公开(公告)号：US4642325A

公开(公告)日：1987-02-10

申请号：US720602

申请日：1985-04-05

Applicant: Yutaka Otsuki ,  Hiroyoshi Omika ,  Akio Oshima ,  Yoshihiko Araki ,  Yasuyuki Tsuchiya

Inventor： Yutaka Otsuki ,  Hiroyoshi Omika ,  Akio Oshima ,  Yoshihiko Araki ,  Yasuyuki Tsuchiya

IPC: C09D5/44 ,  C08L63/10

CPC classification number: C09D5/4488

Abstract: A cathode-depositing electrodeposition coating composition having excellent low-temperature curability comprising as essential ingredients(A) 100 parts by weight of a reaction product of (1) a high molecular compound having a molecular weight of 500 to 5,000 and containing carbon-carbon double bonds with an iodine number of 50 to 500 and 3 to 12% by weight of oxirane oxygen, and (2) 30 to 300 millimoles, per 100 g of the high molecular compound (1), of a specified amine compound,(B) 10 to 200 parts by weight of a reaction product of a specified diglycidyl compound with 1.9 to 2.1 moles, per molecule of the diglycidyl compound, of an alpha, beta-unsaturated carboxylic acid or an unsaturated fatty acid having a molecular weight of 100 to 350 and containing at least 10% by weight of a carbon-carbon double bond, or a mixture of both,(C) 0.5 to 10 parts by weight of a reaction product of a high molecular compound having a molecular weight of 500 to 5,000 and containing a carbon-carbon double bond with an iodine number of 50 to 500 and 40 to 400 millimoles, per 100 g of the high molecular compound, of a specified alpha, beta-unsaturated dicarboxylic acid and(D) 0.005 to 1.0 part by weight, as metal, of a water-soluble salt of an organic acid with a metal selected from manganese, cobalt, and copper.

Abstract translation: 一种阴极沉积电沉积涂料组合物，其具有优异的低温固化性，其包含作为必要成分的（A）100重量份的（1）分子量为500-5000的高分子化合物和含有碳 - 碳双键的反应产物 （A）的碘值为50〜500，3〜12重量％的环氧乙烷的氧键，（2）30〜300毫摩尔的高分子化合物（1），（B） 每分子二缩水甘油基化合物，分子量为100〜350的α，β-不饱和羧酸或不饱和脂肪酸，10〜200重量份指定的二缩水甘油基化合物与1.9〜2.1摩尔的反应产物 并且含有至少10重量％的碳 - 碳双键或两者的混合物，（C）0.5至10重量份的分子量为500至5000的高分子化合物的反应产物并含有 碳碳做 每100克高分子化合物，指定的α，β-不饱和二羧酸和（D）0.005至1.0重量份的作为金属的碘值为50至500和40至400毫摩尔的碘值， 具有选自锰，钴和铜的金属的有机酸的水溶性盐。

公开(公告)号：US4370453A

公开(公告)日：1983-01-25

申请号：US255664

申请日：1981-04-20

Applicant: Hiroyoshi Omika ,  Hajime Hara ,  Yutaka Otsuki ,  Yoshihiko Araki ,  Kazuho Aoyama

Inventor： Hiroyoshi Omika ,  Hajime Hara ,  Yutaka Otsuki ,  Yoshihiko Araki ,  Kazuho Aoyama

IPC: C08F8/14 ,  C08F8/32 ,  C08F8/44 ,  C08F290/00 ,  C08F299/00 ,  C08F299/02 ,  C08G59/00 ,  C08G59/14 ,  C08G59/16 ,  C08G59/17 ,  C08G59/34 ,  C09D5/44 ,  C09D163/00 ,  C08L63/00 ,  C09D3/58 ,  C09D5/40

CPC classification number: C08G59/027 ,  C08G59/1433 ,  C08G59/1494 ,  C09D5/4438 ,  C09D5/4473

Abstract: A process for preparing a cathodic electrodepositable coating composition which comprises, in sequence,(i) epoxidizing a high-molecular-weight compound containing a carbon-carbon double bond and having a molecular weight of 500 to 10,000 and an iodine value of 100 to 500 to form an epoxidized high-molecular-weight compound containing 0.5 to 12% by weight of oxirane oxygen,(ii) reacting a part of the epoxy groups of the epoxidized high-molecular-weight compound with a basic amine compound of the general formula ##STR1## wherein R.sub.1 and R.sub.2, independently from each other, represent a hydrocarbon group having 1 to 10 carbon atoms which may be partly replaced by a hydroxyl group, and R.sub.1 and R.sub.2 together may form a cyclic structure,(iii) reacting a part or the whole of the remaining epoxy groups with an .alpha.,.beta.-unsaturated monocarboxylic acid of the general formula ##STR2## wherein R.sub.3 and R.sub.4 represent a hydrogen atom or a methyl group, at least one of them being a hydrogen atom,to prepare a resin composition, and(iv) neutralizing the resin composition with an organic or inorganic acid to render it water-soluble or water-dispersible.

