公开(公告)号：US3956121A

公开(公告)日：1976-05-11

申请号：US522799

申请日：1974-11-11

申请人： Heinz Haschke ,  Helmut Knorre ,  Gerhard Morlock ,  Gerhard Pohl

发明人： Heinz Haschke ,  Helmut Knorre ,  Gerhard Morlock ,  Gerhard Pohl

IPC分类号： C08F8/00 ,  C02F1/52 ,  C02F1/62 ,  C02F9/00 ,  C08F8/42 ,  C02B1/20

CPC分类号： C02F9/00 ,  C02F1/5236 ,  C02F1/001 ,  C02F1/66 ,  C02F2101/20 ,  C02F2101/303

摘要： A process for precipitating heavy metal ion-polycarboxylate complexes from solution, said process comprising adding to a solution containing at least one of said complexes an aqueous solution of a water soluble aluminum salt, the anion of which does not form any water soluble complexes with said heavy metal ions to be precipitated or optionally such anion-heavy metal complexes having a stability constant, expressed as their decadic logarithm, of less than 2; wherein 0.9 to 1.8 moles of aluminum ions are employed per equivalent of polycarboxylate; and adjusting the pH of the resulting reaction mixture to about 6.5 to about 9.0 with an alkali metal carbonate.

摘要翻译： 一种从溶液中沉淀重金属离子 - 多羧酸盐络合物的方法，所述方法包括向含有至少一种所述络合物的溶液中加入水溶性铝盐的水溶液，水溶性铝盐的阴离子不与所述复合物形成任何水溶性络合物 要沉淀的重金属离子或任选的具有小于2的具有稳定常数（表示为十进制对数）的阴离子 - 重金属络合物; 其中每当量的聚羧酸盐使用0.9至1.8摩尔的铝离子; 并用碱金属碳酸盐将所得反应混合物的pH调节至约6.5至约9.0。

公开(公告)号：US3992343A

公开(公告)日：1976-11-16

申请号：US382258

申请日：1973-07-24

申请人： Heinz Haschke ,  Gerhard Morlock ,  Horst Kruger ,  Gerhard Hebbel

发明人： Heinz Haschke ,  Gerhard Morlock ,  Horst Kruger ,  Gerhard Hebbel

IPC分类号： B65D85/32 ,  B01F17/00 ,  B01F17/34 ,  B01F17/52 ,  C09B67/46 ,  C09C3/00 ,  C09C3/10 ,  C08G2/00 ,  C08J3/20

CPC分类号： B01F17/0028

摘要： Process for dispersing solid, organic or inorganic colorant particles or mixtures thereof in a system comprised mainly of water by mixing into the aqueous system about 0.05 to 10% by weight of at least one dispersing agent comprising a polymer derived from specified units containing carboxyl, carboxylate, carbonyl and/or hydroxyl groups. A dispersing agent and an aqueous dispersion are provided. The process is particularly useful for dispersing pigments in aqueous systems.

摘要翻译： 将固体，有机或无机着色剂颗粒或其混合物分散在主要由水组成的系统中的方法，该方法是通过将约0.05-10％重量的至少一种分散剂混合到含水体系中，所述分散剂包含衍生自含羧基羧酸盐的指定单元的聚合物 ，羰基和/或羟基。 提供分散剂和水分散体。 该方法对于将颜料分散在水性体系中是特别有用的。

公开(公告)号：US3987218A

公开(公告)日：1976-10-19

申请号：US478425

申请日：1974-06-11

申请人： Heinz Haschke ,  Gerhard Morlock ,  Peter Kuzel ,  Horst Kruger

发明人： Heinz Haschke ,  Gerhard Morlock ,  Peter Kuzel ,  Horst Kruger

IPC分类号： C08J3/00 ,  B05D7/00

CPC分类号： C08J3/00 ,  C08J2300/104 ,  Y10T428/2998

摘要： A process for decreasing the hygroscopicity of a polycarboxylate, said process comprising preparing a melt of a composition having a melting point of about 40.degree. - 120.degree. C, said composition giving an acid or neutral pH in an aqueous solution or suspension, said composition being less hygroscopic than said polycarboxylate, said composition capable of being free flowing under equilibrium conditions at about 30.degree. C and in an air atmosphere of at least about 40% relative humidity; heating said melt in a mixer to a temperature of up to about 140.degree. C; gradually adding said polycarboxylate as a powder to said melt while mixing said melt; wherein said composition comprises at least about 3 and at most about 40% by weight of the mixture resulting after all polycarboxylate has been added to said melt.

