公开(公告)号：US5773495A

公开(公告)日：1998-06-30

申请号：US750975

申请日：1997-01-03

申请人： Heinz Haschke ,  Ivan Tomka

发明人： Heinz Haschke ,  Ivan Tomka

IPC分类号： C08L3/00 ,  C08F8/00 ,  C08F261/04 ,  C08L3/02 ,  C08L51/00 ,  C08L101/16

CPC分类号： C08L3/02

摘要： The invention relates to the use of biodegradable graft copolymers producible in the presence of empirically determined quantities of water from polyvinyl alcohols with a degree of saponification of 88 to 99.5 mol. % by an acid catalysed acetalisation and/or transacetylisation reaction with carbohydrates containing carbonyl groups or presumptive carbonyl groups, in which the degree of acetqalisation, expressed in carbonyl equivalents per 100 vinyl alcohol equivalents, is between 0.2 and 20, and preferably between 1 and 10, as a plasticiser for the thermoplaticisation of starch and/or starch mixtures.

摘要翻译： PCT No.PCT / AT96 / 00093 Sec。 371日期1997年1月3日 102（e）日期1997年1月3日PCT提交1996年5月9日PCT公布。 公开号WO96 / 35748 日期1996年11月14日本发明涉及可生物降解的接枝共聚物的使用，该接枝共聚物可以在经验确定量的水存在下从皂化度为88-99.5mol的聚乙烯醇生产。 通过与含有羰基或推测性羰基的碳水化合物的酸催化缩醛化和/或转乙酰化反应，其中以每100个乙烯醇当量的羰基当量表示的乙酰化度为0.2至20，优选1至10 ，作为淀粉和/或淀粉混合物的热塑化的增塑剂。

公开(公告)号：US3992343A

公开(公告)日：1976-11-16

申请号：US382258

申请日：1973-07-24

申请人： Heinz Haschke ,  Gerhard Morlock ,  Horst Kruger ,  Gerhard Hebbel

发明人： Heinz Haschke ,  Gerhard Morlock ,  Horst Kruger ,  Gerhard Hebbel

IPC分类号： B65D85/32 ,  B01F17/00 ,  B01F17/34 ,  B01F17/52 ,  C09B67/46 ,  C09C3/00 ,  C09C3/10 ,  C08G2/00 ,  C08J3/20

CPC分类号： B01F17/0028

摘要： Process for dispersing solid, organic or inorganic colorant particles or mixtures thereof in a system comprised mainly of water by mixing into the aqueous system about 0.05 to 10% by weight of at least one dispersing agent comprising a polymer derived from specified units containing carboxyl, carboxylate, carbonyl and/or hydroxyl groups. A dispersing agent and an aqueous dispersion are provided. The process is particularly useful for dispersing pigments in aqueous systems.

摘要翻译： 将固体，有机或无机着色剂颗粒或其混合物分散在主要由水组成的系统中的方法，该方法是通过将约0.05-10％重量的至少一种分散剂混合到含水体系中，所述分散剂包含衍生自含羧基羧酸盐的指定单元的聚合物 ，羰基和/或羟基。 提供分散剂和水分散体。 该方法对于将颜料分散在水性体系中是特别有用的。

公开(公告)号：US20080103262A1

公开(公告)日：2008-05-01

申请号：US11578155

申请日：2005-04-14

申请人： Heinz Haschke ,  Erika Haschke

发明人： Heinz Haschke ,  Erika Haschke

IPC分类号： C08F8/28

CPC分类号： C08F8/28 ,  C08F8/48 ,  C08F16/06

摘要： A method for the production of packaging material systems for technical and pharmaceutical individual doses uses acid-catalyzed acetalization reaction of polyvinyl alcohol with vinyl alcohol copolymers (PVACL) produced with starch or starch derivatives in conjunction with destructuring agents. In the method, vinyl alcohol copolymers (PVCL) which contain water and which are soluble in cold water are produced either beforehand or after from the films and destructuring agents are added such that the hydrogen bridges between the polymer chains are fully or partially interrupted and that the films of vinyl alcohol copolymers thus prepared are subsequently heated to temperatures below the melting or expansion intervals thereof and are further processed in a sealing process using pressure for the production of a sealing seam for packaging in the form of individual doses.

