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公开(公告)号:US20080193839A1
公开(公告)日:2008-08-14
申请号:US12082726
申请日:2008-04-14
摘要: A seal molding material for cell electrolytic solution, which comprises an EPDM composition comprising a peroxide-crosslinkable EPDM and an organic peroxide, the seal molding material being for use at the electrode site of a nickel-hydrogen cell, wherein the EPDM composition comprises preferably 100 parts by weight of a peroxide-crosslinkable EPDM, 10 to 150 parts by weight of a filler and 1 to 8 parts by weight of an organic peroxide, and not more than 40 parts by weight of hydrocarbon-based oil can be further contained. The seal material molded from the seal molding material for cell electrolytic solution has a sufficient durability against a potassium hydroxide-based electrolytic solution and a longer life, and is free from any deterioration, when energized at the electrode site of a nickel-hydrogen cell.
摘要翻译: 一种用于电池电解液的密封成型材料,其包含含有可过氧化物交联的EPDM和有机过氧化物的EPDM组合物,所述密封成型材料用于镍氢电池的电极部位,其中所述EPDM组合物优选为100 可以进一步包含过氧化物交联性EPDM,重量份为10〜150重量份的填料和1〜8重量份的有机过氧化物,以及40重量份以下的烃系油。 由电解质电解液密封成型材料成型的密封材料对氢氧化钾类电解液具有足够的耐久性,寿命更长,并且在镍氢电池的电极部位通电时不会发生劣化。
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公开(公告)号:US20060235164A1
公开(公告)日:2006-10-19
申请号:US10541688
申请日:2004-03-16
IPC分类号: C08F210/18
摘要: A seal molding material for cell electrolytic solution, which comprises an EPDM composition comprising a peroxide-crosslinkable EPDM and an organic peroxide, the seal molding material being for use at the electrode site of a nickel-hydrogen cell, wherein the EPDM composition comprises preferably 100 parts by weight of a peroxide-crosslinkable EPDM, 10 to 150 parts by weight of a filler and 1 to 8 parts by weight of an organic peroxide, and not more than 40 parts by weight of hydrocarbon-based oil can be further contained. The seal material molded from the seal molding material for cell electrolytic solution has a sufficient durability against a potassium hydroxide-based electrolytic solution and a longer life, and is free from any deterioration, when energized at the electrode site of a nickel-hydrogen cell.
摘要翻译: 一种用于电池电解液的密封成型材料,其包含含有可过氧化物交联的EPDM和有机过氧化物的EPDM组合物,所述密封成型材料用于镍氢电池的电极部位,其中所述EPDM组合物优选为100 可以进一步包含过氧化物交联性EPDM,重量份为10〜150重量份的填料和1〜8重量份的有机过氧化物,以及40重量份以下的烃系油。 由电解质电解液密封成型材料成型的密封材料对氢氧化钾类电解液具有足够的耐久性,寿命更长,并且在镍氢电池的电极部位通电时不会发生劣化。
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公开(公告)号:US4877855A
公开(公告)日:1989-10-31
申请号:US228413
申请日:1988-08-05
IPC分类号: C08G69/42 , C08G77/455 , C08G77/54
CPC分类号: C08G77/54 , C08G77/455
摘要: A siloxane-amide block copolymer represented by formula (I): ##STR1## wherein the symbols are as defined in the specification, is disclosed. The polymer of formula (I) is produced by reacting a polycondensate of a diaminosiloxane and a dicarboxylic acid dihalide with an epoxysilane to induce ring-opening addition reaction between the terminal amino groups of the polymer and the epoxy group of the epoxysilane. The siloxane-amide block copolymer exhibits excellent processability and reactive curability due to the hydrolyzable silyl groups at the both terminals.
摘要翻译: 公开了由式(I)表示的硅氧烷 - 酰胺嵌段共聚物:其中符号如说明书中所定义。 通过使二氨基硅氧烷和二羧酸二卤化物的缩聚物与环氧硅烷反应以在聚合物的末端氨基与环氧基硅烷的环氧基之间引发开环加成反应来制备式(I)的聚合物。 硅氧烷 - 酰胺嵌段共聚物由于两端的可水解甲硅烷基而表现出优异的加工性和反应性固化性。
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公开(公告)号:US5328966A
公开(公告)日:1994-07-12
申请号:US380824
申请日:1989-07-17
申请人: Hisayuki Nagaoka
发明人: Hisayuki Nagaoka
IPC分类号: C08G59/00 , C08G59/40 , C08K5/1515 , C08L63/00 , C08L83/04 , C08L83/10 , C08F283/00 , C08G77/00
摘要: Disclosed is a curable resin composition comprising (a) 100 parts by weight of a siloxane-amide block copolymer of formula (1): ##STR1## where R.sup.1 is a substituted or unsubstituted divalent hydrocarbon group; R.sup.2 may be the same or different and each is a substituted or unsubstituted monovalent hydrocarbon group; R.sup.3 is substituted or unsubstituted divalent aromatic hydrocarbon group; and m and an each are a number of 1 or more; (b) from 1 to 100 parts by weight of a crosslinking agent containing 2 or more epoxy groups in the molecule, and (c) up to 15 parts by weight of a curable catalyst. The composition can be cured at room temperature and in the absence of moisture in a closed system to give a cured product having high oil resistance and mechanical strength.
