Catalyst for preparing carbon nanotubes by controlling its apparent density
    1.
    发明授权
    Catalyst for preparing carbon nanotubes by controlling its apparent density 有权
    通过控制其表观密度来制备碳纳米管的催化剂

    公开(公告)号:US08398894B2

    公开(公告)日:2013-03-19

    申请号:US12642084

    申请日:2009-12-18

    IPC分类号: H01B1/00

    摘要: The present invention relates to a catalyst for preparing a carbon nanotube having desired apparent density by controlling the adding amount of co-precipitating agent in the process of preparing a catalyst in order to obtain a catalyst having a minimized particle size. More specifically, this invention relates to a catalyst for preparing carbon nanotube having desired apparent density based upon the reverse-correlation between the amount of co-precipitating agent added in the process of preparing catalyst and the apparent density of catalyst. The carbon nanotube prepared by the catalyst having low apparent density shows excellent electrical conductivity and highly uniformed dispersion in the polymer/carbon nanotube composite.

    摘要翻译: 本发明涉及通过在制备催化剂的过程中控制共沉淀剂的添加量以获得具有最小粒度的催化剂来制备具有所需表观密度的碳纳米管的催化剂。 更具体地,本发明涉及一种制备具有所需表观密度的碳纳米管的催化剂,其基于在制备催化剂的方法中加入的共沉淀剂的量与催化剂的表观密度之间的反相关性。 通过具有低表观密度的催化剂制备的碳纳米管在聚合物/碳纳米管复合材料中显示出优异的导电性和高度均匀的分散体。

    CATALYST FOR PREPARING CARBON NANOTUBES BY CONTROLLING ITS APPARENT DENSITY
    2.
    发明申请
    CATALYST FOR PREPARING CARBON NANOTUBES BY CONTROLLING ITS APPARENT DENSITY 有权
    通过控制其密度来制备碳纳米管的催化剂

    公开(公告)号:US20110006266A1

    公开(公告)日:2011-01-13

    申请号:US12642084

    申请日:2009-12-18

    IPC分类号: H01B1/12 B01J23/78 D01F9/12

    摘要: The present invention relates to a catalyst for preparing a carbon nanotube having desired apparent density by controlling the adding amount of co-precipitating agent in the process of preparing a catalyst in order to obtain a catalyst having a minimized particle size. More specifically, this invention relates to a catalyst for preparing carbon nanotube having desired apparent density based upon the reverse-correlation between the amount of co-precipitating agent added in the process of preparing catalyst and the apparent density of catalyst. The carbon nanotube prepared by the catalyst having low apparent density shows excellent electrical conductivity and highly uniformed dispersion in the polymer/carbon nanotube composite.

    摘要翻译: 本发明涉及通过在制备催化剂的过程中控制共沉淀剂的添加量以获得具有最小粒度的催化剂来制备具有所需表观密度的碳纳米管的催化剂。 更具体地,本发明涉及一种制备具有所需表观密度的碳纳米管的催化剂,其基于在制备催化剂的方法中加入的共沉淀剂的量与催化剂的表观密度之间的反相关性。 通过具有低表观密度的催化剂制备的碳纳米管在聚合物/碳纳米管复合材料中显示出优异的导电性和高度均匀的分散体。

    Method for preparing a homo-and co-polymers by polymerization of cyclic olefin compounds using fluorine-containing aromatic hydrocarbon compound as catalyst activator
    4.
    发明授权
    Method for preparing a homo-and co-polymers by polymerization of cyclic olefin compounds using fluorine-containing aromatic hydrocarbon compound as catalyst activator 失效
    通过使用含氟芳烃化合物作为催化剂活化剂的环烯烃化合物聚合制备均聚物和共聚物的方法

    公开(公告)号:US06998450B1

    公开(公告)日:2006-02-14

    申请号:US11032821

    申请日:2005-01-11

    IPC分类号: C08F4/80 C08F32/04

    摘要: The present invention provides a method for preparing homo- and co-polymers by polymerizing cyclic olefin compounds using addition polymerization. The method can produce a cyclic olefin polymer having a high molecular weight with a high yield in the presence of, as an addition polymerization catalyst, a complex prepared by mixing a nickel salt compound and an organoaluminoxane compound with at least one fluorine-containing aromatic hydrocarbon compound represented by the following formula 1 or 2 as a catalyst activator: C6RmH6-mFormula 1 where R is CF3; and m is from 1 to 3, or C6FnH6-nFormula 2 where n is from 1 to 6.