摘要翻译： 用于生产用于技术和药物单独剂量的包装材料体系的方法使用聚乙烯醇与由淀粉或淀粉衍生物与破坏剂一起生产的乙烯醇共聚物（PVACL）的酸催化缩醛化反应。 在该方法中，含有水并且可溶于冷水的乙烯醇共聚物（PVCL）在膜之前或之后产生，并且加入破坏剂，使得聚合物链之间的氢桥充分或部分中断，并且 随后将如此制备的乙烯醇共聚物膜加热到低于其熔融或膨胀间隔的温度，并且在密封过程中进一步加工，其中压力用于生产用于以单独剂量形式包装的密封接缝。

公开(公告)号：US5914368A

公开(公告)日：1999-06-22

申请号：US765435

申请日：1997-01-15

申请人： Heinz Haschke ,  Ralf Rausch ,  Franz Reiterer ,  Felix Wehrmann

发明人： Heinz Haschke ,  Ralf Rausch ,  Franz Reiterer ,  Felix Wehrmann

IPC分类号： C08F8/28 ,  C08F16/06 ,  C08F16/38 ,  C08J5/18 ,  C08L33/00 ,  C08L101/16

CPC分类号： C08J5/18 ,  C08F8/48 ,  C08J2329/04

摘要： The description relates to vinyl alcohol copolymers which can be produced by the acid-catalysed acetalisation reaction of polyvinyl alcohols with a degree of saponification of 80-99.5 mol % and preferably between 88 and 99.5 mol % with natural substances or their derivatives containing carbonyl or presumptive carbonyl groups. The description also relates to water-soluble films containing such vinyl alcohol copolymers, the solubility of which can be adjusted to the desired solution temperature. Said water-soluble films are used as packaging materials and auxiliaries, e.g. in the form of sealing lacquers.

摘要翻译： PCT No.PCT / AT95 / 00151 Sec。 371日期1997年1月15日 102（e）日期1997年1月15日PCT提交1995年7月21日PCT公布。 公开号WO96 / 03443 日期1996年2月8日该描述涉及乙烯醇共聚物，其可以通过酸性催化的缩合反应生产，其中皂化度为80-99.5mol％，优选88-99.5mol％的聚乙烯醇与天然物质或它们的 含有羰基或推定羰基的衍生物。 该描述还涉及含有这种乙烯醇共聚物的水溶性膜，其溶解度可以调节到所需的溶液温度。 所述水溶性薄膜用作包装材料和助剂，例如， 以密封漆的形式。

公开(公告)号：US4054739A

公开(公告)日：1977-10-18

申请号：US656845

申请日：1976-02-10

申请人： Heinz Haschke ,  Gerd Schreyer ,  Werner Schwarze ,  Helmut Suchsland

发明人： Heinz Haschke ,  Gerd Schreyer ,  Werner Schwarze ,  Helmut Suchsland

IPC分类号： C07D251/42 ,  C07D251/44 ,  C07D251/50

CPC分类号： C07D251/50 ,  C07D251/44

摘要： There is provided a process for the substitution of one or for the successive substitution of two chlorine atoms of cyanuric chloride by one or two amines whch may be the same or different in the presence of an acid binding agent and in the presence of an organic solvent, particularly for the production of 2-alkylamino-4,6-dichloro-, s-triazines and more preferably for the production of 2,4-di-(alkylamino)-6-chloro-s-triazines wherein there is used a 4 to 60 weight % solution or suspension of cyanuric chloride in a mixture of 65 to 85 weight % of one or more aliphatic hydrocarbons or cycloaliphatic hydrocarbons hving 5 to 10 carbon atoms and/or one or more aromatic hydrocarbons and 35 to 15 weight % of one or more ketones having 3 to 8 carbon atoms.

摘要翻译： 提供了一种方法，用于在酸结合剂的存在下，在有机溶剂的存在下，将一个或两个胺取代一次或连续取代氰尿酰氯的两个氯原子可以相同或不同 ，特别是用于制备2-烷基氨基-4,6-二氯，三 - 三嗪并且更优选用于制备2,4-二 - （烷基氨基）-6-氯-s-三嗪，其中使用4 至60重量％的氰尿酰氯在65至85重量％的一种或多种脂肪烃或5至10个碳原子的脂环族烃和/或一种或多种芳族烃和35至15重量％的一种混合物的混合物中 或更多的具有3-8个碳原子的酮。

