B2

公开(公告)日：2011-03-01

申请号：US12431651

申请日：2009-04-28

申请人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

发明人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

IPC分类号： C07C245/02

CPC分类号： C07D417/12 ,  C07D333/42

摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

摘要翻译： 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

公开(公告)号：US20090294762A1

公开(公告)日：2009-12-03

申请号：US12431651

申请日：2009-04-28

申请人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

发明人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

IPC分类号： H01L51/30 ,  C09B41/00

CPC分类号： C07D417/12 ,  C07D333/42

摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

摘要翻译： 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

公开(公告)号：US07538199B2

公开(公告)日：2009-05-26

申请号：US11398188

申请日：2006-04-04

申请人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

发明人： Hyoyoung Lee ,  Junghyun Lee ,  Heeyoel Baek ,  Gyeong Sook Bang ,  Jonghyurk Park ,  Nak-Jin Choi ,  Kun Jun ,  Seung Rim Shin

IPC分类号： C07C245/02

CPC分类号： C07D417/12 ,  C07D333/42

摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

摘要翻译： 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

公开(公告)号：US07419764B2

公开(公告)日：2008-09-02

申请号：US11505395

申请日：2006-08-17

申请人： Jong Hyurk Park ,  Hyo Young Lee ,  Nak Jin Choi ,  Jung Hyun Lee ,  Gyeong Sook Bang

发明人： Jong Hyurk Park ,  Hyo Young Lee ,  Nak Jin Choi ,  Jung Hyun Lee ,  Gyeong Sook Bang

IPC分类号： G03C5/00

CPC分类号： G03F7/0002 ,  B82Y10/00 ,  B82Y40/00 ,  G03F7/0035 ,  G03F9/00 ,  Y10S430/143

摘要： Provided is a method of fabricating a nanoimprint mold which can form sub-100 nm fine pattern structures. The method includes forming patterns on a first substrate using an E-beam lithography (EBL) process, and transferring the patterns formed on the first substrate to a second substrate using a nanoimprint lithography (NIL) process to complete an NIL mold. Accordingly, the method can easily fabricate the nanoimprint mold at low costs on a quartz or glass substrate, which is not suitable for an EBL process to produce sub-100 nm patterns, by utilizing the advantages of the EBL process with a resolution of tens of nanometers.

摘要翻译： 提供一种制造能够形成亚100nm精细图案结构的纳米压印模具的方法。 该方法包括使用电子束光刻（EBL）工艺在第一衬底上形成图案，并使用纳米压印光刻（NIL）工艺将形成在第一衬底上的图案转移到第二衬底以完成NIL模具。 因此，该方法可以容易地在石英或玻璃基板上以低成本制造纳米压印模具，其不适用于生产亚100nm图案的EBL工艺，通过利用具有数十个分辨率的EBL工艺的优点 纳米。