-
公开(公告)号：US4032498A
公开(公告)日：1977-06-28
申请号：US624545
申请日：1975-10-21
摘要： Flame-retardant PVC-plasticizers of the general formula (I) ##STR1## in which R stands for an alkylene radical or a halogen-substituted alkylene radical having from 2 to 6 carbon atoms, a --CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2 -- radical, a phenylene or an alkyl or halogenoalkyl-substituted diphenylenemethane radical and R.sub.1 stands for a branched or unbranched alkyl radical having from 6 to 18 carbon atoms.
-
公开(公告)号：US4324919A
公开(公告)日：1982-04-13
申请号：US183057
申请日：1980-09-02
申请人： Georg Elsner , Hartfrid Vollmer , Ernst Reutel
发明人： Georg Elsner , Hartfrid Vollmer , Ernst Reutel
IPC分类号： C07F9/50
CPC分类号： C07F9/5059
摘要： The invention relates to a process for making tertiary phosphines of the general formula R.sub.3 P, in which R stands for a linear alkyl radical having 2 to 4 carbon atoms. To this end, hydrogen phosphide is reacted with linear monoolefins having 2 to 4 carbon atoms. More particularly, the tertiary phosphine which is desired to be made is dissolved in an inert solvent and PH.sub.3 and monoolefin are reacted in the solution.
摘要翻译： 本发明涉及一种制备通式R3P的叔膦的方法，其中R代表具有2至4个碳原子的直链烷基。 为此，磷化氢与具有2至4个碳原子的直链单烯烃反应。 更具体地说，希望制备的叔膦溶于惰性溶剂中，PH3和单烯烃在溶液中反应。
-
公开(公告)号：US4091012A
公开(公告)日：1978-05-23
申请号：US780989
申请日：1977-03-24
IPC分类号： B01J27/00 , B01J31/00 , C07B61/00 , C07F9/53 , C07C120/00
CPC分类号： C07F9/5304
摘要： Production of tertiary phosphine oxides which contain nitrile groups and correspond to the following general formula I: ##STR1## in which R.sup.1 and R.sub.2 each stand for a straight or branched, identical or different alkyl, cycloalkyl, aryl, alkylaryl or aralkyl group having 1 to 18 carbon atoms, and in which R.sup.1 or R.sub.2 may be identical with R, which stands for a radical of the following general formula II: ##STR2## in which R.sup.3 and R.sup.4 each stand for a straight or branched, identical or different alkyl, cycloalkyl, aryl, alkylaryl or aralkyl group having 1 to 18 carbon atoms, and/or hydrogen atoms. The tertiary phosphine oxides are made by reacting a phosphine of the following general formula III: ##STR3## in which R.sup.5 has the same meaning as R.sup.3 and R.sup.6 has the same meaning as R.sup.4 but is no hydrogen, with an .alpha.,.beta.-unsaturated nitrile of the following general formula IV: ##STR4## in which R.sup.3 and R.sup.4 have the meanings given above. The reaction is effected in a single stage in the presence of water or a water-solvent mixture and the above formula I compounds are separated from the reaction product.
摘要翻译： 制备含有腈基并且对应于以下通式I的叔膦氧化物：其中R 1和R 2各自表示直链或支链，相同或不同的具有1个碳原子的烷基，环烷基，芳基，烷基芳基或芳烷基 至18个碳原子，其中R 1或R 2可以与R相同，其代表下列通式II的基团：其中R 3和R 4各自代表直链或支链，相同或不同的烷基 ，具有1至18个碳原子的环烷基，芳基，烷基芳基或芳烷基，和/或氢原子。 叔膦氧化物通过使下列通式III的膦：其中R 5具有与R 3相同的含义，R 6具有与R 4相同的含义，但不具有氢，具有α，β-不饱和的 腈，其中R 3和R 4具有上述含义。 反应在水或水 - 溶剂混合物存在下在单一阶段进行，并且上述式I化合物与反应产物分离。
-
公开(公告)号：US4351960A
公开(公告)日：1982-09-28
申请号：US190448
申请日：1980-09-24
申请人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
发明人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5018
摘要： The invention relates to a process for making an isomeric mixture of secondary phosphines with the summation formula C.sub.20 H.sub.27 P. To this end, hydrogen phosphide is reacted with dicyclopentadiene in the presence of an agent yielding free radicals. More specifically, hydrogen phosphide and dicyclopentadiene are used in a molar ratio of 1 to at least 2 and the reaction is effected under a pressure of 5 to 90 bars. The mixture is used in the production of flotation aids and as an ingredient of catalytically active transition metal complexes.
