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公开(公告)号：US5009971A
公开(公告)日：1991-04-23
申请号：US391067
申请日：1989-08-09
CPC分类号： H01M2/1646 , D04H1/4318 , H01M2/162 , H01M2300/0005 , Y10T428/259
摘要： Described is a porous flexible sheet of about 93 to 99.5 weight percent amorphous precipitated silica and from about 0.5 to about 7 weight percent fibrillated, unsintered polymeric material, e.g., polytetrafluoroethylene. The sheet is useful as a separator in absorbed electrolyte gas recombinant batteries, e.g., lead-acid batteries, and has a tensile strength of less than 75 pounds per square inch (0.5 MPa). The sheet preferably has a porosity of from 85 to 92 percent and exhibits an electrical resistance of less than 3.5 milliohm-in.sup.2 /10 mil when saturated with 37 percent sulfuric acid. The sheet is prepared by subjecting a dry homogeneous mixture of the silica and polymeric material, e.g., polytetrafluoroethylene, in the above proportions to mechanical shear blending forces to fibrillate the polymer and thereafter dry forming the resulting admixture into sheet form.
摘要翻译： 描述了约93至99.5重量％的无定形沉淀二氧化硅和约0.5至约7重量％原纤化的未烧结的聚合物材料例如聚四氟乙烯的多孔柔性片材。 该片材可用作吸收的电解质气体重组电池（例如铅酸电池）中的隔板，并且具有小于75磅/平方英寸（0.5MPa）的拉伸强度。 当用37％硫酸饱和时，片材优选具有85-92％的孔隙率并且表现出小于3.5毫欧姆/英寸2/10密耳的电阻。 通过以上述比例将二氧化硅和聚合物材料（例如聚四氟乙烯）的干均匀混合物经受机械剪切共混力使聚合物原纤化，然后将所得混合物干燥形成片状来制备片材。
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公开(公告)号：US4837253A
公开(公告)日：1989-06-06
申请号：US132398
申请日：1987-12-15
申请人： J. Douglas Mansell , Laurence E. Jones , Harlan B. Johnson , Thomas G. Krivak , Dennis W. Carson
发明人： J. Douglas Mansell , Laurence E. Jones , Harlan B. Johnson , Thomas G. Krivak , Dennis W. Carson
CPC分类号： C09D5/084 , C09C1/28 , C01P2002/02 , C01P2004/50 , C01P2004/60 , C01P2004/61 , C01P2004/80 , C01P2006/12 , C01P2006/19 , C01P2006/40 , C01P2006/80 , C01P2006/90
摘要： Corrosion inhibiting calcium-containing amorphous precipitated silica is described. The silica is prepared by admixing simultaneously in a reactor aqueous alkali metal silicate, e.g., sodium silicate, acidifying agent, e.g., hydrochloric acid, and a water-soluble source of calcium, e.g., calcium chloride. The product contains from 6 to 9 weight percent calcium (as CaO). The silica product may be incorporated into a coating composition used for corrodible metallic surfaces.
摘要翻译： 描述了抑制腐蚀性钙的无定形沉淀二氧化硅。 二氧化硅通过在反应器中碱金属硅酸盐例如硅酸钠，酸化剂，例如盐酸和钙的水溶性来源例如氯化钙同时混合来制备。 该产品含有6至9重量％的钙（如CaO）。 二氧化硅产品可以掺入用于可腐蚀金属表面的涂料组合物中。
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公开(公告)号：US4313813A
公开(公告)日：1982-02-02
申请号：US163120
申请日：1980-06-26
摘要： Disclosed is a method of electrolyzing alkali metal chloride brine between an anode and a cathode, with oxidant feed to the cathode, where the cathode is a bed of porous particles having HO.sub.2.sup.- disproportionation catalyst. Also disclosed is an electrolytic cell for carrying out the disclosed process.
摘要翻译： 公开了一种在阳极和阴极之间电解碱金属氯化物盐水的方法，氧化剂进料到阴极，其中阴极是具有HO 2 - 歧化催化剂的多孔颗粒床。 还公开了用于实施所公开的方法的电解池。
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公开(公告)号：US4253924A
公开(公告)日：1981-03-03
申请号：US88695
申请日：1979-10-26
申请人： Harlan B. Johnson
发明人： Harlan B. Johnson
摘要： Disclosed is a solid polymer electrolyte electrolytic cell where one member of the anode cathode electrode pair forms a solid polymer electrolyte with a permionic membrane, and the opposite member is spaced from the permionic membrane.
