公开(公告)号：US5432240A

公开(公告)日：1995-07-11

申请号：US190899

申请日：1994-02-03

申请人： Masahiro Tsumura ,  Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii

发明人： Masahiro Tsumura ,  Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii

IPC分类号： C08G8/28 ,  C08G10/04 ,  C08G14/04 ,  C08L61/14 ,  C08L63/00 ,  H01B3/36 ,  C08G8/10 ,  C08G2/08 ,  C08G2/10 ,  C08G8/20

CPC分类号： H01B3/36 ,  C08G10/04 ,  C08G14/04 ,  C08G8/28 ,  C08L61/14 ,  C08L63/00

摘要： A process for producing a modified phenolic resin comprises heating (a) petroleum heavy oil or pitch and (b) a formaldehyde polymer in a molar ratio of formaldehyde:oil or pitch of from 1 to 15:1 in the presence of an acid catalyst, adding phenol in a molar ratio of phenol:oil or pitch of from 0.5 to 5:1 to form a crude modified phenolic resin, and purifying by performing in optional sequence (i) a treatment with an aliphatic or alicyclic hydrocarbon to remove unreacted components and (ii) an extraction with a solvent wherein the catalyst has a solubility of 0.1 or less to remove the catalyst.

摘要翻译： 一种改性酚醛树脂的制备方法包括：在酸催化剂存在下，加热（a）石油重油或沥青和（b）甲醛：油或沥青的摩尔比为1〜15:1的甲醛聚合物， 以苯酚：油或沥青的摩尔比加入苯酚为0.5〜5:1，形成粗改性酚醛树脂，通过任选的顺序（i）用脂族或脂环族烃处理以除去未反应的组分和 （ii）用溶剂萃取，其中催化剂的溶解度为0.1以下以除去催化剂。

公开(公告)号：US5484854A

公开(公告)日：1996-01-16

申请号：US417779

申请日：1995-04-06

申请人： Masahiro Tsumura ,  Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii

发明人： Masahiro Tsumura ,  Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii

IPC分类号： C08G8/28 ,  C08G10/04 ,  C08G14/04 ,  C08L61/14 ,  C08L63/00 ,  H01B3/36 ,  C08L61/10 ,  C08L63/02 ,  C08L63/04

CPC分类号： H01B3/36 ,  C08G10/04 ,  C08G14/04 ,  C08G8/28 ,  C08L61/14 ,  C08L63/00

摘要： A molding material useful in the fabrication of an electrical or electronic part comprises a modified phenolic resin (A), an epoxy resin (B) and a curing agent (C), said modified phenolic resin prepared by heating heavy oil or pitch and a formaldehyde in a molar ratio of formaldehyde: (oil or pitch) of from 1-15:1 in the presence of an acid catalyst, adding phenol in a molar ratio of phenol: (oil or pitch) of from 0.5-5:1 to form a modified phenolic resin, and purifying by performing in optional sequence (i) a treatment with an aliphatic or alicyclic hydrocarbon and (ii) an extraction with an aromatic hydrocarbon solvent wherein the catalyst has a solubility of 0.1 or less to remove the catalyst.

摘要翻译： 用于制造电气或电子部件的成型材料包括改性酚醛树脂（A），环氧树脂（B）和固化剂（C）），所述改性酚醛树脂通过加热重油或沥青和甲醛 在酸催化剂存在下，甲醛摩尔比（油或沥青）为1-15：1，加入苯酚：（油或沥青）摩尔比为0.5-5:1的苯酚形成 改性酚醛树脂，并通过以任选的顺序（i）用脂族或脂环族烃处理和（ii）用芳烃溶剂萃取进行纯化，其中催化剂的溶解度为0.1以下以除去催化剂。

公开(公告)号：US6034210A

公开(公告)日：2000-03-07

申请号：US24454

申请日：1998-02-17

申请人： Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii ,  Tatsushi Ishizuka ,  Makoto Hasegawa

发明人： Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii ,  Tatsushi Ishizuka ,  Makoto Hasegawa

IPC分类号： C08G8/00 ,  C08G8/28 ,  C08G16/00 ,  C08L61/06 ,  C08L61/14 ,  C08L63/00 ,  C08L91/00 ,  C08L95/00 ,  H01B3/36 ,  C08G59/62 ,  H01L23/29 ,  H01L23/31

CPC分类号： H01B3/36 ,  C08G16/00 ,  C08G8/00 ,  C08G8/28 ,  C08L61/06 ,  C08L61/14 ,  C08L63/00 ,  C08L91/00 ,  C08L95/00

摘要： Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.

摘要翻译： 公开了一种制备高反应性改性酚醛树脂的方法，其包括将重油或沥青与0.3至10mol苯酚，以甲醛计为0.2-9mol，甲醛化合物和0.01-3.0mol 酸催化剂，每个量基于由平均分子量计算的1摩尔重油或沥青; 并在搅拌下加热所得混合物，从而使重油或沥青，苯酚和甲醛化合物缩聚。 根据本发明，可以提供在一个步骤中简单且稳定地制备具有低熔体粘度，优异的耐热性和与环氧树脂的高反应性的高反应性改性酚醛树脂的方法。

公开(公告)号：US6166131A

公开(公告)日：2000-12-26

申请号：US401491

申请日：1999-09-22

申请人： Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii ,  Tatsushi Ishizuka ,  Makoto Hasegawa

发明人： Masao Tashima ,  Hiromi Miyasita ,  Haruhiko Takeda ,  Tomoaki Fujii ,  Tatsushi Ishizuka ,  Makoto Hasegawa

IPC分类号： C08G8/00 ,  C08G8/28 ,  C08G16/00 ,  C08L61/06 ,  C08L61/14 ,  C08L63/00 ,  C08L91/00 ,  C08L95/00 ,  H01B3/36 ,  C08G63/48 ,  C08G63/91

CPC分类号： H01B3/36 ,  C08G8/00 ,  C08G8/28 ,  C08G16/00 ,  C08L61/06 ,  C08L61/14 ,  C08L63/00 ,  C08L91/00 ,  C08L95/00 ,  C08L2666/22 ,  C08L2666/02

摘要： Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.

摘要翻译： 公开了一种制备高反应性改性酚醛树脂的方法，该方法包括将重油或沥青与0.3至10摩尔酚，0.2-9摩尔甲醛化合物和0.01至3.0摩尔的 酸催化剂，每个量基于由平均分子量计算的1摩尔重油或沥青; 并在搅拌下加热所得混合物，从而使重油或沥青，苯酚和甲醛化合物缩聚。 根据本发明，可以提供在一个步骤中简单且稳定地制备具有低熔体粘度，优异的耐热性和与环氧树脂的高反应性的高反应性改性酚醛树脂的方法。