摘要翻译： 本发明涉及一种制备仲膦与异构体混合物的方法，其中R为总和式C20H27P。 为此，在产生自由基的试剂存在下，磷化氢与二环戊二烯反应。 更具体地，使用磷化氢和二环戊二烯的摩尔比为1至至少2，反应在5至90巴的压力下进行。 该混合物用于生产浮选助剂和作为催化活性过渡金属络合物的成分。
-
公开(公告)号：US3998764A
公开(公告)日：1976-12-21
申请号：US521501
申请日：1974-11-06
CPC分类号： C08G79/04 , C07F9/091 , C07F9/093 , C08G18/5084
摘要： Production of agents reducing the flammability of polyurethane moulding compositions. The agents are more particularly comprised of compounds of the following general formula (I) ##STR1## IN WHICH R stands for an alkylene radical having from 2 to 6 carbon atoms, which may be halogen-substituted, if desired, a --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 -- radical, a phenylene radical or an alkyl- or halogenoalkyl-substituted diphenylene methane radical, R.sub.1 and R.sub.2, respectively, stand for a hydrogen atom, an alkyl radical or a halogen-substituted alkyl radical having from 1 to 4 carbon atoms, x + y stand for a number between 0.1 and 3, and n stands for 1 or 2.
摘要翻译： 生产降低聚氨酯模塑组合物的可燃性的试剂。 这些试剂更具体地由以下通式（I）的化合物组成：其中R代表具有2至6个碳原子的亚烷基，如果需要可以被卤素取代 ，-CH 2 -CH 2 -O-CH 2 -CH 2 - 基，亚苯基或烷基 - 或卤代烷基取代的亚苯基甲烷基，R 1和R 2分别代表氢原子，烷基或卤素取代 具有1至4个碳原子的烷基，x + y表示0.1至3之间的数，n表示1或2。
-
公开(公告)号：US3978170A
公开(公告)日：1976-08-31
申请号：US521529
申请日：1974-11-06
摘要： Production of polyols containing halogen and phosphorus. The polyols are more particularly comprised of compounds the following general formula (I) ##EQU1## in which R stands for an alkylene radical having from 2 to 6 carbon atoms, which may be halogen-substituted, if desired, a --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 -- radical, a phenylene radical or an alkyl- or halogenoalkyl-substituted diphenylene methane radical, R.sub.1 and R.sub.2, respectively stand for a hydrogen atom, an alkyl radical or a halogen-substituted alkyl radical having from 1 to 4 carbon atoms, x + y stand for a number between 0.1 and 3, and n stands for 1 or 2. The polyols find use as flameproofing agents in plastics, particularly in polyurethane foams.
-
公开(公告)号：US4156697A
公开(公告)日：1979-05-29
申请号：US823140
申请日：1977-08-09
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines of the general formula:R.sub.n PH.sub.3-n (I)are made. To this end hydrogen phosphide, a primary or a secondary phosphine is reacted with an alkylamine of the general formula:R.sub.n NH.sub.3-n (II)in a molar ratio of 0.1 to 10 mols of the alkylamine of formula II per mol of hydrogen phosphide or primary or secondary phosphine. The reaction is effected at a 150.degree. to 400.degree. C., at atmospheric pressure or a superatmospheric pressure up to 1 atmosphere gauge, and in contact with a catalyst comprising active carbon, copper (II) chromite, or one or more metals of Group Ib or VIII of the Periodic System of the elements. The starting materials are passed through a reaction zone at a rate which permits a contact time between them and the catalyst of 0.1 to 400 seconds.