摘要翻译: 公开了一种可固化树脂组合物,其包含(a)100重量份的式(1)的硅氧烷 - 酰胺嵌段共聚物:其中R 1是取代或未取代的二价烃基; R2可以相同或不同,各自为取代或未取代的单价烃基; R3是取代或未取代的二价芳族烃基; m和a各自为1以上的数; (b)1〜100重量份的分子中含有2个以上环氧基的交联剂,(c)最多15重量份的可固化催化剂。 组合物可以在室温下和在封闭体系中不含水分下固化,得到具有高耐油性和机械强度的固化产物。
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公开(公告)号:US07473382B2
公开(公告)日:2009-01-06
申请号:US12082726
申请日:2008-04-14
摘要: A seal molding material for cell electrolytic solution, which comprises an EPDM composition comprising a peroxide-crosslinkable EPDM and an organic peroxide, the seal molding material being for use at the electrode site of a nickel-hydrogen cell, wherein the EPDM composition comprises preferably 100 parts by weight of a peroxide-crosslinkable EPDM, 10 to 150 parts by weight of a filler and 1 to 8 parts by weight of an organic peroxide, and not more than 40 parts by weight of hydrocarbon-based oil can be further contained. The seal material molded from the seal molding material for cell electrolytic solution has a sufficient durability against a potassium hydroxide-based electrolytic solution and a longer life, and is free from any deterioration, when energized at the electrode site of a nickel-hydrogen cell.
摘要翻译: 一种用于电池电解液的密封成型材料,其包含含有可过氧化物交联的EPDM和有机过氧化物的EPDM组合物,所述密封成型材料用于镍氢电池的电极部位,其中所述EPDM组合物优选为100 可以进一步包含过氧化物交联性EPDM,重量份为10〜150重量份的填料和1〜8重量份的有机过氧化物,以及40重量份以下的烃系油。 由电解质电解液密封成型材料成型的密封材料对氢氧化钾类电解液具有足够的耐久性,寿命更长,并且在镍氢电池的电极部位通电时不会发生劣化。
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公开(公告)号:US5883184A
公开(公告)日:1999-03-16
申请号:US650962
申请日:1996-05-21
申请人: Hisayuki Nagaoka
发明人: Hisayuki Nagaoka
摘要: A curable organopolysiloxane composition is disclosed, comprising (A) 100 parts by weight of an organopolysiloxane having at least two monovalent aliphatic unsaturated hydrocarbon groups bonded to the silicon atoms per molecule, (B) an organopolyhydrogensiloxane having at least three hydrogen atoms bonded to the silicon atoms per molecule in such an amount that the number of the hydrogen atoms bonded to the silicon atoms falls within a range of from 0.25 to 8 per monovalent aliphatic unsaturated hydrocarbon group in component (A), (C) a catalyst selected from the group consisting of platinum and platinum compounds in an amount of from 0.1 to 500 ppm in terms of metallic platinum based on the weight of the component (A), and (D) from 1 to 650 parts by weight of an oil-absorbing filler which has been prepared by impregnating (a) a porous filler with from 1% by weight based on the porous filler up to a saturation amount of (b) a volatile organic compound which is incompatible or partly compatible with component (A) and compatible with an organic oily substance. The composition exhibits satisfactory adhesion to a substrate in such adhesion operation as an FIPG system without requiring wiping of organic oily contaminants on the substrate, such as hydrocarbon oils, e.g., a rust preventing oil and an engine oil.
