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公开(公告)号：US07354645B2
公开(公告)日：2008-04-08
申请号：US10746784
申请日：2003-12-26
IPC分类号： B32B15/00
CPC分类号： H01B3/08 , C03B37/026 , H01B1/02 , Y10T428/2933 , Y10T428/294 , Y10T428/2949 , Y10T428/2958
摘要： A metallic glass-coated wire is formed by drawing a hollow glass fiber from a container in which molten alloy is entrained and solidified. Interference stresses extant between the glass coating and the alloy core of the wire are produced by systematically controlling thickness and mechanical elastic properties of the glass. The interference stress is tailored by selection of glass thickness and chemistry to optimize wire drawing process conditions, such as drawing temperature and strain rate. In addition, the interference stress is especially tailored to assure physical integrity of the glass-alloy composite wire product. Local property variations along the wire length are minimized, facilitating production of discrete wire segments especially suited for use in EAS applications.
摘要翻译： 通过从其中夹带和固化熔融合金的容器中拉出中空玻璃纤维来形成金属玻璃涂层线。 通过系统地控制玻璃的厚度和机械弹性，产生玻璃涂层和金属丝的合金芯之间的干涉应力。 干涉应力是通过选择玻璃的厚度和化学成分来优化拉丝工艺条件，如拉伸温度和应变速率。 此外，干涉应力特别适合于确保玻璃 - 合金复合丝产品的物理完整性。 沿线长度的局部性质变化最小化，便于生产特别适用于EAS应用的分立线段。
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公开(公告)号：US07233249B2
公开(公告)日：2007-06-19
申请号：US10935258
申请日：2004-09-07
申请人： Howard H. Liebermann , William C. LaCourse , Alexis G. Clare , Wesley A. King , James E. O'Keefe, Jr.
发明人： Howard H. Liebermann , William C. LaCourse , Alexis G. Clare , Wesley A. King , James E. O'Keefe, Jr.
IPC分类号： G08B13/14
CPC分类号： G06K19/06018 , G06K19/06046 , G06K19/06187 , G06K19/06196 , Y10T428/12465 , Y10T428/2935 , Y10T428/2938 , Y10T428/2949
摘要： A glass-coated amorphous metallic microwire is encoded with multi-bit digital information. Encoding is achieved magnetically, optically or through a combination of magnetic and optical encoding processes. Magnetic encoding is carried out by modifying the constituent magnetic domain structure through selective relief of interfacial stress between the glass coating and the amorphous metallic alloy core. It is also achieved by selective surface crystallization of the amorphous metallic core in order to produce a controlled magnetic bias field. Optical encoding is associated with the glass coating. It is readily achieved by fluorescent element deposition, patterned removal of fluorescent element coating, Bragg grating, and thermally activated pattern deposition. The magnetic and optical multi-bit encoding approaches for glass-coated amorphous metallic microwire can be used individually or collectively in either a redundant or a complementary manner. Encoded microwire of the instant invention can be assembled into tags for electronic article surveillance and into numerous other structures as well.
摘要翻译： 用多位数字信息编码玻璃涂层的非晶态金属微丝。 编码是通过磁学，光学或通过磁和光编码过程的组合实现的。 通过选择性地避免玻璃涂层和非晶金属合金芯之间的界面应力来改变构成磁畴结构来进行磁编码。 也可以通过非晶金属芯的选择性表面结晶来实现，以产生受控的磁偏置场。 光学编码与玻璃涂层有关。 通过荧光元件沉积，荧光元件涂层的图案化去除，布拉格光栅和热激活图案沉积容易实现。 用于玻璃涂覆的非晶金属微丝的磁和光多位编码方法可以单独使用或以多余或互补的方式共同使用。 本发明的编码微线可以组装成用于电子物品监视的标签以及许多其它结构。
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公开(公告)号：US5873954A
公开(公告)日：1999-02-23
申请号：US796011
申请日：1997-02-05
CPC分类号： H01F1/153 , C21D1/04 , H01F41/0226 , C21D6/008 , C21D8/12
摘要： A ferromagnetic amorphous metallic alloy strip is annealed to minimize exciting power rather than core loss. The strip has an exciting power less than 0.5 VA/kg when measured at 60 Hz and an operating induction of 1.40 to 1.45 Tesla, the measurement being carried out at ambient temperature. Cores composed of the strip can be run at higher operating induction than those annealed to minimize core loss. The physical size of the transformer's magnetic components, including the core, is significantly reduced.
