Optically active transition metal-diamine compound and process for producing optically active alcohol with the same
    2.
    发明授权
    Optically active transition metal-diamine compound and process for producing optically active alcohol with the same 有权
    光活性过渡金属 - 二胺化合物及其制备光学活性醇的方法

    公开(公告)号:US07754889B2

    公开(公告)日:2010-07-13

    申请号:US10594744

    申请日:2005-03-28

    IPC分类号: C07F15/00

    摘要: The present invention provides a water-soluble transition metal-diamine complex which can be easily separated from reaction products through liquid separation, etc. and is recycleable; an optically active diamine compound constituting the ligand of the complex; and a catalyst for asymmetric synthesis which comprises these. The present invention relates to a water-soluble optically active transition metal-diamine complex represented by the formula (2): [wherein R1 and R2 each represents hydrogen, a hydrocarbon group, —SO2R13 (wherein R13 is a hydrocarbon group, substituted amino, etc.), etc.; R3 to R12 each represents hydrogen, a hydrocarbon group, alkoxy, substituted amino, etc.; M represents a transition metal; X represents halogen; L represents a ligand; and * indicates an asymmetric carbon atom; provided that at least one of R3 to R7 and R8 to R12 is substituted amino], a catalyst for asymmetric synthesis containing the complex, and a process for producing an optically active alcohol, which comprises using the catalyst to asymmetrically reduce a ketone.

    摘要翻译: 本发明提供一种水溶性过渡金属 - 二胺络合物,其可以通过液体分离等容易地从反应产物中分离出来并且是可再循环的; 构成络合物配体的光学活性二胺化合物; 和包含这些的不对称合成催化剂。 本发明涉及由式(2)表示的水溶性光学活性过渡金属 - 二胺络合物:其中R1和R2各自表示氢,烃基,-SO2R13(其中R13为烃基,取代氨基, 等等) R3至R12各自表示氢,烃基,烷氧基,取代的氨基等; M表示过渡金属; X表示卤素; L表示配体; 和*表示不对称碳原子; 条件是R 3至R 7和R 8至R 12中的至少一个为取代的氨基],含有络合物的不对称合成催化剂,以及制备光学活性醇的方法,其包括使用该催化剂不对称还原酮。

    Process for producing 3-1-menthoxypropane-1,2-diol
    3.
    发明授权
    Process for producing 3-1-menthoxypropane-1,2-diol 有权
    制备3-1-薄荷氧基丙-1,2-二醇的方法

    公开(公告)号:US06407293B1

    公开(公告)日:2002-06-18

    申请号:US09962122

    申请日:2001-09-26

    IPC分类号: C07C3512

    CPC分类号: C07C43/196 C07C41/03

    摘要: A process for producing highly pure 3-1-menthoxypropane-1,2-diol safely and efficiently, and an intermediate to be used in the process. 3-1-menthoxypropane-1,2-diol represented by the chemical formula (IV) is produced by adding 1-menthol to a 1,2-epoxy-3-halogenopropane represented by the following general formula (I) (wherein X represents a halogen atom) in an organic solvent in the presence of a Lewis acid to produce a novel 1-halogeno-3-1-menthoxypropan-2-ol represented by the following general formula (II), then, epoxidating it with a base in the presence of a phase transfer catalyst to produce a 1,2-epoxy-3-1-menthoxypropane represented by the chemical formula (III), and further hydrolyzing it.

    摘要翻译: 安全有效地生产高纯度3-1-薄荷氧基丙二醇-1,2-二醇的方法,以及该方法中使用的中间体。 由化学式(IV)表示的3-1-薄荷氧基丙烷-1,2-二醇通过将1-薄荷醇加入到由下列通式(I)表示的1,2-环氧-3-氯代丙烷中(其中X表示 卤素原子)在有机溶剂中在路易斯酸存在下反应,得到由以下通式(II)表示的新型1-卤代-3-三氟甲氧基丙-2-醇,然后用碱进行环氧化 存在相转移催化剂以制备由化学式(III)表示的1,2-环氧-3-丁氧基丙烷,并进一步水解。

    Lawn mower with detachable inner members in cutter housing
    6.
    发明授权
    Lawn mower with detachable inner members in cutter housing 失效
    割草机与切割机壳体中可拆卸的内部构件