公开(公告)号：US4042748A

公开(公告)日：1977-08-16

申请号：US382225

申请日：1973-07-24

申请人： Gerhard Hebbel ,  Horst Krueger ,  Heinz Haschke ,  Gerhard Morlock

发明人： Gerhard Hebbel ,  Horst Krueger ,  Heinz Haschke ,  Gerhard Morlock

IPC分类号： D21H19/20 ,  D21H19/36 ,  D21H19/44 ,  D21H19/58 ,  C08L81/00 ,  B32B5/16 ,  C09C3/10

CPC分类号： D21H19/58 ,  Y10T428/25

摘要： A process for improving the processability of a coating composition for paper and paper substitutes in which the composition contains at least one undissolved finely divided inorganic substance, organic substance, or mixture of such substances in a system comprised mainly of water, wherein the process comprises mixing into said system about 0.05 - 5.0 percent by weight of at least one dispersing agent consisting essentially of a polymer derived from specified units containing carboxyl, carboxylate, carbonyl and/or hydroxyl groups. A coating composition is provided.

摘要翻译： 一种用于提高纸和纸替代物的涂料组合物的加工性的方法，其中组合物在主要由水组成的体系中含有至少一种未溶解的细碎无机物质，有机物质或这些物质的混合物，其中该方法包括混合 约0.05-5.0重量％的至少一种分散剂，其基本上由衍生自含羧基，羧酸酯，羰基和/或羟基的特定单元的聚合物组成。 提供涂料组合物。

公开(公告)号：US3962132A

公开(公告)日：1976-06-08

申请号：US519322

申请日：1974-10-30

申请人： Heinz Haschke ,  Gerhard Morlock

发明人： Heinz Haschke ,  Gerhard Morlock

IPC分类号： B01J39/14 ,  C01B39/00 ,  C01B39/02 ,  C11D3/00 ,  C11D3/08 ,  C11D3/12 ,  B01J31/04 ,  B01J29/06 ,  C02B5/06

CPC分类号： C11D3/128 ,  C01B39/026 ,  C11D3/3761

摘要： Process for improving the water wettability of natural or synthetic zeolites, said process comprising thoroughly mixing at least one natural zeolite, synthetic zeolite or mixture of natural and synthetic zeolites with an aqueous solution of a treating agent selected from the group consisting of at least one polyelectrolytic polycarboxylic acid, at least one completely or partially neutralized polycarboxylate, or at least one mixture of said polycarboxylic acid and polycarboxylates; wherein said treating agent has at least about 40 basic mole percent carboxyl or carboxylate groups and a mean degree of polymerization (numerical mean) between about 3 and about 5000; said mixing conducted at about 0.degree. to about 100.degree.C for at least about 5 minutes; said aqueous solution employed in a concentration between about 2 and about 800 g polycarboxylic acid or polycarboxylate per liter and in such quantity that it comprises about 0.01 to about 10 parts by weight, related to one part by weight of zeolite, of the polycarboxylic acid or polycarboxylate.

公开(公告)号：US3984341A

公开(公告)日：1976-10-05

申请号：US540631

申请日：1975-01-13

申请人： Heinz Haschke ,  Gerhard Morlock

发明人： Heinz Haschke ,  Gerhard Morlock

IPC分类号： C08K3/00 ,  A61K9/08 ,  A61K47/00 ,  A61L20060101 ,  C01B7/14 ,  C08F8/00 ,  C08K3/02 ,  C08L29/00 ,  C08L33/00 ,  C08L33/02

摘要： A non-foaming iodophor having a high content of active iodine comprises the product formed by mixing while heating at about 50.degree.-120.degree.C for about 0.75-15 hours a reaction mixture of:I. about 10-30 weight percent of elementary iodine; andIi. about 90-70 weight percent of an aqueous solution consisting essentially of:A. about 7-30 weight percent of at least one polycarboxylic acid, at least one polycarboxylate or mixtures of said polycarboxylic acids and polycarboxylates, having at least 65 carboxyl or carboxylate groups per 100 monomer units in the polymer chain and an average degree of polymerization (numerical average value) between about 10 and 500;B. about 0-20 weight percent of at least one alkali metal iodide, ammonium iodide, mixtures of said iodides or at least one lower, monovalent, aliphatic alcohol;C. about 0-20 weight percent of at least one non-volatile multibasic mineral acid, at least one multibasic oxycarboxylic acid, or mixtures of said acids, wherein said acids do not substantially reduce elementary iodine; andD. water in an amount sufficient so that said aqueous solution comprises 100 weight-percent. The iodophor exhibits biocidal activity.

