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1.发明授权
公开(公告)号：US5432240A
公开(公告)日：1995-07-11
申请号：US190899
申请日：1994-02-03
IPC分类号： C08G8/28 , C08G10/04 , C08G14/04 , C08L61/14 , C08L63/00 , H01B3/36 , C08G8/10 , C08G2/08 , C08G2/10 , C08G8/20
摘要： A process for producing a modified phenolic resin comprises heating (a) petroleum heavy oil or pitch and (b) a formaldehyde polymer in a molar ratio of formaldehyde:oil or pitch of from 1 to 15:1 in the presence of an acid catalyst, adding phenol in a molar ratio of phenol:oil or pitch of from 0.5 to 5:1 to form a crude modified phenolic resin, and purifying by performing in optional sequence (i) a treatment with an aliphatic or alicyclic hydrocarbon to remove unreacted components and (ii) an extraction with a solvent wherein the catalyst has a solubility of 0.1 or less to remove the catalyst.
摘要翻译： 一种改性酚醛树脂的制备方法包括：在酸催化剂存在下，加热（a）石油重油或沥青和（b）甲醛：油或沥青的摩尔比为1〜15:1的甲醛聚合物， 以苯酚：油或沥青的摩尔比加入苯酚为0.5〜5:1，形成粗改性酚醛树脂，通过任选的顺序（i）用脂族或脂环族烃处理以除去未反应的组分和 （ii）用溶剂萃取，其中催化剂的溶解度为0.1以下以除去催化剂。
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2.发明授权
公开(公告)号：US5484854A
公开(公告)日：1996-01-16
申请号：US417779
申请日：1995-04-06
IPC分类号： C08G8/28 , C08G10/04 , C08G14/04 , C08L61/14 , C08L63/00 , H01B3/36 , C08L61/10 , C08L63/02 , C08L63/04
摘要： A molding material useful in the fabrication of an electrical or electronic part comprises a modified phenolic resin (A), an epoxy resin (B) and a curing agent (C), said modified phenolic resin prepared by heating heavy oil or pitch and a formaldehyde in a molar ratio of formaldehyde: (oil or pitch) of from 1-15:1 in the presence of an acid catalyst, adding phenol in a molar ratio of phenol: (oil or pitch) of from 0.5-5:1 to form a modified phenolic resin, and purifying by performing in optional sequence (i) a treatment with an aliphatic or alicyclic hydrocarbon and (ii) an extraction with an aromatic hydrocarbon solvent wherein the catalyst has a solubility of 0.1 or less to remove the catalyst.
摘要翻译： 用于制造电气或电子部件的成型材料包括改性酚醛树脂（A），环氧树脂（B）和固化剂（C）），所述改性酚醛树脂通过加热重油或沥青和甲醛 在酸催化剂存在下，甲醛摩尔比（油或沥青）为1-15：1，加入苯酚：（油或沥青）摩尔比为0.5-5:1的苯酚形成 改性酚醛树脂，并通过以任选的顺序（i）用脂族或脂环族烃处理和（ii）用芳烃溶剂萃取进行纯化，其中催化剂的溶解度为0.1以下以除去催化剂。
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3.发明授权Highly reactive modified phenolic resin and molding material for electrical/electronic parts and semiconductor sealing material 失效高反应性改性酚醛树脂和电子/电子部件和半导体密封材料的成型材料
公开(公告)号：US6166131A
公开(公告)日：2000-12-26
申请号：US401491
申请日：1999-09-22
申请人： Masao Tashima , Hiromi Miyasita , Haruhiko Takeda , Tomoaki Fujii , Tatsushi Ishizuka , Makoto Hasegawa
发明人： Masao Tashima , Hiromi Miyasita , Haruhiko Takeda , Tomoaki Fujii , Tatsushi Ishizuka , Makoto Hasegawa
IPC分类号： C08G8/00 , C08G8/28 , C08G16/00 , C08L61/06 , C08L61/14 , C08L63/00 , C08L91/00 , C08L95/00 , H01B3/36 , C08G63/48 , C08G63/91
CPC分类号： H01B3/36 , C08G8/00 , C08G8/28 , C08G16/00 , C08L61/06 , C08L61/14 , C08L63/00 , C08L91/00 , C08L95/00 , C08L2666/22 , C08L2666/02
摘要： Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.