    公开(公告)号:US5210998A

    公开(公告)日:1993-05-18

    申请号:US822739

    申请日:1992-01-21

    IPC分类号: A01D34/00

    CPC分类号: A01D34/005 A01D2101/00

    摘要: A lawn mower has a cutter blade rotatable in a substantially horizontal plane, and a cutter housing with the cutter blade being rotatably accommodated therein, the cutter housing comprising an upper wall having a raised scroll, and a circumferential wall having a discharge duct contiguous to the scroll and defining a discharge port. A first inner member is detachably disposed along inner surfaces of the upper and circumferential walls of the cutter housing, the first inner member having an inner surface of arcuate cross section. A second inner member is detachably disposed in the discharge duct contiguously to the first inner member in closing relationship to the discharge port, the second inner member being separate from the first inner member and having an inner surface of arcuate cross section.

    摘要翻译: 割草机具有可在基本水平的平面中旋转的切割刀片,并且具有可旋转地容纳在其中的切割刀片的切割器壳体,所述切割器壳体包括具有升高的涡卷的上壁,以及周壁,其具有与所述切割刀片相邻的排出管 滚动并定义排放口。 第一内部构件沿着切割器壳体的上壁和周壁的内表面可拆卸地设置,第一内部构件具有弓形横截面的内表面。 第二内部构件以与排出口关闭的关系与第一内部构件连续地可拆卸地设置在排出管道中,第二内部构件与第一内部构件分离并且具有弓形横截面的内表面。

    Lawn mower with blower
    7.
    发明授权
    Lawn mower with blower 失效
    割草机与鼓风机

    公开(公告)号:US4996829A

    公开(公告)日:1991-03-05

    申请号:US422224

    申请日:1989-10-16

    IPC分类号: A01D34/63 A01D43/077

    摘要: A riding lawn mower comprises a frame supported by wheels, a mower housing carried at the underside of the frame, a plurality of cutter blades located within the mower housing to cut grass, a collection bag mounted on the rear of the frame, a discharge chute extending between the mower housing and the collection bag and defining a clipping path from the cutter blades into the collection bag, a blower including an impeller housing attached to the mower housing and an impeller located within the impeller housing and cooperating with the butter blades to convey the grass clippings into the collection bag through the discharge chute. A short conduit connects the impeller housing to the upstream end of the discharge chute to conduct an air generated by the impeller into the discharge chute. A central axis of the conduit is offset downwardly from a central axis of the discharge chute.

    摘要翻译: 骑马割草机包括由车轮支撑的框架,在框架的下侧承载的割草机壳体,位于割草机壳体内以切割草的多个切割刀片,安装在框架后部的收集袋,排料槽 在割草机壳体和收集袋之间延伸并且限定从切割刀片进入收集袋的剪切路径,鼓风机,包括附接到割草机壳体的叶轮壳体和位于叶轮壳体内的叶轮并与黄油叶片配合以传送 草屑通过排放槽进入收集袋。 短管道将叶轮壳体连接到排放槽的上游端,以将由叶轮产生的空气导入排料槽。 导管的中心轴线从排出槽的中心轴线向下偏移。

    Grass cutting height indicator for lawn mower and tractor combination
    8.
    发明授权
    Grass cutting height indicator for lawn mower and tractor combination 失效
    草坪割草机和拖拉机组合的割草高度指示器

    公开(公告)号:US4577455A

    公开(公告)日:1986-03-25

    申请号:US676907

    申请日:1984-11-30

    摘要: A grass cutting height indicator in a combination of a lawn mower and a power-driven tractor having an operator's seat, including a lawn mower unit suspended from a tractor frame of the tractor, an adjusting lever disposed adjacent to the operator's seat, and a link mechanism operatively connected between the adjusting lever and the lawn mower unit for adjusting the height of the lawn mower unit above ground in response to operation of the adjusting lever. The indicator comprises an indicator member mounted on the link mechanism and having indicia for indicating grass cutting heights, and an indicator window defined in a tractor body adjacent to the operator's seat, the indicator member being positioned so that the indicia has at least a portion thereof facing the indicator window.