摘要翻译： 具有高活性碘含量的非起泡碘伏混合物包括通过在约50-120℃下加热约0.75-15小时混合形成的产物，反应混合物为：

公开(公告)号：US5773495A

公开(公告)日：1998-06-30

申请号：US750975

申请日：1997-01-03

申请人： Heinz Haschke ,  Ivan Tomka

发明人： Heinz Haschke ,  Ivan Tomka

IPC分类号： C08L3/00 ,  C08F8/00 ,  C08F261/04 ,  C08L3/02 ,  C08L51/00 ,  C08L101/16

CPC分类号： C08L3/02

摘要： The invention relates to the use of biodegradable graft copolymers producible in the presence of empirically determined quantities of water from polyvinyl alcohols with a degree of saponification of 88 to 99.5 mol. % by an acid catalysed acetalisation and/or transacetylisation reaction with carbohydrates containing carbonyl groups or presumptive carbonyl groups, in which the degree of acetqalisation, expressed in carbonyl equivalents per 100 vinyl alcohol equivalents, is between 0.2 and 20, and preferably between 1 and 10, as a plasticiser for the thermoplaticisation of starch and/or starch mixtures.

摘要翻译： PCT No.PCT / AT96 / 00093 Sec。 371日期1997年1月3日 102（e）日期1997年1月3日PCT提交1996年5月9日PCT公布。 公开号WO96 / 35748 日期1996年11月14日本发明涉及可生物降解的接枝共聚物的使用，该接枝共聚物可以在经验确定量的水存在下从皂化度为88-99.5mol的聚乙烯醇生产。 通过与含有羰基或推测性羰基的碳水化合物的酸催化缩醛化和/或转乙酰化反应，其中以每100个乙烯醇当量的羰基当量表示的乙酰化度为0.2至20，优选1至10 ，作为淀粉和/或淀粉混合物的热塑化的增塑剂。

公开(公告)号：US4017413A

公开(公告)日：1977-04-12

申请号：US632952

申请日：1975-11-18

申请人： Friedrich Bittner ,  Heinz Haschke ,  Helmut Suchsland ,  Gerd Schreyer ,  Werner Schwarze

发明人： Friedrich Bittner ,  Heinz Haschke ,  Helmut Suchsland ,  Gerd Schreyer ,  Werner Schwarze

IPC分类号： C07D251/28 ,  B01F3/08

CPC分类号： C07D251/28

摘要： There is provided a process for the production of a solution or suspension of cyanuric chloride in a water containing organic solvent wherein the liquid cyanuric chloride and the organic-aqueous solvent are mixed together while being agitated, the liquid cyanuric chloride at a temperature between its melting point and 200.degree. C. is led into the flowing organic-aqueous solvent with a velocity of Vcy (in kg per hour) wherein ##EQU1## where P is the desired concentration of cyanuric chloride in the solution or suspension to be produced in weight %, P.sub.LM is the concentration of cyanuric chloride in the solvent used which also includes O,V.sub.lm is the velocity of the solvent added in kg/h,And P.sub.LM, V.sub.LM and T.sub.LM, the temperature of the added solvent, are so selected that the expression ##EQU2## does not exceed the boiling temperature in .degree. C. of the solvent used and wherein C.sub.p (LM) and C.sub.p (Cy) signify the specific heat capacities in cal. x g.sup.-.sup.1 .times. (.degree.degree C).sup.-.sup.1 of the solvent and cyanuric chloride respectively, whereupon in a given case within at most 3 minutes after bringing the cyanuric chloride and solvent into contact the flowing mixture is cooled to the desired storage temperature.

