公开(公告)号：US4229491A

公开(公告)日：1980-10-21

申请号：US969077

申请日：1978-12-13

申请人： Helmut Dislich ,  Paul Hinz ,  Gunther Wolf

发明人： Helmut Dislich ,  Paul Hinz ,  Gunther Wolf

IPC分类号： C01G19/00 ,  C03C17/25 ,  B05D1/18 ,  B05D3/02 ,  B05D3/04

CPC分类号： C01G19/00 ,  C03C17/253 ,  C03C2217/232 ,  C03C2217/24 ,  C03C2218/111

摘要： A dipping process for the production of cadmium stannate layers on a substrate, preferably glass, which comprises:(a) dipping said substrate into an alcoholic solution of a reaction product containing cadmium and tin, said solution consisting essentially of compounds having hydrolyzable and pyrolyzable residues;(b) withdrawing the substrate from said solution in a humid atmosphere; and(c) gradually heating the coated substrate to 650.degree. C., whereby hydrolysis and pyrolysis removes said residues from the coated substrate to form a coated substrate in which the molar ratio Cd:Sn corresponds to that of said alcoholic dipping solution.

摘要翻译： 一种用于在基材上，优选玻璃上生产锡酸镉层的浸渍方法，其包括：（a）将所述底物浸入含有镉和锡的反应产物的醇溶液中，所述溶液基本上由具有可水解和可热解残余物的化合物组成 ; （b）在潮湿气氛中从所述溶液中取出底物; 和（c）将涂覆的基材逐渐加热至650℃，由此水解和热解从所涂覆的基材上除去所述残余物以形成其中Cd:Sn的摩尔比对应于所述醇浸渍溶液的摩尔比的涂布基材。

公开(公告)号：US4715999A

公开(公告)日：1987-12-29

申请号：US796460

申请日：1985-11-08

申请人： Helmut Dislich ,  Nanning J. Arfsten ,  Helmut Schmidt ,  Gottfried Philipp ,  Gerhard Tuenker

发明人： Helmut Dislich ,  Nanning J. Arfsten ,  Helmut Schmidt ,  Gottfried Philipp ,  Gerhard Tuenker

IPC分类号： B29C43/00 ,  B29C45/00 ,  C08F283/12 ,  C08G77/58 ,  G02B1/04 ,  B29D11/00

CPC分类号： G02B1/04 ,  C08F283/124 ,  C08G77/58 ,  G02B1/041 ,  B29C43/00 ,  B29C45/00

摘要： Optical blanks, for example spectacle lenses, are produced by hot-blank pressing or injection molding of polyorganoheterosiloxanes which are obtainable by hydrolytic polycondensation of at least one titanium-, zirconium-or tin-compound, at least one organofunctional silane and, where applicable, at least one inorganic oxide component. For control of the optical characteristics and working properties, polyorganoheterosiloxanes which have a polymerizable organic radical may be modified by additional polymerization with other copolymerizable condensates or monomers.

摘要翻译： 光学毛坯，例如眼镜片，是通过热毛坯压制或注射成型聚有机基硅氧烷生产的，所述聚有机硅氧烷通过至少一种钛，锆或锡化合物，至少一种有机官能硅烷的水解缩聚获得， 至少一种无机氧化物组分。 为了控制光学特性和加工性能，可以通过与其它可共聚的缩合物或单体的另外的聚合来改性具有可聚合的有机基团的聚有机基硅氧烷。