摘要翻译: 公开了一种可固化的有机基聚硅氧烷组合物,其包含(A)100重量份的具有至少两个与每个分子的硅原子键合的一价脂族不饱和烃基的有机聚硅氧烷,(B)具有至少三个氢原子键合到硅上的有机聚氢硅氧烷 每个分子的原子数量使得与硅原子键合的氢原子的数量落在组分(A)中的每一个脂族不饱和烃基的0.25至8的范围内,(C)选自以下的催化剂: 的铂和铂化合物的量为0.1〜500ppm(以成分(A)的重量计)的金属铂,和(D)1〜650重量份的吸油性填料 通过浸渍(a)基于多孔填料的1重量%的多孔填料直到饱和量的(b)不相容或部分共混的挥发性有机化合物 与组分(A)相容并与有机油状物质相容。 组合物在与FIPG系统的粘合操作中对基材表现出令人满意的粘合性,而不需要擦拭基材上的有机油性污染物,例如烃油,例如防锈油和发动机油。
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公开(公告)号:US5807913A
公开(公告)日:1998-09-15
申请号:US760864
申请日:1996-12-05
申请人: Kenji Mikuni , Hisayuki Nagaoka , Norio Tanaka
发明人: Kenji Mikuni , Hisayuki Nagaoka , Norio Tanaka
CPC分类号: C09K3/10 , C08K5/5317 , C09K2200/0417 , C09K2200/0488 , C09K2200/0625
摘要: An active halogen-containing acrylic rubber composition for molding oil filter-gaskets, which comprises an active halogen-containing acrylic rubber and a metal phosphonate represented by the following general formula: RR'nPO(OH)(OM) wherein R is an alkyl group having 1 to 32 carbon atoms, a polyfluorocarbon group or a perfluoropolyether group; R' is an alkylene group having 1 to 6 carbon atoms, a phenylene group, an oxyphenylene group or a sulfonamide group; M is an alkali metal; and n is 0 or 1, gives oil filter-gaskets having a distinguished durable protection against fixation without lowering of high temperature sealability, even if used in engine oil.
摘要翻译: 一种用于成型油过滤垫片的活性含卤素丙烯酸橡胶组合物,其包含由以下通式表示的含活性卤素的丙烯酸橡胶和金属膦酸盐:RR'nPO(OH)(OM)其中R是烷基 具有1至32个碳原子,多氟碳基团或全氟聚醚基团; R'是具有1至6个碳原子的亚烷基,亚苯基,氧亚苯基或磺酰胺基; M是碱金属; 并且n为0或1,即使在发动机机油中使用,也能得到具有突出的耐久性保护的油过滤垫圈,而不降低高温密封性。
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公开(公告)号:US5004793A
公开(公告)日:1991-04-02
申请号:US374796
申请日:1989-07-03
IPC分类号: C08L83/10 , C08G77/42 , C08G77/455 , C08K5/54 , C08L83/04
CPC分类号: C08K5/54 , C08G77/455 , Y10S528/901
摘要: A room temperature-curable composition comprising(a) 100 parts by weight of a siloxane-amide block copolymer represented by the formula (1) ##STR1## wherein Y represents a hydrolyzable group-containing organosilyl group of the formula --SiR.sup.5.sub.a X.sub.a-ain whichR.sup.5 represents a substituted or unsubstituted monovalent hydrocarbon group,a is an integer of 0, 1 or 2, andX is directly bonded to the silicon atom and represents a hydolyzable group or a hydroxyl group,R.sup.1 represents a divalent group selected from the group consisting of ##STR2## in which R.sup.6 represents a hydrogen atom, a substituted or unsubstituted monovalent hydrocarbon group, or an organosilyl group of the formula --SiR.sup.8.sub.b X.sub.3-bin whichR.sup.8 represents a substituted or unsubstituted monovalent hydrocarbon group,b is an integer of 0, 1, 2, or 3, and X is the same as defined above, andR.sup.7 represents a substituted or unsubstituted divalent hydrocarbon group which has 1 to 8 carbon atoms and may contain an ether bond including an oxygen or sulfur atom,R.sup.2 represents a substituted or unsubstituted divalent hydrocarbon group,R.sup.3 represents a substituted or unsubstituted monovalent hydrocarbon group,R.sup.4 represents a substituted or unsubstituted divalent aromatic hydrocarbon group, andm and n each independently is a number of 1 or more;(b) 0 to 25 parts by weight of a crosslinking agent; and(c) 0.01 to 3 parts by weight of a curing catalyst.
