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    Process for producing the ion-sensitive probe electrode of a heavy-metal-ion sensor
    3.
    发明授权
    Process for producing the ion-sensitive probe electrode of a heavy-metal-ion sensor 失效
    用于生产重金属离子传感器的离子敏感探针电极的方法

    公开(公告)号：US5262205A

    公开(公告)日：1993-11-16

    申请号：US886229

    申请日：1992-05-20

    Applicant: Volker Leonhard ,  Hartmut Erdmann ,  Wing F. Chu

    Inventor： Volker Leonhard ,  Hartmut Erdmann ,  Wing F. Chu

    IPC: G01N27/333 ,  G01N27/403 ,  G05D1/36 ,  B05D5/12

    CPC classification number: G01N27/333

    Abstract: A method of producing an ion sensitive working electrode for a heavy metal ion sensor, the ion sensitive working electrode including a mixture of Ag.sub.2 S and MeS in which Me represents a heavy metal to be determined in a solution to be measured, the method including applying a conductive layer onto a substrate using at least one thick-film technique selected from the group consisting essentially of screen printing and film casting; applying a layer comprised of a plurality of juxtaposed sections on top of the conductive layer, each section of the plurality of juxtaposed sections being comprised of a mixture of Ag.sub.2 S and MeS, with each section of the plurality of juxtaposed sections containing a different heavy metal, Me; and applying a covering layer on top of the layer comprised of a plurality of juxtaposed sections and on top of at least a portion of the conductive layer, which portion of the conductive layer will contact the solution to be measured in use whereby the covering layer protects the conductive layer from the solution to be measured in use, the covering layer having defined therein a plurality of window regions, one window region for each section of the plurality of juxtaposed sections, whereby the solution to be measured in use is provided access to the layer comprised of a plurality of juxtaposed sections.

    Abstract translation: 一种重金属离子传感器的离子敏感性工作电极的制造方法，所述离子敏感性工作电极包括Ag2S和MeS的混合物，其中Me表示待测溶液中测定的重金属，所述方法包括： 导电层使用至少一种选自丝网印刷和膜铸造的厚膜技术在基底上; 将由多个并置部分组成的层施加在导电层的顶部上，多个并置部分的每个部分由Ag 2 S和MeS的混合物组成，多个并置部分的每个部分含有不同的重金属， 我; 并且在由多个并置部分组成的层的顶部上施加覆盖层，并且在导电层的至少一部分的顶部上，导电层的哪一部分将在使用中与待测量的溶液接触，由此覆盖层保护 来自待测溶液的导电层，所述覆盖层在其中限定有多个窗口区域，所述多个并置部分的每个部分的一个窗口区域，由此在使用中待测量的溶液被提供到 层由多个并列部分组成。

    Solid electrolyte sensor for measuring gaseous anhydrides
    4.
    发明授权
    Solid electrolyte sensor for measuring gaseous anhydrides 失效
    用于测量气态酸酐的固体电解质传感器

    公开(公告)号：US06203678B1

    公开(公告)日：2001-03-20

    申请号：US08776389

    申请日：1998-10-13

    Applicant: Volker Leonhard ,  Ulrich Guth ,  Hartmut Erdmann ,  Marianne Ilgenstein ,  Heidrun Koppen ,  Dieter Fischer

    Inventor： Volker Leonhard ,  Ulrich Guth ,  Hartmut Erdmann ,  Marianne Ilgenstein ,  Heidrun Koppen ,  Dieter Fischer

    IPC: G01N27407

    CPC classification number: G01N27/4074 ,  G01N27/4114

    Abstract: A galvanic solid electrolyte sensor for measuring gaseous anhydrides includes a ceramic solid electrolyte that has a material that conducts electrons, a measuring electrode that includes a pure or doped alkaline or alkaline earth salt and a reference electrode spatially separated from the measuring electrode and sealed off from the anhydride measuring gas by a gas-tight enclosure. The reference electrode is made of a metal material that conducts electrons. The gas-tight enclosure is made of a layer of a glass containing zirconium and lead that covers only the material of the reference electrode, with only a marginal area of this layer abutting the solid electrolyte.

    Abstract translation: 用于测量气态酸酐的电流固体电解质传感器包括具有传导电子的材料的陶瓷固体电解质，包含纯或掺杂的碱金属或碱土金属盐的测量电极以及与测量电极在空间上分离的参考电极， 酸酐测量气体由气密的外壳。 参考电极由传导电子的金属材料制成。 气密外壳由含有锆和铅的玻璃层制成，仅覆盖参比电极的材料，只有该层的边缘区域与固体电解质相邻。

    Solid state electrode for the determination of sodium ion concentrations in solutions
    5.
    发明授权
    Solid state electrode for the determination of sodium ion concentrations in solutions 失效
    用于确定溶液中钠离子浓度的固态电极

    公开(公告)号：US5122254A

    公开(公告)日：1992-06-16

    申请号：US348013

    申请日：1989-01-23

    Applicant: Sonja Ammende ,  Hartmut Erdmann ,  Heinz-Werner Etzkorn ,  Klaus Zucholl

    Inventor： Sonja Ammende ,  Hartmut Erdmann ,  Heinz-Werner Etzkorn ,  Klaus Zucholl

    IPC: G01N27/333 ,  G01N27/416

    CPC classification number: G01N27/333

    Abstract: A solid state electrode for the determination of sodium ion concentrations in solutions, with a solid state electrolyte having a high conductivity for sodium ions being provided as the sodium sensitive membrane. The solid state electrode and a reference electrode forms a sensor.The advantages of the sensor of invention are, in particular, high selectivity combined with economical production in thick-film technology. The sensor may be constructed in cylindridcal form.

    Abstract translation: 提供用于测定溶液中的钠离子浓度的固态电极，其中提供具有用于钠离子的高导电性的固态电解质作为敏感膜。 固态电极和参考电极形成传感器。 本发明的传感器的优点特别是高选择性与厚膜技术的经济生产相结合。 传感器可以以圆柱形的形式构造。

    Method for making a sensor for monitoring hydrogen concentrations in gases
    6.
    发明授权
    Method for making a sensor for monitoring hydrogen concentrations in gases 失效
    制造用于监测气体中氢气浓度的传感器的方法

    公开(公告)号：US4976991A

    公开(公告)日：1990-12-11

    申请号：US426276

    申请日：1989-10-25

    Applicant: Sonya Ammende ,  Hartmut Erdmann ,  Heinz-Werner Etzkorn ,  Klaus Zucholl

    Inventor： Sonya Ammende ,  Hartmut Erdmann ,  Heinz-Werner Etzkorn ,  Klaus Zucholl

    IPC: B05D5/12 ,  G01N27/407 ,  G01N27/417

    CPC classification number: G01N27/4074

    Abstract: A sensor for monitoring hydrogen concentrations in gases, containing a solid electrolyte body, a detector electrode having a surface which is exposable to a gas to be monitored, and a reference electrode, in which the reference and detector electrodes make contact with the solid electrolyte, and the detector electrode contains a platinum metal or a platinum metal oxide. A method of making the sensor is also disclosed.

    Abstract translation: 一种用于监测含有固体电解质体的气体中的氢浓度的传感器，具有可暴露于待监测气体的表面的检测器电极和参考电极，其中参考电极和检测器电极与固体电解质接触， 并且检测器电极含有铂金属或铂金属氧化物。 还公开了制造传感器的方法。

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