摘要翻译： 提供了一种在含有有机溶剂的水中制备氰尿酰氯的溶液或悬浮液的方法，其中液体氰尿酰氯和有机 - 水溶剂在搅拌下混合在一起，液态氰尿酰氯在其熔融 点和200℃以Vcy速度（以kg /小时计）流入有机 - 水溶剂，其中P是待生成的溶液或悬浮液中所需浓度的氰尿酰氯，其重量％ PLM是所用溶剂中氰尿酰氯的浓度，其还包括O，VLM是以kg / h加入的溶剂的速度，而PLM，VLM和TLM，加入的溶剂的温度如此选择，使得表达式 ＆lt; IMAGE＆gt;不超过使用的溶剂的沸点（℃），其中Cp（LM）和Cp（Cy）表示比热容。 xg <1>（℃C）-1的溶剂和氰尿酰氯，因此在给出的情况下，在将氰尿酰氯和溶剂接触之前的最多3分钟内，将流动的混合物冷却至所需的 储存温度。

公开(公告)号：US20080103262A1

公开(公告)日：2008-05-01

申请号：US11578155

申请日：2005-04-14

申请人： Heinz Haschke ,  Erika Haschke

发明人： Heinz Haschke ,  Erika Haschke

IPC分类号： C08F8/28

CPC分类号： C08F8/28 ,  C08F8/48 ,  C08F16/06

摘要： A method for the production of packaging material systems for technical and pharmaceutical individual doses uses acid-catalyzed acetalization reaction of polyvinyl alcohol with vinyl alcohol copolymers (PVACL) produced with starch or starch derivatives in conjunction with destructuring agents. In the method, vinyl alcohol copolymers (PVCL) which contain water and which are soluble in cold water are produced either beforehand or after from the films and destructuring agents are added such that the hydrogen bridges between the polymer chains are fully or partially interrupted and that the films of vinyl alcohol copolymers thus prepared are subsequently heated to temperatures below the melting or expansion intervals thereof and are further processed in a sealing process using pressure for the production of a sealing seam for packaging in the form of individual doses.

摘要翻译： 用于生产用于技术和药物单独剂量的包装材料体系的方法使用聚乙烯醇与由淀粉或淀粉衍生物与破坏剂一起生产的乙烯醇共聚物（PVACL）的酸催化缩醛化反应。 在该方法中，含有水并且可溶于冷水的乙烯醇共聚物（PVCL）在膜之前或之后产生，并且加入破坏剂，使得聚合物链之间的氢桥充分或部分中断，并且 随后将如此制备的乙烯醇共聚物膜加热到低于其熔融或膨胀间隔的温度，并且在密封过程中进一步加工，其中压力用于生产用于以单独剂量形式包装的密封接缝。

公开(公告)号：US5914368A

公开(公告)日：1999-06-22

申请号：US765435

申请日：1997-01-15

申请人： Heinz Haschke ,  Ralf Rausch ,  Franz Reiterer ,  Felix Wehrmann

发明人： Heinz Haschke ,  Ralf Rausch ,  Franz Reiterer ,  Felix Wehrmann

IPC分类号： C08F8/28 ,  C08F16/06 ,  C08F16/38 ,  C08J5/18 ,  C08L33/00 ,  C08L101/16

CPC分类号： C08J5/18 ,  C08F8/48 ,  C08J2329/04

摘要： The description relates to vinyl alcohol copolymers which can be produced by the acid-catalysed acetalisation reaction of polyvinyl alcohols with a degree of saponification of 80-99.5 mol % and preferably between 88 and 99.5 mol % with natural substances or their derivatives containing carbonyl or presumptive carbonyl groups. The description also relates to water-soluble films containing such vinyl alcohol copolymers, the solubility of which can be adjusted to the desired solution temperature. Said water-soluble films are used as packaging materials and auxiliaries, e.g. in the form of sealing lacquers.

摘要翻译： PCT No.PCT / AT95 / 00151 Sec。 371日期1997年1月15日 102（e）日期1997年1月15日PCT提交1995年7月21日PCT公布。 公开号WO96 / 03443 日期1996年2月8日该描述涉及乙烯醇共聚物，其可以通过酸性催化的缩合反应生产，其中皂化度为80-99.5mol％，优选88-99.5mol％的聚乙烯醇与天然物质或它们的 含有羰基或推定羰基的衍生物。 该描述还涉及含有这种乙烯醇共聚物的水溶性膜，其溶解度可以调节到所需的溶液温度。 所述水溶性薄膜用作包装材料和助剂，例如， 以密封漆的形式。