摘要翻译： 将铁磁性非晶金属合金带退火以使激发功率最小化而不是铁芯损耗。 当在60Hz测量时，该条具有小于0.5VA / kg的激励功率，并且操作感应为1.40至1.45特斯拉，测量在环境温度下进行。 由钢带组成的铁心可以比较高的工作感应运行，而不是退火的铁心，以减少铁心的损耗。 包括核心在内的变压器磁性部件的物理尺寸大大减少。
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公开(公告)号：US5019336A
公开(公告)日：1991-05-28
申请号：US464608
申请日：1990-01-11
CPC分类号： B23K35/262 , C22C13/00
摘要： Tin-based alloys that include micro-additions of certain elements avoid the discoloration that otherwise afflict those alloys when they are melted. The discoloration, which results from tin oxidation, correlates with poor performance of the alloys in filler metal applications. A preferred method of preparing the alloys of the invention is by rapid solidification from the melt.
摘要翻译： 包含某些元素的微量添加剂的锡基合金避免了变色，否则会在熔化时损害这些合金。 由锡氧化引起的变色与填料金属应用中的合金性能差。 制备本发明合金的优选方法是通过熔体快速凝固。
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公开(公告)号：US4791979A
公开(公告)日：1988-12-20
申请号：US166738
申请日：1988-03-02
申请人： Howard H. Liebermann
发明人： Howard H. Liebermann
IPC分类号： B22D11/06
CPC分类号： B22D11/0697
摘要： A method and apparatus for casting rapidly solidified metallic strip includes a nozzle mechanism which has an orifice for directing a stream of molten metal onto a movable quench surface. An upstream constraint mechanism constrains an upstream portion of a melt puddle formed on the quench surface by molten metal from the molten metal stream. A side constraint mechanism constrains two, opposite side portions of the melt puddle, and a downstream constraint mechanism provides a selected gas pressure, constraining force against a downstream, top surface of the melt puddled.
摘要翻译： 用于铸造快速凝固的金属带的方法和设备包括喷嘴机构，其具有用于将熔融金属流引导到可移动淬火表面上的孔口。 上游约束机构通过来自熔融金属流的熔融金属约束在骤冷表面上形成的熔融熔池的上游部分。 侧面约束机构约束熔融水坑的两个相对的侧部，并且下游约束机构提供选定的气体压力，约束熔化物熔化的下游顶部表面的约束力。
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公开(公告)号：US07368166B2
公开(公告)日：2008-05-06
申请号：US11098052
申请日：2005-04-04
CPC分类号： B01L7/52 , A61B2017/008 , B01L3/502707 , B01L3/502715 , B01L3/50851 , B01L3/561 , B01L2200/12 , B01L2200/16 , B01L2300/0838 , B01L2300/0845 , B01L2300/16 , B01L2300/1827 , C12Q1/686 , Y10T428/2933 , Y10T428/294 , Y10T428/2958
摘要： A metallic glass-coated microwire has controllable surface porosity. The porosity is achieved by etching the metallic glass-coated microwire or other shapes of glass-coated bodies with acid after annealing to produce a multi-phase glass coating. Porous metallic glass-coated microwires are found to make superior PCR machines, which find use in a variety of in vivo, biochemical, and chemical sensors. Advantageously, the PCR apparatus is smaller, less expensive to construct than conventional units. It readily carries out in vivo passive or active operations.
摘要翻译： 金属玻璃涂层微丝具有可控的表面孔隙度。 通过在退火之后用酸蚀刻金属玻璃包覆的微丝或其它形状的玻璃涂覆体以产生多相玻璃涂层来实现孔隙率。 发现多孔金属玻璃涂层微丝可以制造出优异的PCR机器，可用于各种体内，生物化学和化学传感器。 有利地，PCR装置比常规单元更小，更便宜。 它容易进行体内被动或主动操作。
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公开(公告)号：US5043029A
公开(公告)日：1991-08-27
申请号：US627871
申请日：1990-12-13
IPC分类号： B22D11/06
CPC分类号： B22D11/0611 , B22D11/0697
摘要： An apparatus and method for casting metal strip include a moving chill body that has a quench surface. A nozzle mechanism deposits a stream of molten metal on a quenching region of the quench surface to form the strip. The nozzle mechanism has an exit portion with a nozzle orifice. A depletion mechanism supplies a reducing gas to a depletion region located adjacent to and upstream from the quenching region. The reducing gas reacts exothermically to lower the density provide a low density reducing atmosphere within the depletion and substantially prevent formation of gas pockets in the strip.