    摘要翻译: 一种割草高度指示器,其包括具有操作者座椅的割草机和动力拖拉机的组合,包括从拖拉机的拖拉机架悬挂的割草机单元,与操作者座椅相邻设置的调节杆,以及连杆 可操作地连接在调节杆和割草机单元之间的机构,用于响应于调节杆的操作来调节割草机单元在地面上方的高度。 指示器包括安装在连杆机构上并具有指示切割高度的指示器的指示器部件和与操作者座椅相邻的拖拉机主体中限定的指示器窗口,该指示器部件定位成使得标记具有至少一部分 面向指示窗。

    SACRIFICIAL ELECTRODE MOUNTING STRUCTURE
    9.
    发明申请
    SACRIFICIAL ELECTRODE MOUNTING STRUCTURE 有权
    极性电极安装结构

    公开(公告)号:US20100251978A1

    公开(公告)日:2010-10-07

    申请号:US12700203

    申请日:2010-02-04

    IPC分类号: F01P11/06

    CPC分类号: F01P11/06

    摘要: Mounting port, provided adjacent to a cooling water passageway, has a hole opening from the passageway for mounting an anode metal in the passageway. Lid member, which closes the outer end of the hole, has a head portion formed at its outer end and an externally threaded portion engageable with an internally threaded portion of the hole with a sealing member sandwiched therebetween. The lid member having the anode metal fixed thereto is inserted in and attached to the port with the threaded portions engaging with each other with a sealing tape sandwiched therebetween. Space is defined between an outer end portion of the port and an outer end portion of the lid member between the head portion and the externally threaded portion so that part of the sealing member protruding from between the threaded portions can be received in the space.

    摘要翻译: 设置在冷却水通道附近的安装口具有从通道开口的孔,用于将阳极金属安装在通道中。 关闭孔的外端的盖构件具有形成在其外端的头部部分和外螺纹部分,该部分可与孔的内螺纹部分接合,密封构件夹在其间。 将固定有阳极金属的盖构件插入并附接到端口,螺纹部分彼此接合,并且夹在其间的密封带。 在端头的外端部和盖部件的外端部之间限定空间,头部和外螺纹部分之间,使得从螺纹部分之间突出的部分密封件能够被容纳在空间中。

    Optically active transition metal-diamine compound and process for producing optically active alcohol with the same
    10.
    发明申请
    Optically active transition metal-diamine compound and process for producing optically active alcohol with the same 有权
    光活性过渡金属 - 二胺化合物及其制备光学活性醇的方法

    公开(公告)号:US20070149831A1

    公开(公告)日:2007-06-28

    申请号:US10594744

    申请日:2005-03-28

    IPC分类号: C07C29/14 C07F15/00

    摘要: The present invention provides a water-soluble transition metal-diamine complex which can be easily separated from reaction products through liquid separation, etc. and is recycleable; an optically active diamine compound constituting the ligand of the complex; and a catalyst for asymmetric synthesis which comprises these. The present invention relates to a water-soluble optically active transition metal-diamine complex represented by the formula (2): [wherein R1 and R2 each represents hydrogen, a hydrocarbon group, —SO2R13 (wherein R13 is a hydrocarbon group, substituted amino, etc.), etc.; R3 to R12 each represents hydrogen, a hydrocarbon group, alkoxy, substituted amino, etc.; M represents a transition metal; X represents halogen; L represents a ligand; and * indicates an asymmetric carbon atom; provided that at least one of R3 to R7 and R8 to R12 is substituted amino], a catalyst for asymmetric synthesis containing the complex, and a process for producing an optically active alcohol, which comprises using the catalyst to asymmetrically reduce a ketone.

    摘要翻译: 本发明提供一种水溶性过渡金属 - 二胺络合物,其可以通过液体分离等容易地从反应产物中分离出来并且是可再循环的; 构成络合物配体的光学活性二胺化合物; 和包含这些的不对称合成催化剂。 本发明涉及由式(2)表示的水溶性光学活性过渡金属 - 二胺络合物:其中R 1和R 2各自表示氢, 烃基,-SO 2 R 13(其中R 13是烃基,取代的氨基等)等; R 12至R 12各自表示氢,烃基,烷氧基,取代的氨基等; M表示过渡金属; X表示卤素; L表示配体; 和*表示不对称碳原子; 条件是R 3至R 7和R 8至R 12中的至少一个为取代的氨基], 含有络合物的不对称合成催化剂,以及制备光学活性醇的方法,其包括使用该催化剂不对称地还原酮。