    摘要翻译: 本发明提供了使用加成聚合使环烯烃化合物聚合制备均聚物和共聚物的方法。 该方法可以在作为加成聚合催化剂存在下,通过将镍盐化合物和有机铝氧烷化合物与至少一种含氟芳族烃混合而制备的配合物来制备具有高分子量的环状烯烃聚合物, 由下式1或2表示的化合物作为催化活性物质

    Method for grouping unit cells using pattern matching technology of impedance spectrum
    5.
    发明授权
    Method for grouping unit cells using pattern matching technology of impedance spectrum 失效
    使用阻抗谱图案匹配技术对单位单元进行分组的方法

    公开(公告)号:US06674287B2

    公开(公告)日:2004-01-06

    申请号:US10208608

    申请日:2002-07-30

    IPC分类号: G01N27416

    CPC分类号: H01M10/482

    摘要: A method for grouping unit cells of a similar impedance spectrum uses pattern matching technology to optimize the performance of a battery pack made of primary or secondary batteries as the unit cells connected in series, in parallel or in combination of them. To make an optimal battery pack with unit cells of a different internal characteristic, the method includes measuring the impedance spectrum of the individual unit cell in a wide frequency region at the same temperature and in the same state of charge (SOC), digitizing the difference in impedance spectrum among the unit cells into a relative value using the pattern matching technology, and selecting unit cells of a most similar impedance spectrum (i.e., a smallest relative difference in impedance spectrum) to make a battery pack.

    摘要翻译: 用于对类似阻抗谱的单位单元进行分组的方法使用模式匹配技术来优化由主单元或二次电池组成的电池组的性能,所述单电池串联,并联或组合连接。 为了制造具有不同内部特性的单位电池的最佳电池组,该方法包括在相同温度和相同充电状态(SOC)的宽频率区域中测量各单元电池的阻抗谱,数字化差分 使用模式匹配技术将单位单元之间的阻抗谱转换成相对值,并选择最相似阻抗谱的单位单元(即,阻抗谱中的最小相对差),以制作电池组。

    High capacity composite electrode and secondary cell therefrom
    6.
    发明授权
    High capacity composite electrode and secondary cell therefrom 失效
    高容量复合电极和二次电池

    公开(公告)号:US6090504A

    公开(公告)日:2000-07-18

    申请号:US149432

    申请日:1998-09-08

    IPC分类号: H01M4/60

    摘要: The present invention relates to an improved secondary battery having high weight energy density and good reversibility, more specifically, a battery containing i) a positive electrode comprising a reversible positive electrode material containing an organosulfur compound wherein sulfur-sulfur bond is formed upon oxidation and sulfur-sulfur bond is cleaved upon electrolytic reduction, an electroactive component selected from main group elements compound, electrically conductive ingredients and a current collector containing copper metal; ii) a polymer electrolyte having lithium salt; and iii) a negative electrode made of lithium metal, lithium alloy or lithium intercalating carbon.

    摘要翻译: 本发明涉及具有高重量能量密度和良好可逆性的改进的二次电池,更具体地说,涉及一种电池,其包含i)正极,其包含含有有机硫化合物的可逆正极材料,其中在硫氧化时形成硫 - 硫键 硫键在电解还原时被切割,选自主要元素化合物,导电成分和含铜金属的集电体的电活性成分; ii)具有锂盐的聚合物电解质; 和iii)由锂金属,锂合金或嵌入碳的锂制成的负极。

    Method of preparing cyclic olefin copolymer having controlled gel contents
    8.
    发明授权
    Method of preparing cyclic olefin copolymer having controlled gel contents 失效
    制备具有受控凝胶含量的环烯烃共聚物的方法

    公开(公告)号:US07468417B2

    公开(公告)日:2008-12-23

    申请号:US11467100

    申请日:2006-08-24

    IPC分类号: C08G61/08 C08F2/38 C08F4/78

    CPC分类号: C08G61/08

    摘要: The present invention relates to a method of preparing a copolymer having controlled gel content by polymerizing cyclic olefin compound by ROMP (Ring Opening Metathesis Polymerization), and more precisely, a method of preparing cyclic olefin copolymer with high yield, in which a complex prepared by mixing a W salt compound and an organoaluminum halide compound is used as a catalyst in the presence or absence of a molecular weight regulator, and a method of controlling gel formation by regulating the composition of cyclic olefin monomer composing a copolymer as shown in the following Empirical Formula 1 without using a reaction speed regulator or gel formation inhibitor. (Empirical Formula 1) Norbornene=30˜70 weight % Cyclic olefin compound=70˜30 weight % At this time, the cyclic olefin compound presented in the above Empirical Formula 1 is one or more compounds selected from a group consisting of dicyclopentadiene and compounds represented by the following Formula 1. Wherein, m is an integer of 0-1, R1 is C1-C5 alkyl and R2 is H or C1-C10 alkyl.