摘要翻译: 一种室温可固化组合物,其包含(a)100重量份由式(1)表示的硅氧烷 - 酰胺嵌段共聚物,其中Y表示可水解基团的有机甲硅烷基 式-SiR5aXa-a,其中R5表示取代或未取代的单价烃基,a为0,1或2的整数,X直接键合到硅原子上,表示可水解的基团或羟基,R1表示 选自由下列组成的组的二价基团:其中R 6表示氢原子,取代或未取代的单价烃基或式-SiR8bX3-b的有机甲硅烷基,其中R8表示取代或未取代的单价烃基 b为0,1,2或3的整数,X与上述定义相同,R 7为取代或未取代的碳原子数为1〜8的二价烃基,可以含有醚键 丁氧基或硫原子,R2表示取代或未取代的二价烃基,R3表示取代或未取代的单价烃基,R4表示取代或未取代的二价芳族烃基,m和n各自独立地为1或 更多; (b)0〜25重量份的交联剂; 和(c)0.01〜3重量份的固化催化剂。
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公开(公告)号:US5641832A
公开(公告)日:1997-06-24
申请号:US585434
申请日:1996-01-11
申请人: Hisayuki Nagaoka
发明人: Hisayuki Nagaoka
CPC分类号: C08K9/04
摘要: A room temperature-curable organopolysiloxane composition is disclosed, comprising (A) 100 parts by weight of an organopolysiloxane terminated with a silanol group or an alkoxy group, (B) from 0.1 to 30 parts by weight of an organosilicon compound containing more than 2, in average, of hydrolyzable groups bonded to the silicon atom per molecule, (C) from 1 to 650 parts by weight of an oil-absorbing filler which has been prepared by impregnating (a) a porous filler with (b) a volatile organic compound which is incompatible or partly compatible to component (A) and compatible with an organic oily substance in an amount of from 1% by weight based on the weight of the porous filler up to a saturation amount and, if desired, (D) a requisite amount of a curing catalyst. The composition exhibits satisfactory adhesion to a substrate in such adhesion operation as an FIPG system without requiring wiping of organic oily contaminants on the substrate, such as hydrocarbon oils, e.g., a rust preventing oil and an engine oil.
摘要翻译: 公开了一种室温可固化的有机基聚硅氧烷组合物,其包含(A)100重量份用硅烷醇基或烷氧基封端的有机聚硅氧烷,(B)0.1至30重量份的含有大于2的有机硅化合物, 平均来说,每分子与硅原子键合的可水解基团,(C)1〜650重量份的吸油性填料,其通过用(b)挥发性有机化合物浸渍(a)多孔填料而制备 其与组分(A)不相容或部分相容,并且相对于有机油性物质,其量为基于多孔填料的重量的1重量%,直至饱和量,并且如果需要,(D)必需的 固化催化剂的量。 组合物在与FIPG系统的粘合操作中对基材表现出令人满意的粘合性,而不需要擦拭基材上的有机油性污染物,例如烃油,例如防锈油和发动机油。
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公开(公告)号:US5378406A
公开(公告)日:1995-01-03
申请号:US89552
申请日:1993-07-12
申请人: Hisayuki Nagaoka
发明人: Hisayuki Nagaoka
IPC分类号: A01N47/18 , C08K5/00 , C08K5/34 , C08K5/3432 , C08K5/3447 , C08L83/04 , C09K3/10 , C08L83/05 , H01B1/12
CPC分类号: C08K5/3432 , C08K5/0058 , C08K5/3447
摘要: A fungiresistant polyorganosiloxane composition comprising(A) 100 parts by weight of a polyorganosiloxane having a viscosity at 25.degree. C. of from 100 to 500,000 cSt, each of both the terminals of which being blocked with a silanol group or an alkoxy group,(B) from 0.1 to 20 parts by weight of an organisilicon compound having on the average more than 2 hydrolyzable groups each bonded to a silicon atom in the molecule,(C) from 0.001 to 25 parts by weight of a benzimidazolylcarbamate compound represented by the formula ##STR1## wherein R.sup.1 represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitro group; R.sup.2 represents an alkyl group having from 1 to 4 carbon atoms or an alkoxyalkyl group having from 2 to 4 carbon atoms: and R.sup.3 represents a hydrogen atom, an N-substituted or unsubstituted carbamoyl group or an N-substituted or unsubstituted carbamoyloxy group, and(D) from 0.001 to 25 parts by weight of bis(2-pyridylthio-1-oxide) zinc salt shown by the formula ##STR2##
摘要翻译: 一种真菌聚有机硅氧烷组合物,其包含(A)100重量份在25℃下的粘度为100至500,000cSt的聚有机硅氧烷,其两个末端都被硅烷醇基或烷氧基封闭,(B )0.1〜20重量份具有平均多于2个可水解基团的有机硅化合物,每个可分解基团与分子中的硅原子键合,(C)0.001至25重量份的由下式表示的苯并咪唑基氨基甲酸酯化合物: IMAGE>其中R1表示氢原子,具有1至4个碳原子的烷基,卤原子或硝基; R2表示碳原子数1〜4的烷基或碳原子数2〜4的烷氧基烷基,R3表示氢原子,N-取代或未取代的氨基甲酰基或N-取代或未取代的氨基甲酰氧基, (D)0.001至25重量份由式[IMAGE]所示的双(2-吡啶硫基-1-氧化物)锌盐,
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