摘要翻译： 公开了一种制备高反应性改性酚醛树脂的方法，该方法包括将重油或沥青与0.3至10摩尔酚，0.2-9摩尔甲醛化合物和0.01至3.0摩尔的 酸催化剂，每个量基于由平均分子量计算的1摩尔重油或沥青; 并在搅拌下加热所得混合物，从而使重油或沥青，苯酚和甲醛化合物缩聚。 根据本发明，可以提供在一个步骤中简单且稳定地制备具有低熔体粘度，优异的耐热性和与环氧树脂的高反应性的高反应性改性酚醛树脂的方法。
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4.发明授权Process for producing highly reactive modified phenolic resin and molding material 失效生产高反应性改性酚醛树脂和成型材料的方法
公开(公告)号：US6034210A
公开(公告)日：2000-03-07
申请号：US24454
申请日：1998-02-17
申请人： Masao Tashima , Hiromi Miyasita , Haruhiko Takeda , Tomoaki Fujii , Tatsushi Ishizuka , Makoto Hasegawa
发明人： Masao Tashima , Hiromi Miyasita , Haruhiko Takeda , Tomoaki Fujii , Tatsushi Ishizuka , Makoto Hasegawa
IPC分类号： C08G8/00 , C08G8/28 , C08G16/00 , C08L61/06 , C08L61/14 , C08L63/00 , C08L91/00 , C08L95/00 , H01B3/36 , C08G59/62 , H01L23/29 , H01L23/31
CPC分类号： H01B3/36 , C08G16/00 , C08G8/00 , C08G8/28 , C08L61/06 , C08L61/14 , C08L63/00 , C08L91/00 , C08L95/00
摘要： Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.
摘要翻译： 公开了一种制备高反应性改性酚醛树脂的方法，其包括将重油或沥青与0.3至10mol苯酚，以甲醛计为0.2-9mol，甲醛化合物和0.01-3.0mol 酸催化剂，每个量基于由平均分子量计算的1摩尔重油或沥青; 并在搅拌下加热所得混合物，从而使重油或沥青，苯酚和甲醛化合物缩聚。 根据本发明，可以提供在一个步骤中简单且稳定地制备具有低熔体粘度，优异的耐热性和与环氧树脂的高反应性的高反应性改性酚醛树脂的方法。
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公开(公告)号：US5521259A
公开(公告)日：1996-05-28
申请号：US377347
申请日：1995-01-24
申请人： Masahiro Tsumura , Masao Tashima , Hiromi Miyasita
发明人： Masahiro Tsumura , Masao Tashima , Hiromi Miyasita
IPC分类号： C08G8/28 , C08G10/04 , C08G14/04 , C08L61/14 , C08L63/00 , H01B3/36 , C08L61/04 , C08L59/02 , C08L59/04
摘要： A process for producing a highly reactive modified phenolic resin, comprising the steps of polycondensing a petroleum heavy oil or pitch, a formaldehyde polymer and a phenol in the presence of an acid catalyst to thereby prepare a modified phenolic resin; and reacting the resultant modified phenolic resin with a phenol in the presence of an acid catalyst but in the absence of a crosslinking agent such as a formaldehyde polymer to thereby lower the molecular weight of the modified phenolic resin. This highly reactive modified phenolic resin has a low number average molecular weight and a high phenol content, so that its resin melt viscosity is low and that it exhibits a markedly improved reactivity with an epoxy resin. Accordingly, the combination thereof with an epoxy resin provides a molding material suitable for producing a molding which is excellent in not only thermal resistance and moldability but also dimensional stability and other mechanical properties, especially a material for electrical or electronic part and a semiconductor sealer.
摘要翻译： 一种生产高反应性改性酚醛树脂的方法，包括在酸催化剂存在下使石油重油或沥青，甲醛聚合物和苯酚缩聚的步骤，从而制备改性酚醛树脂; 在酸催化剂的存在下，使所得的改性酚醛树脂与酚反应，但不存在交联剂如甲醛聚合物，从而降低改性酚醛树脂的分子量。 该高反应性改性酚醛树脂具有低的数均分子量和高的苯酚含量，使得其树脂熔体粘度低，并且显示出与环氧树脂显着改善的反应性。 因此，其与环氧树脂的组合提供了适合于制造不仅耐热性和成型性优异的成型材料，而且尺寸稳定性和其它机械性能，特别是电气或电子部件的材料和半导体封口剂的成型材料。
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6.发明授权
公开(公告)号：US5936010A
公开(公告)日：1999-08-10
申请号：US061324
申请日：1998-04-17
摘要： A process for producing a highly reactive low-viscosity modified phenolic resin comprising the steps of polycondensating a petroleum heavy oil or pitch, a formaldehyde polymer, and a phenol in the presence of an acid catalyst to prepare a modified phenolic resin; and reacting the resultant modified phenolic resin with the phenols at a temperature higher than 120.degree. C. and not more than 200.degree. C. in the presence of the acid catalyst to lower the molecular weight of the modified phenolic resin. The highly reactive low-viscosity modified phenolic resin obtained according to this process has high reactivity with epoxy resins and low resin melt viscosity. In addition, this resin can be used for producing a molding material having good moldability and considerably low moisture absorption when combined with an epoxy resin.
