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6 条记录 (耗时 0.017 秒)

    Method and agent for enhancing diffusivity and long-lasting property of fragrance
    1.
    发明授权
    Method and agent for enhancing diffusivity and long-lasting property of fragrance 有权

    公开(公告)号：US07538081B2

    公开(公告)日：2009-05-26

    申请号：US09949718

    申请日：2001-09-12

    申请人： Kenya Ishida ,  Takashi Nishida ,  Hiroyuki Matsuda ,  Hisao Iwai ,  Toshimitsu Hagiwara

    发明人： Kenya Ishida ,  Takashi Nishida ,  Hiroyuki Matsuda ,  Hisao Iwai ,  Toshimitsu Hagiwara

    IPC分类号： A61K8/00

    CPC分类号： A61Q13/00 ,  A23L2/56 ,  A61K8/34 ,  C11B9/0034

    摘要： A fragrance composition having an excellent diffusivity and long-lasting property of fragrance and a cosmetic, toiletry, bath composition, food and drink and pharmaceutical having an excellent diffusivity and long-lasting property of fragrance by using a novel fixative. A compound represented by the following general formula (1) is incorporated in a fragrance composition or the foregoing products. The amount of the compound of the general formula (1) to be incorporated in the fragrance composition is preferably from 0.01 to 90% by weight. The amount of the compound of the general formula (1) to be incorporated directly in the foregoing products is preferably from 0.0001 to 2.0 times (by weight) the weight of the aroma composition and/or composition to be incorporated therein. In this arrangement, a fragrance composition or products having an enhanced diffusivity and long-lasting property of fragrance can be obtained without causing any safety problem on human being. wherein A represents H or OH group; B represents H or methyl group; and n represents an integer of from 0 to 2.

    Diene compound and process for producing the same
    3.
    发明授权
    Diene compound and process for producing the same 失效
    二烯化合物及其制备方法

    公开(公告)号：US06323174B1

    公开(公告)日：2001-11-27

    申请号：US09571549

    申请日：2000-05-16

    申请人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

    发明人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

    IPC分类号： A61K746

    CPC分类号： C11B9/0019 ,  C07C2/04 ,  C07C45/54 ,  C07C47/21 ,  C07C67/293 ,  C07C2531/22 ,  C11B9/0007 ,  C07C11/12 ,  C07C69/007 ,  C07C69/145 ,  C07C69/16 ,  C07C69/24

    摘要： The invention provides a chain diene compound with desirable regioselectivity, in the presence of a specific ruthenium compound. This chain diene compound is a promising raw material for terpene. It has a structure represented by the general formula (I): wherein R1 represents H, a C1-C6 alkyl group which may be substituted or a C2-C6 alkenyl group which may be substituted, R2 represents a phenyl group which may have a C1-C4 alkyl group or a C1-C12 acyloxy group which may have a phenyl group or a naphthyl group, or a benzyl group or R2 is a hydroxy group which reversibly forms an aldehyde group through shifting of the position of the double bond adjacent to said hydroxy group. The chain diene compound is produced by reacting 2-substituted-1,3-butadienes with terminal olefins in the presence of a ruthenium compound in a hydrophilic solvent. Further, the above method provides an inexpensive process for preparing a mild fragrant component and a perfume composition, such as 4-methyl-5-hexen-1-al and 4-vinyl-8-methyl-7-nonenal.

    摘要翻译： 在特定的钌化合物的存在下，本发明提供具有理想的区域选择性的链二烯化合物。 该链二烯化合物是萜烯的有希望的原料。 它具有由通式（I）表示的结构：其中R1表示H，可被取代的C1-C6烷基或可被取代的C2-C6烯基，R2表示可具有C1 -C4烷基或可以具有苯基或萘基的C1-C12酰氧基或苄基，或R2是通过使所述双键邻近的所述双键移位而可逆地形成醛基的羟基 羟基。 链二烯化合物通过在亲水性溶剂中在钌化合物的存在下使2-取代-1,3-丁二烯与末端烯烃反应制备。 此外，上述方法提供了用于制备温和香料组分和香料组合物的廉价方法，例如4-甲基-5-己烯-1-醇和4-乙烯基-8-甲基-7-壬烯醛。

    Diene compound and process for producing the same
    4.
    发明授权
    Diene compound and process for producing the same 失效
    二烯化合物及其制备方法

    公开(公告)号：US06239324B1

    公开(公告)日：2001-05-29

    申请号：US09383920

    申请日：1999-08-26

    申请人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

    发明人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

    IPC分类号： C07C202

    CPC分类号： C11B9/0019 ,  C07C2/04 ,  C07C45/54 ,  C07C47/21 ,  C07C67/293 ,  C07C2531/22 ,  C11B9/0007 ,  C07C11/12 ,  C07C69/007 ,  C07C69/145 ,  C07C69/16 ,  C07C69/24

    摘要： The invention provides a chain diene compound with desirable regioselectivity, in the presence of a specific ruthenium compound. This chain diene compound is a promising raw material for terpene. It has a structure represented by the general formula (IX): wherein R1 represents H, a C1-C6 alkyl group which may be substituted or a C2-C6 alkenyl group which may be substituted, R2 represents a phenyl group which may have a C1-C4 alkyl group or a C1-C12 acyloxy group which may have a phenyl group or a naphthyl group, or a benzyl group or R2 is a hydroxy group which reversibly forms an aldehyde group through shifting of the position of the double bond adjacent to said hydroxy group. The chain diene compound is produced by reacting 2-substituted-1,3-butadienes with terminal olefins in the presence of a ruthenium compound in a hydrophilic solvent. Further, the above method provides an inexpensive process for preparing a mild fragrant component and a perfume composition, such as 4-methyl-5-hexen-1-al and 4-vinyl-8-methyl-7-nonenal.

    摘要翻译： 在特定的钌化合物的存在下，本发明提供具有理想的区域选择性的链二烯化合物。 该链二烯化合物是萜烯的有希望的原料。 其具有由通式（IX）表示的结构：其中R 1表示H，可被取代的C 1 -C 6烷基或可被取代的C 2 -C 6烯基，R 2表示可具有C 1 -C4烷基或可以具有苯基或萘基的C1-C12酰氧基或苄基，或R2是通过使所述双键邻近的所述双键的位置的移动可逆地形成醛基的羟基 羟基。 链二烯化合物通过在亲水性溶剂中在钌化合物的存在下使2-取代-1,3-丁二烯与末端烯烃反应制备。 此外，上述方法提供了用于制备温和香料组分和香料组合物的廉价方法，例如4-甲基-5-己烯-1-醇和4-乙烯基-8-甲基-7-壬烯醛。