公开(公告)号：US3984341A

公开(公告)日：1976-10-05

申请号：US540631

申请日：1975-01-13

申请人： Heinz Haschke ,  Gerhard Morlock

发明人： Heinz Haschke ,  Gerhard Morlock

IPC分类号： C08K3/00 ,  A61K9/08 ,  A61K47/00 ,  A61L20060101 ,  C01B7/14 ,  C08F8/00 ,  C08K3/02 ,  C08L29/00 ,  C08L33/00 ,  C08L33/02

摘要： A non-foaming iodophor having a high content of active iodine comprises the product formed by mixing while heating at about 50.degree.-120.degree.C for about 0.75-15 hours a reaction mixture of:I. about 10-30 weight percent of elementary iodine; andIi. about 90-70 weight percent of an aqueous solution consisting essentially of:A. about 7-30 weight percent of at least one polycarboxylic acid, at least one polycarboxylate or mixtures of said polycarboxylic acids and polycarboxylates, having at least 65 carboxyl or carboxylate groups per 100 monomer units in the polymer chain and an average degree of polymerization (numerical average value) between about 10 and 500;B. about 0-20 weight percent of at least one alkali metal iodide, ammonium iodide, mixtures of said iodides or at least one lower, monovalent, aliphatic alcohol;C. about 0-20 weight percent of at least one non-volatile multibasic mineral acid, at least one multibasic oxycarboxylic acid, or mixtures of said acids, wherein said acids do not substantially reduce elementary iodine; andD. water in an amount sufficient so that said aqueous solution comprises 100 weight-percent. The iodophor exhibits biocidal activity.

摘要翻译： 具有高活性碘含量的非起泡碘伏混合物包括通过在约50-120℃下加热约0.75-15小时混合形成的产物，反应混合物为：

公开(公告)号：US3956121A

公开(公告)日：1976-05-11

申请号：US522799

申请日：1974-11-11

申请人： Heinz Haschke ,  Helmut Knorre ,  Gerhard Morlock ,  Gerhard Pohl

发明人： Heinz Haschke ,  Helmut Knorre ,  Gerhard Morlock ,  Gerhard Pohl

IPC分类号： C08F8/00 ,  C02F1/52 ,  C02F1/62 ,  C02F9/00 ,  C08F8/42 ,  C02B1/20

CPC分类号： C02F9/00 ,  C02F1/5236 ,  C02F1/001 ,  C02F1/66 ,  C02F2101/20 ,  C02F2101/303

摘要： A process for precipitating heavy metal ion-polycarboxylate complexes from solution, said process comprising adding to a solution containing at least one of said complexes an aqueous solution of a water soluble aluminum salt, the anion of which does not form any water soluble complexes with said heavy metal ions to be precipitated or optionally such anion-heavy metal complexes having a stability constant, expressed as their decadic logarithm, of less than 2; wherein 0.9 to 1.8 moles of aluminum ions are employed per equivalent of polycarboxylate; and adjusting the pH of the resulting reaction mixture to about 6.5 to about 9.0 with an alkali metal carbonate.

摘要翻译： 一种从溶液中沉淀重金属离子 - 多羧酸盐络合物的方法，所述方法包括向含有至少一种所述络合物的溶液中加入水溶性铝盐的水溶液，水溶性铝盐的阴离子不与所述复合物形成任何水溶性络合物 要沉淀的重金属离子或任选的具有小于2的具有稳定常数（表示为十进制对数）的阴离子 - 重金属络合物; 其中每当量的聚羧酸盐使用0.9至1.8摩尔的铝离子; 并用碱金属碳酸盐将所得反应混合物的pH调节至约6.5至约9.0。

