Resinous particles, method for production thereof, and uses therefor
    1.
    发明授权
    Resinous particles, method for production thereof, and uses therefor 失效
    树脂颗粒,其制造方法及其用途

    公开(公告)号:US5420218A

    公开(公告)日:1995-05-30

    申请号:US77560

    申请日:1993-06-15

    摘要: A polymeric monomer (A) having as a main component thereof a (meth)acryl type monomer which is subjected to aqueous suspension polymerization in the presence of a compound (B) which is substantially insoluble in water and sparingly soluble in the polymeric monomer (A). The compound (B) has at least one, preferably two or more, structural units, selected from the group consisting of --SH, --S--S--, --COOH, --NO.sub.2, and --OH. The use of compound (B), in the suspension polymerization of the (meth)acryl type monomer, represses of the production of by-produced minute particles due to sympathetic emulsion polymerization. The suspension polymerization permits production of meth)acryl type polymer particles having high heat stability and a small range of particle diameters.

    摘要翻译: 作为主要成分的(甲基)丙烯酸类单体的聚合单体(A),其在基本上不溶于水并微溶于聚合单体(A)的化合物(B)的存在下进行水性悬浮聚合 )。 化合物(B)具有至少一个,优选两个或更多个选自-SH,-S-S-,-COOH,-NO 2和-OH的结构单元。 在(甲基)丙烯酸类单体的悬浮聚合中使用化合物(B)抑制由于交联乳液聚合而产生副生成的微小颗粒。 悬浮聚合可以生产具有高热稳定性和小范围的粒径的甲基丙烯酸类聚合物颗粒。