    摘要翻译: 本发明涉及通过ROMP(开环复分解聚合)聚合环烯烃化合物制备具有控制凝胶含量的共聚物的方法,更确切地说,一种以高产率制备环烯烃共聚物的方法,其中将由 在存在或不存在分子量调节剂的情况下,将W盐化合物和有机铝卤化物混合物用作催化剂,以及通过调节构成共聚物的环烯烃单体的组成来控制凝胶形成的方法,如以下实验 式1不使用反应速度调节剂或凝胶形成抑制剂。 (实验式1)降冰片烯= 30〜70重量%环状烯烃化合物= 70〜30重量%此时,上述实验式1中所示的环状烯烃化合物是选自二环戊二烯和化合物 其中m为0-1的整数,R1为C1-C5烷基,R2为H或C1-C10烷基。

    METHOD OF PREPARING CYCLIC OLEFIN COPOLYMER HAVING CONTROLLED GEL CONTENTS
    9.
    发明申请
    METHOD OF PREPARING CYCLIC OLEFIN COPOLYMER HAVING CONTROLLED GEL CONTENTS 失效
    制备具有控制凝胶含量的环状烯烃共聚物的方法

    公开(公告)号:US20070060730A1

    公开(公告)日:2007-03-15

    申请号:US11467100

    申请日:2006-08-24

    IPC分类号: C08F136/00

    CPC分类号: C08G61/08

    摘要: The present invention relates to a method of preparing a copolymer having controlled gel content by polymerizing cyclic olefin compound by ROMP (Ring Opening Metathesis Polymerization) and more precisely, a method of preparing cyclic olefin copolymer with high yield, in which a complex prepared by mixing a W salt compound and an organoaluminum halide compound is used as a catalyst in the presence or absence of a molecular weight regulator, and a method of controlling gel formation by regulating the composition of cyclic olefin monomer composing a copolymer as shown in the following Empirical Formula 1 without using a reaction speed regulator or gel formation inhibitor. (Empirical Formula 1) Norbornene=30˜70 weight % Cyclic olefin compound=70˜30 weight % At this time, the cyclic olefin compound presented in the above Empirical Formula 1 is one or more compounds selected from a group consisting of dicyclopentadiene and compounds represented by the following Formula 1. Wherein, m is an integer of 0−1, R1 is C1-C5 alkyl and R2 is H or C1-C10 alkyl.

    摘要翻译: 本发明涉及通过ROMP(开环复分解聚合)聚合环烯烃化合物制备具有控制凝胶含量的共聚物的方法,更准确地说,一种以高产率制备环烯烃共聚物的方法,其中通过混合 在存在或不存在分子量调节剂的情况下,使用W盐化合物和有机铝卤化物作为催化剂,以及通过调节构成共聚物的环烯烃单体的组成来控制凝胶形成的方法,如以下经验式 1,而不使用反应速度调节剂或凝胶形成抑制剂。 (实验式1)降冰片烯= 30〜70重量%环状烯烃化合物= 70〜30重量%此时,上述实验式1中所示的环状烯烃化合物是选自二环戊二烯和化合物 其中m为0-1的整数,R 1为C 1 -C 5烷基,R 1为C 1 -C 5烷基,R H 2是H或C 1 -C 10烷基。

    Cathode including transition metal/matrix polymer composition and a secondary polymer battery therefrom
    10.
    发明授权
    Cathode including transition metal/matrix polymer composition and a secondary polymer battery therefrom 失效
    阴极包括过渡金属/基质聚合物组合物和二次聚合物电池

    公开(公告)号:US06620547B1

    公开(公告)日:2003-09-16

    申请号:US09390635

    申请日:1999-09-07

    IPC分类号: H01M460

    摘要: A secondary polymer battery is provided with: a) a cathode containing a current collector made of an electrically conductive substrate and a composition placed on said current collector, said composition including i) one or more transition metal compounds selected among a transition metal and transition metal salt of the formula MXn, wherein M is a transition metal, X is a halogen negative ion, and n is an integral number between 1 to 6; ii) a matrix polymer which has a basic functional group with affinity for the transition metal species; (b) a polymer electrolyte containing a lithium salt; and (c) an anode including the material selected among a lithium metal, a lithium alloy and a lithium intercalation material such as carbon. The secondary polymer battery has a high energy density and a high charging/discharging efficiency with extended cycle life.

    摘要翻译: 二次聚合物电池设置有:a)包含由导电基板制成的集电器和放置在所述集电器上的组合物的阴极,所述组合物包括i)一种或多种选自过渡金属和过渡金属中的过渡金属化合物 式MXn的盐,其中M是过渡金属,X是卤素负离子,n是1至6之间的整数; ii)具有对过渡金属物质具有亲和力的碱性官能团的基质聚合物;(b)含有锂盐的聚合物电解质; 和(c)包括选自锂金属,锂合金和锂嵌入材料如碳的材料的阳极。 二次聚合物电池具有高能量密度和高充电/放电效率,延长了循环寿命。