摘要翻译： 公开了一种固体聚合物电解质电解质电池，其中阳极阴极电极对的一个部件形成具有永久膜的固体聚合物电解质，并且相对的部件与永久膜隔开。
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公开(公告)号：US4101394A
公开(公告)日：1978-07-18
申请号：US774308
申请日：1977-03-04
申请人： Harlan B. Johnson
发明人： Harlan B. Johnson
摘要： Disclosed is a method of reducing the cathodic voltage of an electrolytic cell while electrolytically producing alcohols, aldehydes, acids, and ketones from peroxy bond-containing organic compounds such as peracids, peroxides, hydroperoxides, and derivatives thereof. According to the disclosed method, the peroxy bond-containing organic compound is fed to the catholyte compartment of an electrolytic cell and an aqueous chloride solution, e.g., sodium chloride or hydrochloric acid, is fed to the anolyte chamber of the cell while passing an electrical current from an anode of the cell to a cathode of the cell. Chlorine is recovered as the anodic product of the cell while the reaction products of the peroxy bond-containing organic compound are recovered as cathodic products. Also disclosed is a method of electrolyzing aqueous chloride solutions, e.g., sodium chloride solutions, and hydrochloric acid solutions at a reduced cell voltage. In addition to the steps of feeding the chloride solution to an electrolytic cell, passing an electrical current from an anode of the cell to the cathode of the cell, evolving chlorine on the anode of the cell, and recovering the chlorine gas from the anolyte chamber of the cell, the disclosed method also includes feeding an oxidant to the catholyte chamber of the cell and recovering cathodic reaction products of the oxidant, in addition to water and alkali metal hydroxides, from the catholyte chamber. Disclosed oxidants include organic compounds containing peroxy bonds such as peracids, peroxides, hydroperoxides, and their derivatives where the cathodic reaction products of the oxidant are alcohol, ketone, aldehyde, or acid corresponding to the peroxy-containing organic oxidant.
摘要翻译： 公开了一种降低电解槽的阴极电压的方法，同时电解产生含过氧键的有机化合物如过酸，过氧化氢及其衍生物的醇，醛，酸和酮。 根据所公开的方法，将含有过氧键的有机化合物进料到电解槽的阴极电解液室中，并将氯化钠或盐酸水溶液进料到电池的阳极电解液室，同时通过电 从电池的阳极到电池的阴极的电流。 回收氯作为电池的阳极产物，而含有过氧键的有机化合物的反应产物作为阴极产物回收。 还公开了以降低的电池电压电解氯化钠溶液，例如氯化钠溶液和盐酸溶液的方法。 除了将氯化物溶液供给到电解槽的步骤之外，将电流从电池的阳极传递到电池的阴极，在电池的阳极上放出氯，并从阳极电解液室回收氯气 所公开的方法还包括将氧化剂进料到电池的阴极电解液室中，并从阴极电解液室中回收除了水和碱金属氢氧化物之外的氧化剂的阴极反应产物。 公开的氧化剂包括含有过氧键的有机化合物，例如过酸，过氧化物，氢过氧化物及其衍生物，其中氧化剂的阴极反应产物是对应于过氧的有机氧化剂的醇，酮，醛或酸。
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公开(公告)号：US4040918A
公开(公告)日：1977-08-09
申请号：US661582
申请日：1976-02-26
摘要： Disclosed is an improved method of conducting electrolysis where a first electrode and a second electrode are inserted in an electrolyte, and an electrical current passes from one of the electrodes to the other electrode. At least one of the electrodes has an oxide coating formed in situ on an electroconductive substrate. According to the disclosed method, an external portion of the coating is abraded to expose an inner portion of the coating.
摘要翻译： 公开了一种改进的电解方法，其中第一电极和第二电极插入电解质中，并且电流从一个电极传递到另一个电极。 至少一个电极具有在导电基底上原位形成的氧化物涂层。 根据所公开的方法，将涂层的外部部分磨损以暴露涂层的内部。
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公开(公告)号：US5071645A
公开(公告)日：1991-12-10
申请号：US672252
申请日：1991-03-20
CPC分类号： C08J9/28 , A01N25/18 , A41G1/006 , A61K9/7007 , A61L9/042 , B29C55/005 , B29K2105/04 , C08J2201/0543 , C08J2201/0546 , C08J2323/02 , Y10S514/963
摘要： An active agent delivery device comprises (a) microporous material comprising a matrix consisting essentially of linear ultrahigh molecular weight polyolefin, a large proportion of finely divided water-insoluble filler of which at least about 50 percent by weight is siliceous, and interconnecting pores; and (b) a releasable active agent or precursor thereof associated with at least a portion of the filler.
