摘要:
A polymeric monomer (A) having as a main component thereof a (meth)acryl type monomer which is subjected to aqueous suspension polymerization in the presence of a compound (B) which is substantially insoluble in water and sparingly soluble in the polymeric monomer (A). The compound (B) has at least one, preferably two or more, structural units, selected from the group consisting of --SH, --S--S--, --COOH, --NO.sub.2, and --OH. The use of compound (B), in the suspension polymerization of the (meth)acryl type monomer, represses of the production of by-produced minute particles due to sympathetic emulsion polymerization. The suspension polymerization permits production of meth)acryl type polymer particles having high heat stability and a small range of particle diameters.
摘要:
A polymeric monomer (A) having as a main component thereof a (meth)acryl type monomer which is subjected to aqueous suspension polymerization in the presence of a compound (B) which is substantially insoluble in water and sparingly soluble in the polymeric monomer (A). The compound (B) has at least one, preferably two or more, structural units, selected from the group consisting of --SH, --S--S--, --COOH, --NO.sub.2, and --OH. The use of compound (B), in the suspension polymerization of the (meth)acryl type monomer, represses of the production of by-produced minute particles due to sympathetic emulsion polymerization. The suspension polymerization permits production of (meth)acryl type polymer particles having high heat stability and a small range of particle diameters.
摘要:
A carbon black graft polymer which excels in stability of dispersion in various media, coloring property, and imperviousness to light is obtained by mixing under heating a block- or graft-copolymer having a segment (A) containing a reactive group capable of reacting with a functional group on the surface of carbon black and a segment (B) different in skeletal structure from the segment (A) with carbon black. The carbon black graft polymer, by causing the graft chain thereof to incorporate therein an ethylenically unsaturated double bond and/or a carboxyl group, is enabled to manifest photosensitivity, developability with an alkali, and insulating property and acquire usefulness for a black photocurable resin composition such as, for example, the material for the formation of a black matrix particularly in a color filter.