公开(公告)号：US4058662A

公开(公告)日：1977-11-15

申请号：US656849

申请日：1976-02-10

申请人： Heinz Haschke ,  Gerd Schreyer ,  Werner Schwarze ,  Helmut Suchsland

发明人： Heinz Haschke ,  Gerd Schreyer ,  Werner Schwarze ,  Helmut Suchsland

IPC分类号： C07D251/50 ,  C07D251/44

CPC分类号： C07D251/50 ,  C07D251/44

摘要： There is provided a process, preferably continuous and in a given case successive, substitution of one or two chlorine atoms of cyanuric chloride by one or two amines, which may be the same or different, in the presence of an acid acceptor and in the presence of an organic solvent, particularly for the production of 2-alkylamino-4,6-dichloro and preferably for the production of 2,4-di(alkylamino)-6-chloro-s-triazines wherein there is added 1.00 to 1.05 mole, preferably 1.00 to 1.03 mole of a first amine to a 4.5 to 50 weight % suspension or solution of cyanuric chloride in a mixture of 65 to 85 weight % of xylene, toluene, ethylbenzene, benzene and/or an aliphatic or cycloaliphatic hydrocarbon with 5 to 10 carbon atoms (toluene being preferred) and 35 to 15 weight % of a ketone with 3 to 8 carbon atoms, preferably acetone, while maintaining the temperature between about 0 and about 20.degree. C, preferably about 10 to 18.degree. C., continuously so regulating the pH value of the reaction mixture obtained in accordance with the reaction time by addition of alkali and in a given case, water so that this corresponds to a point within the area bounded by lines ABCD of FIG. 1, which runs through the area beginning with the reaction time t,(step 1)= 0 until reaching a position in the area bounded by the lines BCEF and after reaching a pH of 7.0, preferably 7.2 maintains a temperature of about 10.degree. to about 60.degree. C., preferably about 25.degree. to 40.degree. C., after addition of 0.96 to 1.05, preferably 0.98 to 1.02 equivalents of alkali per mole of cyanuric chloride, adding at least an equimolar amount, preferably 1.00 to 1.02 mole of the second amine per mole of cyanuric chloride and continuously so adjusting the pH value of the reaction mixture obtained depending on the reaction time by addition of alkali that this corresponds to a point within the area which is defined by lines GHIJ in FIG. 3 which passes through the band beginning with the reaction time t(step 2)= 0 of the second reaction step until reaching a position in the area bounded by the lines HIKL and thereby maintaining a temperature of 40 to 70.degree. C., preferably 45.degree. to 55.degree. C. and thereafter working up the product in known manner wherein t.sub.1 is a time of 4 to 10 hours, preferably about 7 hours and t.sub.2 is a time of 2 to 8 hours, preferably about 6 hours and wherein the B C corresponds to the equation, pH = -(12.6/t.sub.1)+ 14.35 and the line H I corresponds to the equation pH = -(24,857/t.sub.2)+ 23.9285. There are also disclosed novel, purified mono and bis alkylamino-cyanoalkylalkylamino -- s -- triazines.

公开(公告)号：US4007222A

公开(公告)日：1977-02-08

申请号：US607051

申请日：1975-08-22

申请人： Heinz Haschke ,  Wolfgang Leuchtenberger ,  Gerd Schreyer ,  Werner Schwarze

发明人： Heinz Haschke ,  Wolfgang Leuchtenberger ,  Gerd Schreyer ,  Werner Schwarze

IPC分类号： C07C53/19 ,  C07B9/00

CPC分类号： C07C53/19

摘要： 2-Chloro-n-caproic acid and 6-substituted 2-chloro-n-caproic acids are produced from n-caproic acid or 6-substituted n-caproic acids are chlorinated in the presence of sulfur halides and phosphorus halides at elevated temperatures using for each mole of caproic acid there is used up to about 1.2 mole of chlorine and as catalyst at least one compound of the group of sulfur chlorides, sulfur bromides, phosphorus chloride and phosphorus bromide at a temperature of about 110.degree. to 130 .degree. C.

摘要翻译： 2-氯 - 正己酸和6-取代的2-氯正己酸由正己酸生成，或6-取代的正己酸在高温下在卤化硫和卤化磷存在下氯化，使用 对于每摩尔的己酸，在约110-130℃的温度下使用多至约1.2摩尔氯，并且使用至少一种硫化氯，硫化溴，氯化磷和溴化磷的化合物作为催化剂。

公开(公告)号：US3983223A

公开(公告)日：1976-09-28

申请号：US532295

申请日：1974-12-12

申请人： Karlheinz Janzon ,  Heinz Haschke ,  Rudolf Muller

发明人： Karlheinz Janzon ,  Heinz Haschke ,  Rudolf Muller

IPC分类号： C01B15/10

CPC分类号： C01B15/103

摘要： Alkali percarbonates are prepared from aqueous alkali carbonate and hydrogen peroxide solution in the presence of polymeric carboxylates, especially those that contain in addition to carboxylate or carboxylic groups hydroxyl groups and if desired carbonyl groups and which have an average degree of polymerization of 5 to 5000.

摘要翻译： 碱性碳酸酯由碱金属碳酸盐和过氧化氢水溶液在聚合羧酸盐存在下制备，特别是含有羧酸盐或羧基羟基以及如果需要的羰基，并且平均聚合度为5至5000的那些。