Abstract translation: 一种制备阴极电沉积涂料组合物的方法，其顺序包括（i）环氧化含有碳 - 碳双键并且分子量为500至10,000且碘值为100至500的高分子量化合物 形成环氧化的高分子量化合物，其含有0.5〜12重量％的环氧乙烷氧，（ii）将一部分环氧化高分子量化合物的环氧基与通式 其中R1和R2彼此独立地表示可以部分被羟基取代的具有1-10个碳原子的烃基，并且R 1和R 2可以一起形成环状结构，（iii）使一部分或 剩余的全部环氧基与通式为“IMAGE”的α，β-不饱和一元羧酸，其中R3和R4代表氢原子或甲基，至少其中一个为氢原子，制备 是树脂组合物，（iv）用有机或无机酸中和树脂组合物，使其具有水溶性或水分散性。

公开(公告)号：US4563501A

公开(公告)日：1986-01-07

申请号：US493277

申请日：1983-05-10

Applicant: Yutaka Otsuki ,  Yoshihiko Araki ,  Hiroyoshi Omika ,  Hajime Hara ,  Kazuho Aoyama

Inventor： Yutaka Otsuki ,  Yoshihiko Araki ,  Hiroyoshi Omika ,  Hajime Hara ,  Kazuho Aoyama

IPC: C08C19/36 ,  C08C19/40 ,  C09D5/44 ,  C09D163/10 ,  C09D5/40

CPC classification number: C09D5/4473 ,  C08C19/36 ,  C08C19/40 ,  C09D163/10 ,  Y10S525/922

Abstract: A cathode-precipitating electrodeposition coating composition consisting essentially of (A) 100 parts of a high-molecular-weight compound having a molecular weight of 500 to 10,000 and containing an amino group and a carbon-carbon double bond, (B) 3 to 200 parts by weight of a reaction product obtained by reacting an unsaturated carboxylic acid having 3 or 4 carbon atoms with the terminal glycidyl group of a glycidyl compound obtained by reacting a bisphenol with epichlorohydrin, and (C) 0.2 to 20 parts by weight of an oil-soluble manganese salt of a monoester of a 1,2-dicarboxylic acid or a manganese salt of sulfonated or maleinized polybutadiene having a molecular weight of 300 to 3,000.

Abstract translation: 一种阴极沉淀电沉积涂料组合物，主要由（A）100份分子量为500至10,000的含有氨基和碳 - 碳双键的高分子量化合物，（B）3至200 将通过使具有3或4个碳原子的不饱和羧酸与通过使双酚与表氯醇反应获得的缩水甘油基化合物的末端缩水甘油基反应得到的反应产物重量份（C）0.2至20重量份的油 可溶的1,2-二羧酸的单酯或分子量为300〜3000的磺化或马来化聚丁二烯的锰盐的锰盐。

公开(公告)号：US4543406A

公开(公告)日：1985-09-24

申请号：US661177

申请日：1984-10-15

Applicant: Yutaka Otsuki ,  Hiroyoshi Omika ,  Akio Oshima ,  Yoshihiko Araki ,  Yasuyuki Tsuchiya

Inventor： Yutaka Otsuki ,  Hiroyoshi Omika ,  Akio Oshima ,  Yoshihiko Araki ,  Yasuyuki Tsuchiya

IPC: C08G59/16 ,  C08G59/42 ,  C08G59/68 ,  C09D5/44 ,  C09D163/10 ,  C08L63/10 ,  C08L63/08

CPC classification number: C09D5/4473 ,  C08G59/1455 ,  C08G59/4292 ,  C08G59/68 ,  C09D163/10

Abstract: A cathode-precipitating electrodeposition coating having excellent low-temperature curability, said composition consisting essentially of(A) 100 parts by weight of a high molecular compound having a molecular weight of 500 to 10,000 and containing carbon-carbon double bonds with an iodine value of 50 to 500 and 30 to 300 millimoles of amino groups per 100 g,(B) 10 to 200 parts by weight of a product of reaction of a diglycidyl compound represented by the general formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 represent a hydrogen atom or a methyl group and n represents an integer of from 0 to 20, with at least one organic acid component selected from the group consisting of(a) both an alpha,beta-unsaturated dicarboxylic acid and an alpha,beta-unsaturated monocarboxylic acid, (b) an unsaturated fatty acid containing at least 10% by weight of carbon-carbon conjugated double bonds and having a molecular weight of 100 to 350, and (c) an alpha,beta-unsaturated monocarboxylic acid, a 1,2-dicarboxylic acid anhydride, and a monoepoxy compound in this sequence, and(C) 0.005 to 1.0 part by weight as metal of a manganese salt of an organic acid or manganese dioxide.

