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公开(公告)号：US4584175A
公开(公告)日：1986-04-22
申请号：US609636
申请日：1984-05-14
申请人： Irvin W. Martenson
发明人： Irvin W. Martenson
IPC分类号： C08K5/17 , C08K5/3445 , C08K5/42 , C23F11/02 , C23F11/00
CPC分类号： C23F11/02 , C08K5/17 , C08K5/3445 , C08K5/42
摘要： There is disclosed a method for the inhibiting of corrosion of a variety of metals by placing the metal in the presence of a plastic sheet carrier having incorporated therein effective amounts of corrosion inhibitors which include; (a) certain hydroxyalkyl fatty amines, and (b) certain fatty imidazolinium quaternary compounds. The aforementioned compounds provide remarkable corrosion protection for ferrous metals. There can be also included in the plastic certain benzotriazoles or tolyltriazoles when it is desired to extend the protection to copper and copper base alloys, and to aluminum and aluminum base alloys. When protection is also desired for magnesium and magnesium alloys with other metals such as aluminum, there can also be included in the plastic sheet carrier an organic phosphate adduct with diethyl amine. In the preferred embodiment, the metal objects to be protected are sealed in an envelope formed of the plastic sheet material. In this application, extended shelf life and continued effectiveness of the corrosion inhibition can be achieved by also including in the plastic film a non-fugitive organic anti-oxidant, such as an aromatic phenol with sterically hindered hydroxyl groups.The composition of the invention comprises a stable gel in which the aforementioned plastic additives are dissolved and/or suspended which can be used as a liquid carrier to dispense the aforementioned compounds into the plastic sheet or film during its formation. For this purpose, the aforementioned hydroxyalkyl fatty amines can be gelled, neat or dissolved with a plasticizer for the plastic, by the addition thereto of certain expanding lattice organophyillic clays.
摘要翻译： 公开了通过将金属放置在其中并入有有效量的腐蚀抑制剂的塑料片载体的存在下来抑制各种金属的腐蚀的方法，所述腐蚀抑制剂包括： （a）某些羟烷基脂肪胺，和（b）某些脂肪咪唑啉季化合物。 上述化合物为黑色金属提供了显着的防腐蚀保护。 当需要将保护剂延伸到铜和铜基合金以及铝和铝基合金时，也可以包括在塑料中的某些苯并三唑或甲苯基三唑中。 当与其它金属如铝合金的镁和镁合金也需要保护时，也可以在塑料片载体中包含与二乙胺的有机磷酸盐加合物。 在优选实施例中，待保护的金属物体被密封在由塑料片材料形成的封套中。 在这种应用中，通过在塑料膜中还包括非瞬散有机抗氧化剂，例如具有空间位阻羟基的芳族苯酚，可以实现延长保存期限和持续的腐蚀抑制作用。 本发明的组合物包含稳定的凝胶，其中上述塑料添加剂溶解和/或悬浮，其可以用作液体载体，以在其形成期间将上述化合物分配到塑料片或膜中。 为此目的，上述羟烷基脂肪胺可通过添加某些膨胀的晶格有机微生物粘土而与塑料的增塑剂胶凝，整齐或溶解。
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公开(公告)号：US4448916A
公开(公告)日：1984-05-15
申请号：US217175
申请日：1980-12-16
申请人： Irvin W. Martenson
发明人： Irvin W. Martenson
IPC分类号： C08K5/17 , C08K5/3445 , C08K5/42 , C08K5/20 , D06M13/46
CPC分类号： C08K5/42 , C08K5/17 , C08K5/3445 , Y10S260/20 , Y10S524/913
摘要： There is disclosed a liquid gel composition useful for incorporation in thermoplastic and thermosetting resins. The liquid gel comprises a liquid mixture of certain hydroxyalkyl fatty amines or fatty imidazolium quaternaries which is gelled by an organophilic, expanding lattice clay that is ion exchanged with alkyl ammonium ions. The clay is employed at a sufficient concentration to form a stable gel and is milled into the liquid vehicle to form a gel of a suitable viscosity to permit it to be added to the resin with metering injection equipment. The composition when used at low concentrations in resins enhances the physical properties of the resins by imparting a permanent anti-static characteristic to the resins and by significantly decreasing their brittleness, thereby increasing elongation, impact and tensile strengths of the resins. Solid, subdivided colorants can also be blended into the liquid gel composition at a concentration from 10 to about 70 weight percent of the resultant mixture, thereby providing a liquid colorant composition to color the resins and improve their physical properties with a single composition.