摘要翻译： 用于铸造金属带的装置和方法包括具有淬火表面的移动冷却体。 喷嘴机构将熔融金属流沉积在淬火表面的淬火区域上以形成条带。 喷嘴机构具有带有喷嘴孔口的出口部分。 耗尽机构将还原气体提供给位于淬火区域附近和上游的耗尽区域。 还原气体放热反应以降低密度，从而在耗尽期间提供低密度的还原气氛，并且基本上防止在带中形成气穴。
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公开(公告)号：US4869312A
公开(公告)日：1989-09-26
申请号：US898826
申请日：1986-08-20
IPC分类号： B22D11/06
CPC分类号： B22D11/0611 , B22D11/0697
摘要： An apparatus and method for casting metal strip includes a moving chill body that has a quench surface. A nozzle mechanism deposits a stream of molten metal on a quenching region of the quench surface to form the strip. The nozzle mechanism has an exit portion with a nozzle orifice. A depletion mechanism supplies a reducing gas to a depletion region located adjacent to and upstream from the quenching region. The reducing gas reacts exothermically to lower the density to provide a low density reducing atmosphere within the depletion and substantially prevent formation of gas pockets in the strip.
摘要翻译： 用于铸造金属带的装置和方法包括具有淬火表面的移动冷却体。 喷嘴机构将熔融金属流沉积在淬火表面的淬火区域上以形成条带。 喷嘴机构具有带有喷嘴孔口的出口部分。 耗尽机构将还原气体提供给位于淬火区域附近和上游的耗尽区域。 还原气体放热反应以降低密度，以在耗尽之内提供低密度的还原气氛，并且基本上防止条带中的气穴的形成。
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公开(公告)号：US4734256A
公开(公告)日：1988-03-29
申请号：US854455
申请日：1986-04-21
申请人： Howard H. Liebermann , Debasis Bose
发明人： Howard H. Liebermann , Debasis Bose
CPC分类号： C22C11/00 , B23K35/268 , C22C11/06 , Y10T428/12431
摘要： A lead based alloy is modified by adding thereto a surfactant consisting of about 0.01 to 0.5 weight percent tellurium, about 0.01 to 0.5 weight percent selenium, about 0.01 to 0.5 weight percent selenium plus about 0.1-0.5 weight percent antimony, and mixtures thereof. The alloy is rapidly solidified by forming a melt thereof containing the surfactant addition and quenching the melt on a moving chill surface at a quenching rate of at least about 10.sup.3 .degree. C./sec. Addition of the surfactant lowers melt surface tension and thereby promotes improved wetting.
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公开(公告)号：US4676298A
公开(公告)日：1987-06-30
申请号：US781207
申请日：1985-09-30
申请人： Howard H. Liebermann
发明人： Howard H. Liebermann
CPC分类号： B22D11/005 , B22D11/06
摘要： An apparatus and method for casting metal strip include a moving chill body that has a quench surface. A nozzle mechanism deposits a stream of molten metal on a quenching region of the quench surface to form the strip. The nozzle mechanism has an exit portion with a nozzle orifice. A depletion mechanism supplies a low density atmosphere to a depletion region located adjacent to and upstream of the quenching region. The quench surface is heated to a temperature that substantially prevents precipitation of condensed or solidified constituents from the low density atmosphere onto the depletion region.
摘要翻译： 用于铸造金属带的装置和方法包括具有淬火表面的移动冷却体。 喷嘴机构将熔融金属流沉积在淬火表面的淬火区域上以形成条带。 喷嘴机构具有带有喷嘴孔口的出口部分。 耗尽机构将低密度气氛提供给位于淬火区域附近和上游的耗尽区域。 淬火表面被加热到基本上防止冷凝或固化的组分从低密度气氛沉淀到耗尽区上的温度。
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