Abstract translation: 一种具有优异的低温固化性的阴极沉淀电沉积涂料，所述组合物基本上由（A）100重量份的分子量为500至10,000的高分子化合物组成，并且含有碳 - 碳双键，碘值为 50至500和30至300毫摩尔氨基/ 100g，（B）10至200重量份由通式（IMAGE）+ TR＆lt; IMAGE＆gt;表示的二缩水甘油基化合物的反应产物，其中R1，R2 并且R 3表示氢原子或甲基，n表示0至20的整数，其中至少一种有机酸组分选自（a）α，β-不饱和二羧酸和α， β-不饱和单羧酸，（b）含有至少10重量％碳 - 碳共轭双键且分子量为100至350的不饱和脂肪酸，和（c）α，β-不饱和一元羧酸， a 1， 2-二羧酸酐和单环氧化合物，（C）0.005〜1.0重量份的有机酸或二氧化锰的锰盐金属。

公开(公告)号：US4283313A

公开(公告)日：1981-08-11

申请号：US89748

申请日：1979-10-30

Applicant: Hiroyoshi Omika ,  Hajime Hara ,  Yutaka Otsuki ,  Yoshihiko Araki ,  Kazuho Aoyama

Inventor： Hiroyoshi Omika ,  Hajime Hara ,  Yutaka Otsuki ,  Yoshihiko Araki ,  Kazuho Aoyama

IPC: C08C19/40 ,  C08G59/14 ,  C09D5/44 ,  C08L63/00 ,  C09D5/40 ,  C25D13/06

CPC classification number: C08C19/40 ,  C08G59/14 ,  C08G59/1433 ,  C09D5/4403 ,  Y10S524/901

Abstract: A coating composition for cathode-precipitating electrodeposition consisting essentially of(A) 100 parts by weight of an unsaturated organic compound having a molecular weight of 500 to 10,000 containing a carbon-carbon double bond in an amount corresponding to an iodine value of 100 to 500, said unsaturated organic compound having bonded thereto, through a carbon-carbon bond, basic groups of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and X are as defined in claim 1, the amount of said basic groups in said component (A) being 0.02 to 0.3 mole per 100 g of said component (A), and(B) 3 to 100 parts by weight of at least one compound represented by the general formula ##STR2## wherein R.sub.5, R.sub.6, n, m, Y and Y' are as defined in claim 1, said component (A) and said component (B) being neutralized with an organic acid or an inorganic acid and dissolved or dispersed in water.

Abstract translation: 一种用于阴极沉淀电沉积的涂料组合物，其基本上由（A）100重量份的含有对应于碘值为100至500的量的碳 - 碳双键的分子量为500至10,000的不饱和有机化合物 通过碳 - 碳键键合的所述不饱和有机化合物，其中R 1，R 2，R 3，R 4和X如权利要求1中所定义的通式为“IMAGE”的碱基，所述组分中所述碱性基团的量 （A）每100g所述组分（A）为0.02至0.3摩尔，和（B）3至100重量份的至少一种由通式 IMA表示的化合物，其中R 5，R 6，n ，m，Y和Y'如权利要求1所定义，所述组分（A）和所述组分（B）用有机酸或无机酸中和并溶解或分散在水中。

公开(公告)号：US6057900A

公开(公告)日：2000-05-02

申请号：US113999

申请日：1998-07-10

Applicant: Norikatsu Ono ,  Masayuki Ando ,  Yutaka Otsuki ,  Hiroyoshi Omika

Inventor： Norikatsu Ono ,  Masayuki Ando ,  Yutaka Otsuki ,  Hiroyoshi Omika

IPC: G02F1/1335 ,  G02F1/1339 ,  G02F1/1333

CPC classification number: G02F1/1339 ,  G02F1/133514

Abstract: A color liquid crystal display device contains a color filter substrate, a counterelectrode substrate disposed to oppose the color filter substrate via a sealing material disposed in contact with peripheral portions of the color filter substrate and the counterelectrode substrate, and a liquid crystal layer sealed between the color filter substrate and the counterelectrode substrate and surrounded by the sealing material. The color filter substrate contains a transparent substrate, a black matrix and a plurality of colored layers of plural colors, the black matrix and the colored layers being formed in a predetermined pattern in a first region on the transparent substrate, and a resin layer having substantially same thickness as that of the black matrix and formed in a second peripheral region on the transparent substrate positioned peripherally adjacent to the first region. The sealing material is in contact with the resin layer and a black matrix portion in periphery of the first region. A method for producing the color filter substrate involves the steps for forming the resin layer having substantially the same thickness as that of the black matrix.