摘要翻译： 具有以下通式的烷基膦：
-
公开(公告)号：US4118590A
公开(公告)日：1978-10-03
申请号：US736092
申请日：1976-10-27
申请人： Hartfrid Vollmer , Klaus Hestermann
发明人： Hartfrid Vollmer , Klaus Hestermann
IPC分类号： C07F9/54 , D06M13/282 , D06M13/285 , D06M13/46
CPC分类号： D06M13/46 , C07F9/5407 , D06M13/282 , D06M13/285
摘要： Production of novel phosphobetaines of general formula I ##STR1## in which R.sup.1 and R.sup.2 each stand for organic groups having from 1 to 18 carbon atoms, and R.sup.1 or R.sup.2 may be identical with the substituent R, the substituent R being a radical of the general formula II ##STR2## in which R.sup.3 and R.sup.4 each stand for organic groups having from 1 to 18 carbon atoms, and/or hydrogen atoms, and R.sup.5 stands for a linear or branched alkyl group having from 1 to 4 carbon atoms, which may optionally have a halogen or hydroxylic group substituent attached thereto.
摘要翻译： 制备通式I的新型磷酸甜菜碱，其中R 1和R 2各自代表具有1至18个碳原子的有机基团，并且R 1或R 2可以与取代基R相同，取代基R是 通式II其中R 3和R 4各自代表具有1至18个碳原子的有机基团和/或氢原子，R 5代表具有1至4个碳原子的直链或支链烷基，其中 可以任选地具有连接到其上的卤素或羟基取代基。
-
公开(公告)号：US4061696A
公开(公告)日：1977-12-06
申请号：US727459
申请日：1976-09-28
CPC分类号： C08G79/04 , C07F9/091 , C08G18/5084
摘要： Production of agents reducing the flammability of polyurethane moulding compositions. The agents are more particularly comprised of compounds of the following general formula (I) ##STR1## in which R stands for an alkylene radical having from 2 to 6 carbon atoms, which may be halogen-substituted, if desired, a --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 -- radical, a phenylene radical or an alkyl- or halogenoalkyl-substituted diphenylene methane radical, R.sub.1 and R.sub.2, respectively, stand for a hydrogen atom, an alkyl radical or a halogen-substituted alkyl radical having from 1 to 4 carbon atoms, x + y stand for a number between 0.1 and 3, and n stands for 1 or 2.
摘要翻译： 生产降低聚氨酯模塑组合物的可燃性的试剂。 这些试剂更具体地由以下通式（I）的化合物组成：其中R代表具有2至6个碳原子的亚烷基，如果需要可以被卤素取代 ，-CH 2 -CH 2 -O-CH 2 -CH 2 - 基，亚苯基或烷基 - 或卤代烷基取代的亚苯基甲烷基，R 1和R 2分别代表氢原子，烷基或卤素取代 具有1至4个碳原子的烷基，x + y表示0.1至3之间的数，n表示1或2。
-
公开(公告)号：US4029721A
公开(公告)日：1977-06-14
申请号：US624546
申请日：1975-10-21
摘要： Halogen-containing phosphoric acid polyesters of the general formula (I) ##STR1## IN WHICH R stands for an alkylene radical or a halogen-substituted alkylene radical having from 2 to 6 carbon atoms, a --CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2 -- radical, a phenylene or an alkyl or halogenoalkyl-substituted diphenylenemethane radical, and R.sub.1 stands for a branched or unbranched alkyl radical having from 6 to 18 carbon atoms.
摘要翻译： 通式（I）的含卤素的磷酸聚酯，其中R表示具有2至6个碳原子的亚烷基或卤素取代的亚烷基，-CH 2 CH 2 -O-CH 2 CH 2 - 基， 亚苯基或烷基或卤代烷基取代的二苯基甲烷基，R1代表具有6至18个碳原子的支链或非支链烷基。
-
-
-
-
-
-
-
-
-
搜索结果
11 条记录 (耗时 0.01 秒)