公开(公告)号：US5262204A

公开(公告)日：1993-11-16

申请号：US909331

申请日：1992-07-06

申请人： Paul Hinz ,  Helmut Dislich ,  Herwig Scheidler ,  Gerhard Weber

发明人： Paul Hinz ,  Helmut Dislich ,  Herwig Scheidler ,  Gerhard Weber

IPC分类号： C03C17/34 ,  C23C26/00

CPC分类号： C03C17/3411

摘要： The invention is related to a glass-ceramic article decorated with a ceramic baking finish. A SiO.sub.2 layer, about 20-200 nm thick, is placed between the decoration and the glass-ceramic material. The SiO.sub.2 layer can additionally contain, to match the refractive index to the refractive index of the glass-ceramic, up to 66.5 wt. % of oxides which change the refractive index, in particular TiO.sub.2, ZrO.sub.2, SnO.sub.2, MgO or Al.sub.2 O.sub.3. In the process to produce the decorated glass ceramic article, the SiO.sub.2 layer is preferably produced according to the known sol-gel process. Preferably, an SiO.sub.2 gel layer, optionally precondensed by a brief thermal treatment, is produced on the still-vitreous article. The decoration is applied to this gel layer and afterward the vitreous article is subjected to ceramization. The SiO.sub.2 -gel layer is converted into an SiO.sub.2 layer, and the ceramic color of the decoration is baked-in. The SiO.sub.2 layer permits, above all, the production of substantially "halo"-free decorations with sharp contours.

摘要翻译： 本发明涉及用陶瓷烤漆装饰的玻璃陶瓷制品。 大约20-200nm厚的SiO 2层被放置在装饰和玻璃 - 陶瓷材料之间。 SiO 2层可以另外包含与玻璃 - 陶瓷的折射率相匹配的高达66.5wt。 改变折射率的氧化物的百分比，特别是TiO 2，ZrO 2，SnO 2，MgO或Al 2 O 3。 在制造装饰玻璃陶瓷制品的方法中，SiO 2层优选根据已知的溶胶 - 凝胶法制备。 优选地，通过短暂热处理任选地预缩合的SiO 2凝胶层在剩余玻璃制品上产生。 对该凝胶层进行装饰，然后对玻璃制品进行陶瓷化。 将SiO 2凝胶层转化为SiO 2层，将陶瓷的装饰颜色烘烤。 首先，SiO 2层允许生产具有尖锐轮廓的基本上“无卤”的装饰。

公开(公告)号：US5137779A

公开(公告)日：1992-08-11

申请号：US607878

申请日：1990-11-05

申请人： Paul Hinz ,  Helmut Dislich ,  Herwig Scheidler ,  Gerhard Weber

发明人： Paul Hinz ,  Helmut Dislich ,  Herwig Scheidler ,  Gerhard Weber

IPC分类号： C04B41/85 ,  C03C17/34

CPC分类号： C03C17/3411 ,  Y10S428/901 ,  Y10T428/24926 ,  Y10T428/265

摘要： The invention is related to a glass-ceramic article decorated with a ceramic baking finish. A SiO.sub.2 layer, about 20-200 nm thick, is placed between the decoration and the glass-ceramic material. The SiO.sub.2 layer can additionally contain, to match the refractive index to the refractive index of the glass-ceramic, up to 66.5 wt % of oxides which change the refractive index, in particular TiO.sub.2, ZrO.sub.2, SnO.sub.2, MgO or Al.sub.2 O.sub.3. In the process to produce the decorated glass ceramic article, the SiO.sub.2 layer is preferably produced according to the known sol-gel process. Preferably, an SiO.sub.2 gel layer, optionally precondensed by a brief thermal treatment, is produced on the still-vitreous article. The decoration is applied to this gel layer and afterward the vitreous article is subjected to ceramization. The SiO.sub.2 -gel layer is converted into an SiO.sub.2 layer, and the ceramic color of the decoration is baked-in. The SiO.sub.2 layer permits, above all, the production of substantially "halo"-free decorations with sharp contours.