Abstract translation: 彩色液晶显示装置包括滤色器基板，经由与滤色器基板和反电极基板的周边部分接触设置的密封材料与滤色器基板相对设置的反电极基板，以及密封在滤色器基板之间的液晶层 滤色器基板和反电极基板，并被密封材料包围。 滤色器基板包括透明基板，黑色矩阵和多个多色着色层，黑色矩阵和着色层在透明基板上的第一区域中以预定图案形成，并且具有基本上 形成在与第一区域周边相邻的透明基板上的第二周边区域中。 密封材料与第一区域的周围的树脂层和黑色矩阵部分接触。 用于制造滤色器基板的方法包括用于形成具有与黑矩阵基本上相同的厚度的树脂层的步骤。

公开(公告)号：US5718992A

公开(公告)日：1998-02-17

申请号：US743888

申请日：1996-11-06

Applicant: Haruyoshi Sato ,  Toru Nakamura ,  Hitoshi Yuasa ,  Yutaka Otsuki ,  Hiroyoshi Omika ,  Norikatsu Ono ,  Tadafumi Shindo

Inventor： Haruyoshi Sato ,  Toru Nakamura ,  Hitoshi Yuasa ,  Yutaka Otsuki ,  Hiroyoshi Omika ,  Norikatsu Ono ,  Tadafumi Shindo

IPC: C09D5/44 ,  G02B5/20 ,  G02F1/1335 ,  G03F7/00

CPC classification number: G02F1/133512 ,  G03F7/0007

Abstract: A method for preparing a substrate having a light-shielding layer involves forming a photosensitive coating film on a transparent electrically conductive layer formed on a transparent substrate, exposing the photosensitive coating film via a mask exhibiting light transmitting properties, removing and developing the coating film for exposing the transparent electrically conductive layer and electrodepositing a dark-hued coating on the exposed transparent electrically conductive layer for forming the light-shielding layer, and heating the light-shielding layer. The substrate having the light-shielding layer has a volume resistivity of 1.times.10.sup.2 ohm.cm or higher and may be used for a counterelectrode substrate for a TFT array substrate incorporated in a liquid crystal display device.

Abstract translation: 制备具有遮光层的基板的方法包括在形成于透明基板上的透明导电层上形成感光性涂膜，通过具有透光性的掩模曝光感光性涂膜，除去和显影涂膜 暴露透明导电层并在暴露的透明导电层上电沉积暗色涂层以形成遮光层，并加热遮光层。 具有遮光层的基板具有1×102欧姆·厘米或更高的体积电阻率，并且可以用于结合在液晶显示装置中的TFT阵列基板的反电极基板。

公开(公告)号：US5527649A

公开(公告)日：1996-06-18

申请号：US249754

申请日：1994-05-26

Applicant: Haruyoshi Sato ,  Toru Nakamura ,  Hitoshi Yuasa ,  Yutaka Otsuki ,  Hiroyoshi Omika ,  Norikatsu Ono ,  Tadafumi Shindo

Inventor： Haruyoshi Sato ,  Toru Nakamura ,  Hitoshi Yuasa ,  Yutaka Otsuki ,  Hiroyoshi Omika ,  Norikatsu Ono ,  Tadafumi Shindo

IPC: C09D5/44 ,  G02B5/20 ,  G02F1/1335 ,  G03F7/00

CPC classification number: G02F1/133512 ,  G03F7/0007

Abstract: A method for preparing a substrate having a light-shielding layer involves forming a photosensitive coating film on a transparent electrically conductive layer formed on a transparent substrate, exposing the photosensitive coating film via a mask exhibiting light transmitting properties, removing and developing the coating film for exposing the transparent electrically conductive layer and electrodepositing a dark-hued coating on the exposed transparent electrically conductive layer for forming the light-shielding layer, and heating the light-shielding layer. The substrate having the light-shielding layer has a volume resistivity of 1.times.10.sup.2 ohm.multidot.cm or higher and may be used for a counterelectrode substrate for a TFT array substrate incorporated in a liquid crystal display device.