摘要翻译： 一种生产高反应性低粘度改性酚醛树脂的方法，包括在酸催化剂存在下使石油重油或沥青，甲醛聚合物和苯酚缩聚以制备改性酚醛树脂的步骤; 并在酸催化剂存在下，使所得改性酚醛树脂与酚在高于120℃，不超过200℃的温度下反应，以降低改性酚醛树脂的分子量。 根据该方法获得的高反应性低粘度改性酚醛树脂与环氧树脂具有高反应性和低树脂熔体粘度。 此外，该树脂可以用于制造与环氧树脂组合时具有良好成型性和显着低吸湿性的成型材料。
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公开(公告)号：US5792826A
公开(公告)日：1998-08-11
申请号：US797631
申请日：1997-02-07
摘要： A process for producing a highly reactive low-viscosity modified phenolic resin comprising the steps of polycondensating a petroleum heavy oil or pitch, a formaldehyde polymer, and a phenol in the presence of an acid catalyst to prepare a modified phenolic resin; and reacting the resultant modified phenolic resin with the phenols at a temperature higher than 120.degree. C. and not more than 200.degree. C. in the presence of the acid catalyst to lower the molecular weight of the modified phenolic resin. The highly reactive low-viscosity modified phenolic resin obtained according to this process has high reactivity with epoxy resins and low resin melt viscosity. In addition, this resin can be used for producing a molding material having good moldability and considerably low moisture absorption when combined with an epoxy resin.
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公开(公告)号：US5614600A
公开(公告)日：1997-03-25
申请号：US404457
申请日：1995-03-15
IPC分类号： C08G8/28 , C08G10/04 , C08G14/04 , C08J5/24 , C08L61/14 , C08L63/00 , C08F283/00 , C08L61/00
CPC分类号： C08J5/24 , C08G10/04 , C08G14/04 , C08G8/28 , C08L61/14 , C08L63/00 , C08J2361/14 , C08J2363/00 , Y10S525/935
摘要： A fiber-reinforced resin plate comprising a fibrous base material and a matrix bonding the fibers contained in the fibrous base material, the matrix being formed by curing a resin composition comprising a highly reactive modified phenolic resin (A) prepared by polycondensing a petroleum heavy oil or pitch, a formaldehyde polymer and a phenol in the presence of an acid catalyst to thereby prepare a modified phenolic resin and-reacting the resultant modified phenolic resin with a phenol in the presence of an acid catalyst to thereby lower the molecular weight of the modified phenolic resin, and an epoxy resin (B). Also, a prepreg and a process for producing the fiber-reinforced resin plate. This fiber-reinforced resin plate is excellent not only in adhesion to copper and other metals, heat resistance and electrical insulating properties but also in dimensional stability, strength and other mechanical properties, especially those at heating, because of the formation of the matrix by curing of the above resin composition comprising the highly reactive modified phenolic resin (A) and the epoxy resin (B).
摘要翻译： 一种纤维增强树脂板，包括纤维基材和将纤维基材中包含的纤维粘合的基体，所述基体通过固化树脂组合物形成，所述树脂组合物包含通过使石油重油缩聚而制备的高反应性改性酚醛树脂（A） 或沥青，甲醛聚合物和苯酚，在酸催化剂存在下制备改性酚醛树脂，并使所得改性酚醛树脂与苯酚在酸催化剂存在下反应，从而降低改性酚醛树脂的分子量 酚醛树脂和环氧树脂（B）。 另外，也可以使用预浸料坯和纤维增强树脂板的制造方法。 该纤维增强树脂板不仅对铜等金属的粘合性，耐热性和电绝缘性也优异，而且在尺寸稳定性，强度等机械性能方面优异，特别是加热时，由于通过固化形成基体 的上述树脂组合物，其包含高反应性改性酚醛树脂（A）和环氧树脂（B）。
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