Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound
    4.
    发明授权
    Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound 失效
    具有硫醇锚定基团的化合物,其合成方法和使用该化合物形成分子活性层的分子电子器件

    公开(公告)号:US07897735B2

    公开(公告)日:2011-03-01

    申请号:US12431651

    申请日:2009-04-28

    IPC分类号: C07C245/02

    CPC分类号: C07D417/12 C07D333/42

    摘要: Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

    摘要翻译: 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物,合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团,在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

    MOLECULAR ELECTRONIC DEVICE INCLUDING PLURALITY OF MOLECULAR ACTIVE LAYERS AND METHOD OF MANUFACTURING THE MOLECULAR ELECTRONIC DEVICE
    5.
    发明申请
    MOLECULAR ELECTRONIC DEVICE INCLUDING PLURALITY OF MOLECULAR ACTIVE LAYERS AND METHOD OF MANUFACTURING THE MOLECULAR ELECTRONIC DEVICE 失效
    分子电子器件,包括分子活性层的多样性和制备分子电子器件的方法

    公开(公告)号:US20100019230A1

    公开(公告)日:2010-01-28

    申请号:US12365882

    申请日:2009-02-04

    IPC分类号: H01L51/30 H01L51/40

    摘要: Provided are a molecular electronic device including a functional molecular active layer having a stack structure including oppositely charged first and second molecular active layers, and a method of manufacturing the molecular electronic device. The molecular electronic device includes: a first electrode; an organic dielectric thin layer comprising molecules each having a first end self-assembled on a surface of the first electrode and a second end having a cationic or anionic group; a functional molecular active layer stacked on the organic dielectric thin layer by selective self-assembly with positive and negative ions and comprising an electroactive functional group having a cyclic compound; and a second electrode formed on the functional molecular active layer.

    摘要翻译: 提供一种分子电子器件,其包括具有包括相反电荷的第一和第二分子活性层的堆叠结构的功能分子活性层,以及制造该分子电子器件的方法。 分子电子器件包括:第一电极; 有机电介质薄层,其包含各自具有自组装在第一电极的表面上的第一端和具有阳离子或阴离子基团的第二端的分子; 功能性分子活性层,其通过与正离子和负离子的选择性自组装堆叠在有机电介质薄层上,并且包含具有环状化合物的电活性官能团; 和形成在功能分子活性层上的第二电极。

    COMPOUND HAVING THIOL ANCHORING GROUP, METHOD OF SYNTHESIZING THE SAME, AND MOLECULAR ELECTRONIC DEVICE HAVING MOLECULAR ACTIVE LAYER FORMED USING THE COMPOUND
    6.
    发明申请
    COMPOUND HAVING THIOL ANCHORING GROUP, METHOD OF SYNTHESIZING THE SAME, AND MOLECULAR ELECTRONIC DEVICE HAVING MOLECULAR ACTIVE LAYER FORMED USING THE COMPOUND 失效
    具有THIOL锚固组的化合物,其合成方法和具有使用化合物形成的分子活性层的分子电子装置

    公开(公告)号:US20090294762A1

    公开(公告)日:2009-12-03

    申请号:US12431651

    申请日:2009-04-28

    IPC分类号: H01L51/30 C09B41/00

    CPC分类号: C07D417/12 C07D333/42

    摘要: Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

    摘要翻译: 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物,合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团,在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

    Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound
    7.
    发明授权
    Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound 失效
    具有硫醇锚定基团的化合物,其合成方法和使用该化合物形成分子活性层的分子电子器件

    公开(公告)号:US07538199B2

    公开(公告)日:2009-05-26

    申请号:US11398188

    申请日:2006-04-04

    IPC分类号: C07C245/02

    CPC分类号: C07D417/12 C07D333/42

    摘要: Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.

    摘要翻译: 提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物,合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。 用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。 该化合物在分子电子器件中形成分子活性层。 使用偶氮化合物中的硫醇衍生物作为锚定基团,在电极上自组装分子活性层。 分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件 。

    Method for manufacturing organic molecular device
    8.
    发明授权
    Method for manufacturing organic molecular device 有权
    有机分子装置的制造方法

    公开(公告)号:US07510663B2

    公开(公告)日:2009-03-31

    申请号:US10727900

    申请日:2003-12-05

    IPC分类号: C23F1/00

    摘要: Disclosed is a method for manufacturing a conductive organic thin film device. An air-bridge type of an upper electrode is formed over a lower electrode by using a sacrificial layer and then a gap having a thickness of several nano meter is formed in a part at which the upper electrode and the lower electrode intersect by removing the sacrificial layer. The conductive organic molecules are uniformly adsorbed between the upper electrode and the lower electrode of the nano gap. Adsorption extent of the conductive organic molecules is confirmed by observing a current flowing through the upper and lower electrodes when the conductive organic molecules are adsorbed. Thus, reproducibility of a manufacturing process is improved and mass production is facilitated by adoption of a standardized process.

    摘要翻译: 公开了一种导电有机薄膜器件的制造方法。 通过使用牺牲层在下电极上形成上电极的气桥型,然后在上电极和下电极相交的部分中除去牺牲层,形成厚度为几纳米的间隙 层。 导电有机分子被均匀地吸附在纳米间隙的上电极和下电极之间。 当导电有机分子吸附时,通过观察流过上下电极的电流来确认导电有机分子的吸附程度。 因此,通过采用标准化方法,提高了制造工艺的再现性并促进了批量生产。

    MOLECULAR ELECTRONIC DEVICE INCLUDING ELECTRODE HAVING CONDUCTIVE POLYMER ELECTRODE LAYER
    9.
    发明申请
    MOLECULAR ELECTRONIC DEVICE INCLUDING ELECTRODE HAVING CONDUCTIVE POLYMER ELECTRODE LAYER 失效
    分子电子器件,包括具有导电聚合物电极层的电极

    公开(公告)号:US20080116451A1

    公开(公告)日:2008-05-22

    申请号:US11776917

    申请日:2007-07-12

    IPC分类号: H01L51/30

    摘要: Provided is a molecular electronic device including an electrode including a conductive polymer electrode layer. The molecular electronic device includes a first electrode; a functional molecular active layer, self-assembled on the first electrode, including an electroactive functional group having a cyclic compound; and a second electrode disposed on the functional molecular active layer. The second electrode includes a conductive polymer electrode layer contacting with the functional molecular active layer and a metal electrode layer disposed on the conductive polymer electrode layer. The conductive polymer electrode layer of the second electrode prevents damage to the functional molecular active layer, thereby preventing a short circuit in an ultra-thin molecular electronic device.

    摘要翻译: 提供一种分子电子器件,其包括具有导电聚合物电极层的电极。 分子电子器件包括第一电极; 功能性分子活性层,其自组装在第一电极上,包括具有环状化合物的电活性官能团; 以及设置在功能分子活性层上的第二电极。 第二电极包括与功能分子活性层接触的导电聚合物电极层和设置在导电聚合物电极层上的金属电极层。 第二电极的导电聚合物电极层防止对功能分子活性层的损害,从而防止超薄分子电子器件的短路。