Abstract translation: 制备具有遮光层的基板的方法包括在形成于透明基板上的透明导电层上形成感光性涂膜，通过具有透光性的掩模曝光感光性涂膜，除去和显影涂膜 暴露透明导电层并在暴露的透明导电层上电沉积暗色涂层以形成遮光层，并加热遮光层。 具有遮光层的基板的体积电阻率为1×102ohm×cm以上，可以用于配置在液晶显示装置中的TFT阵列基板的反电极基板。

公开(公告)号：US4423172A

公开(公告)日：1983-12-27

申请号：US363427

申请日：1982-03-30

Applicant: Yutaka Otsuki ,  Yoshihiko Araki ,  Hiroyoshi Omika ,  Hajime Hara ,  Kazuho Aoyama

Inventor： Yutaka Otsuki ,  Yoshihiko Araki ,  Hiroyoshi Omika ,  Hajime Hara ,  Kazuho Aoyama

IPC: C08C19/36 ,  C08F299/02 ,  C08G59/60 ,  C09D5/44 ,  C09D133/04 ,  C09D163/00 ,  C09D201/02 ,  C08K5/07

CPC classification number: C09D5/4473 ,  C08C19/36 ,  C08F299/02 ,  C08G59/60 ,  C09D163/00

Abstract: A self-curable coating composition for cathode-precipitating electrodeposition is disclosed which essentially comprises a water-dispersible resin having a carbon-carbon double bond and a tertiary amino group and an epoxy resin having a teritary amino group and an unsaturated group of the formula ##STR1## The two resins are neutralized by an acid to render the composition water-soluble or water-dispersible.

Abstract translation: 公开了一种用于阴极沉淀电沉积的自固化涂料组合物，其主要包括具有碳 - 碳双键和叔氨基的水分散性树脂和具有无定形氨基的环氧树脂和式 图像>两种树脂被酸中和以使组合物具有水溶性或水分散性。

公开(公告)号：US5665496A

公开(公告)日：1997-09-09

申请号：US489817

申请日：1995-06-13

Applicant: Hiroyoshi Omika ,  Yutaka Otsuki ,  Hitoshi Yuasa ,  Eiji Yoda ,  Toru Nakamura ,  Masayuki Ando ,  Teruhisa Kuroki ,  Norikatsu Ono

Inventor： Hiroyoshi Omika ,  Yutaka Otsuki ,  Hitoshi Yuasa ,  Eiji Yoda ,  Toru Nakamura ,  Masayuki Ando ,  Teruhisa Kuroki ,  Norikatsu Ono

IPC: G03F7/00 ,  G03F9/00

CPC classification number: G03F7/0007

Abstract: A method for producing a color filter involves (a) forming a positive photosensitive coating film on a transparent electrically conductive layer of a transparent substrate; (b) forming a light-irradiated region where a light irradiation amount is different in two steps; (c) developing a larger light-irradiated portion to lay-open the transparent electrically conductive layer followed by electrodepositing a light shielding layer thereon; (d) forming on the positive photosensitive coating film undeveloped in the step (c) a light-irradiated region where a light irradiation amount is different in two steps; (e) developing a larger light-irradiated portion of the photosensitive coating film to lay-open the transparent electrically conductive layer followed by electrodepositing a colored coating thereon; (f) forming on the positive photosensitive coating film undeveloped in the step (e) a light-irradiated region where a light irradiation amount is different in at least three steps; and (g) developing the photosensitive coating film to lay-open the transparent electrically conductive layer followed by electrodepositing a colored coating thereon, operation of the developing and electrodepositing being sequentially repeated at least twice in decreasing light irradiation amounts.

Abstract translation: 制造滤色器的方法包括：（a）在透明基板的透明导电层上形成正性感光性涂膜; （b）在两个步骤中形成光照射量不同的光照射区域; （c）显影较大的光照射部分以打开透明导电层，随后在其上电沉积遮光层; （d）在步骤（c）中未显影的正光敏涂层上形成两个光照射量不同的光照射区域; （e）显影感光性涂膜的较大的光照射部分，以打开透明导电层，然后在其上电沉积着色涂层; （f）在步骤（e）中未显影的正光敏涂层上形成至少三个步骤中光照射量不同的光照射区域; 和（g）显影感光涂膜以打开透明导电层，随后在其上电沉积着色涂层，显影和电沉积的操作在减少光照射量下依次重复至少两次。