摘要翻译： 本发明涉及用陶瓷烤漆装饰的玻璃陶瓷制品。 大约20-200nm厚的SiO 2层被放置在装饰和玻璃 - 陶瓷材料之间。 SiO 2层可以另外包含使玻璃 - 陶瓷的折射率与折射率相匹配的高达66.5重量％的改变折射率的氧化物，特别是TiO 2，ZrO 2，SnO 2，MgO或Al 2 O 3。 在制造装饰玻璃陶瓷制品的方法中，SiO 2层优选根据已知的溶胶 - 凝胶法制备。 优选地，通过短暂热处理任选地预缩合的SiO 2凝胶层在剩余玻璃制品上产生。 对该凝胶层进行装饰，然后对玻璃制品进行陶瓷化。 将SiO 2凝胶层转化为SiO 2层，将陶瓷的装饰颜色烘烤。 首先，SiO 2层允许生产具有尖锐轮廓的基本上“无卤”的装饰。

公开(公告)号：US4877668A

公开(公告)日：1989-10-31

申请号：US4404

申请日：1987-01-20

申请人： Paul Hinz ,  Helmut Dislich ,  Gerhard Weber

发明人： Paul Hinz ,  Helmut Dislich ,  Gerhard Weber

IPC分类号： C03C17/23 ,  G01D11/26

CPC分类号： G02B7/007 ,  C03C17/23 ,  G01D11/26 ,  C03C2217/211 ,  C03C2217/23 ,  C03C2218/112 ,  Y10T428/23 ,  Y10T428/238 ,  Y10T428/239

摘要： A pressure vessel sight glass, especially a tempered glass, is protected against the corrosive attack of normally alkaline, boiler feed water heated up to 300.degree. C., by providing the sight glass with a metallic oxide coating consisting essentially of SnO.sub.2, optionally combined with Cr.sub.2 O.sub.3. The coating is preferably applied as a sprayed solution of soluble salt convertible to the oxide.

摘要翻译： 压力容器观察镜，特别是钢化玻璃，通过为观察玻璃提供基本上由SnO2组成的金属氧化物涂层，防止通常加热到300℃的通常碱性锅炉给水的腐蚀性侵害，任选地与 Cr2O3。 该涂层优选以可转化成氧化物的可溶性盐的喷雾溶液的形式施用。

公开(公告)号：US4568578A

公开(公告)日：1986-02-04

申请号：US569885

申请日：1984-01-11

申请人： Nanning J. Arfsten ,  Reinhard Kaufmann ,  Helmut Dislich

发明人： Nanning J. Arfsten ,  Reinhard Kaufmann ,  Helmut Dislich

IPC分类号： C01G19/00 ,  C03C17/00 ,  C03C17/25 ,  C03C17/27 ,  C03C17/34 ,  C03C27/12 ,  C23C18/12 ,  G02F1/1343 ,  B32B17/06 ,  B05D1/38 ,  B05D3/02

CPC分类号： C03C17/27 ,  C03C17/3417 ,  C03C2217/23 ,  C03C2217/231 ,  C03C2218/111 ,  C03C2218/322 ,  C03C2218/324 ,  G02F1/13439 ,  Y10T428/265

摘要： A process for the production of transparent, electrically conductive, infrared-reflecting indium oxide-tin oxide layers, especially on glass panes, involves steps wherein the glass panes are dipped into a first solution containing a hydrolyzable silicon compound and hydrolyzable compounds of titanium, zirconium, aluminum, tin or tantalum;the glass panes are heated up to 450.degree. C. in a moisture-containing atmosphere;the initially coated panes are dipped into a second solution containing hydrolyzable compounds of indium and of tin;the panes are dried at temperatures below 250.degree. C.; andthe panes are finally heated up to 550.degree. C. in a reducing atmosphere.

摘要翻译： 用于生产透明导电的红外反射氧化铟锡氧化物层的方法，特别是在玻璃板上的方法涉及将玻璃板浸入含有可水解硅化合物的第一溶液和钛，锆的可水解化合物的步骤 ，铝，锡或钽; 玻璃板在含湿气氛中加热至450℃; 将初始涂覆的窗玻璃浸入含有可水解的铟和锡化合物的第二溶液中; 玻璃板在低于250℃的温度下干燥。 最后在还原气氛中将玻璃板加热至550℃。