摘要翻译： 活性剂递送装置包括（a）微孔材料，其包含基本上由线性超高分子量聚烯烃组成的基质，大部分细分散的水不溶性填充剂，其至少约50重量％是硅质的，以及互连孔; 和（b）与至少一部分填料相关联的可释放的活性剂或其前体。
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公开(公告)号：US4970020A
公开(公告)日：1990-11-13
申请号：US377676
申请日：1989-07-10
IPC分类号： C01B11/06
CPC分类号： C01B11/068
摘要： Granular calcium hypochlorite containing from about 0.001 to about 1.0 weight percent of finely-divided polyfluorinated polymer, e.g., polytetrafluoroethylene, dispersed throughout the granules is described. The product may be compressed and formed into shaped articles, e.g., tablets. The granules may be prepared by admixing the polyfluorinated polymer with particulate calcium hypochlorite, compacting the mixture and granulating the compacted product. Tablets prepared from the polyfluorinated polymer containing granular calcium hypochlorite dissolve in water at a rate slower than tablets prepared without the polyfluorinated polymer. Finely-divided calcium hypochlorite powder, e.g., powder of less than about 10 microns in size, is rendered more conveyable and compactible by the addition of the finely-divided polyfluorinated polymer; and mixtures of finely-divided calcium hypochlorite powder and particulate calcium hypochlorite is rendered more readily compactible.
摘要翻译： 描述了含有分散在整个颗粒中的约0.001至约1.0重量％的细碎多氟化聚合物（例如聚四氟乙烯）的颗粒状次氯酸钙。 产品可以被压缩并形成成型制品，例如片剂。 颗粒可以通过将多氟化聚合物与颗粒次氯酸钙混合来制备，压实混合物并造粒压实产物。 由含有颗粒次氯酸钙的多氟化聚合物制备的片剂以比没有多氟化聚合物制备的片剂慢的速率溶解在水中。 细碎的次氯酸钙粉末，例如尺寸小于约10微米的粉末，通过加入细碎的多氟化聚合物使其变得更可传送和可压实; 并且细分次氯酸钙粉末和颗粒次氯酸钙的混合物变得更容易压实。
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公开(公告)号：US4865760A
公开(公告)日：1989-09-12
申请号：US178180
申请日：1988-04-06
CPC分类号： C01B11/068
摘要： Granular calcium hypochlorite containing from about 0.001 to about 1.0 weight percent of finely-divided polyfluorinated polymer, e.g., polytetrafluoroethylene, dispersed throughout the granules is described. The product may be compressed and formed into shaped articles, e.g., tablets. The granules may be prepared by admixing the polyfluorinated polymer with particulate calcium hypochlorite, compacting the mixture and granulating the compacted product. Tablets prepared from the polyfluorinated polymer containing granular clacium hypochlorite dissolve in water at a rate slower than tablets prepared without the polyfluorinated polymer. Finely-divided calcium hypochlorite powder, e.g., powder of less than about 10 microns in size, is rendered more conveyable and compactible by the addition of the finely-divided polyfluorinated polymer; and mixtures of finely-divided calcium hypochlorite powder and particulate calcium hypochlorite is rendered more readily compactible.
摘要翻译： 描述了含有分散在整个颗粒中的约0.001至约1.0重量％的细碎多氟化聚合物（例如聚四氟乙烯）的颗粒状次氯酸钙。 产品可以被压缩并形成成型制品，例如片剂。 颗粒可以通过将多氟化聚合物与颗粒次氯酸钙混合来制备，压实混合物并造粒压实产物。 由含有颗粒状次氯酸盐的多氟化聚合物制备的片剂以比没有多氟化聚合物制备的片剂慢的速率溶解在水中。 细碎的次氯酸钙粉末，例如尺寸小于约10微米的粉末，通过加入细碎的多氟化聚合物使其变得更可传送和可压实; 并且细分次氯酸钙粉末和颗粒次氯酸钙的混合物变得更容易压实。
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10.发明授权Brine electrolysis using fixed bed oxygen depolarized cathode chlor-alkali cell 失效盐水电解采用固定床氧去极化阴极氯碱电池
公开(公告)号：US4244793A
公开(公告)日：1981-01-13
申请号：US82841
申请日：1979-10-09
摘要： Disclosed is a method of electrolyzing alkali metal chloride brine between an anode and a cathode, with oxidant feed to the cathode, where the cathode is a bed of porous particles having HO.sub.2.sup.31 disproportionation catalyst. Also disclosed is an electrolytic cell for carrying out the disclosed process.
摘要翻译： 公开了一种在阳极和阴极之间电解碱金属氯化物盐水的方法，其中氧化剂进料到阴极，阴极是具有HO231歧化催化剂的多孔颗粒床。 还公开了用于实施所公开的方法的电解池。
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