摘要翻译： 公开了可用于掺入热塑性和热固性树脂中的液体凝胶组合物。 液体凝胶包含某些羟基烷基脂肪胺或脂肪咪唑鎓季铵盐的液体混合物，其由与烷基铵离子离子交换的亲有机质的膨胀晶格粘土凝胶化。 以足够的浓度使用粘土以形成稳定的凝胶，并将其研磨成液体载体以形成具有合适粘度的凝胶，以允许其用计量注射设备加入到树脂中。 在树脂中以低浓度使用时的组合物通过赋予树脂永久抗静电特性并显着降低其脆性从而增加树脂的伸长率，冲击强度和拉伸强度，从而提高树脂的物理性能。 固体，细分着色剂也可以以所得混合物的10至约70重量％的浓度混合到液体凝胶组合物中，从而提供液体着色剂组合物以使树脂着色并用单一组合物改善其物理性能。
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公开(公告)号：US4341565A
公开(公告)日：1982-07-27
申请号：US191320
申请日：1980-09-26
申请人： Irvin W. Martenson
发明人： Irvin W. Martenson
CPC分类号： C09B67/006 , C08J3/22
摘要： There is disclosed a stable liquid gel of colorants useful for incorporation in thermoplastic and thermosetting resins. The liquid gel comprises a liquid vehicle which is a plasticizer for the resins and which is gelled by an organophilic, expanding lattice clay which is ion exchanged with alkyl ammonium ions. Preferably the gel is modified by the addition of certain hydroxyalkyl fatty amines or fatty imidazolium quaternaries. The clay is employed at a sufficient concentration to form a stable gel and is milled into the liquid vehicle to form a pre-gel of substantially lesser than the final, desired viscosity. Solid, subdivided colorants are blended into the pre-gel at a concentration from 10 to about 70 weight percent and the resultant mixture is milled to the final desired viscosity. The presence of the fatty amine or fatty imidazolium compounds greatly increases the colorant loading capacity of the gel and imparts desirable properties to the molded products such as reduced brittleness and anti-static properties.
摘要翻译： 公开了可用于结合到热塑性和热固性树脂中的稳定的着色剂液体凝胶。 液体凝胶包括液体载体，其为树脂的增塑剂，并且通过与烷基铵离子离子交换的亲有机质的膨胀格子状粘土凝胶化。 优选地，通过加入某些羟烷基脂肪胺或脂肪咪唑季铵来修饰凝胶。 以足够的浓度使用粘土以形成稳定的凝胶并研磨成液体载体以形成基本上小于最终所需粘度的预凝胶。 将固体，细分着色剂以10至约70重量％的浓度掺入预凝胶中，并将所得混合物研磨至最终所需粘度。 脂肪胺或脂肪咪唑化合物的存在大大增加了凝胶的着色剂负载能力，并赋予模制产品所需的性能，例如降低的脆性和抗静电性能。
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公开(公告)号：US3376138A
公开(公告)日：1968-04-02
申请号：US32882863
申请日：1963-12-09
IPC分类号： G03F7/038
CPC分类号： G03F7/0388
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公开(公告)号：US4792464A
公开(公告)日：1988-12-20
申请号：US56378
申请日：1987-06-01
申请人： Irvin W. Martenson
发明人： Irvin W. Martenson
摘要： There is disclosed a water-base coating composition and method for its use that forms a readily strippable protective film on metal surfaces. The composition includes a film former ingredient which is a terpolymer of polyvinyl butyral, polyvinyl alcohol and polyvinyl acetate. The water-base coating composition also contains a fugitive corrosion inhibitor, i.e., a corrosion inhibitor having a sufficient vapor pressure to impart corrosion resistance to surfaces coated with the film former composition. Suitable corrosion inhibitors are aromatic triazoles such as benzotriazole. A leveling agent such as morpholine is used to prevent the film from pulling from the edges during drying. Morpholine is particularly advantageous as it extends the working time when coating objects, and prevents the dispersion from clogging nozzles of spraying equipment. Morpholine also contributes to the corrosion inhibition of the coating.
摘要翻译： 公开了一种水性涂料组合物及其使用方法，其在金属表面上形成易剥离的保护膜。 该组合物包括成膜剂成分，它是聚乙烯醇缩丁醛，聚乙烯醇和聚乙酸乙烯酯的三元共聚物。 水性涂料组合物还含有挥发性缓蚀剂，即具有足够蒸气压以赋予涂覆有成膜剂组合物的表面耐腐蚀性的腐蚀抑制剂。 合适的腐蚀抑制剂是芳族三唑如苯并三唑。 使用诸如吗啉的流平剂来防止在干燥期间膜从边缘拉出。 吗啉是特别有利的，因为它延长了涂覆物体的工作时间，并且防止了分散体堵塞喷涂设备的喷嘴。 吗啉还有助于涂层的腐蚀抑制。
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公开(公告)号：US4444714A
公开(公告)日：1984-04-24
申请号：US391488
申请日：1982-06-24
申请人： Irvin W. Martenson
发明人： Irvin W. Martenson
CPC分类号： C09B67/006 , C08J3/22
摘要： There is disclosed a stable liquid gel of colorants useful for incorporation in thermoplastic and thermosetting resins. The liquid gel comprises a liquid vehicle which is a plasticizer for the resins and which is gelled by an organophilic, expanding lattice clay which is ion exchanged with alkyl ammonium ions. Preferably the gel is modified by the addition of certain hydroxyalkyl fatty amines or fatty imidazolium quaternaries. The clay is employed at a sufficient concentration to form a stable gel and is milled into the liquid vehicle to form a pre-gel of substantially lesser than the final, desired viscosity. Solid, subdivided colorants are blended into the pre-gel at a concentration from 10 to about 70 weight percent and the resultant mixture is milled to the final desired viscosity. The presence of the fatty amine or fatty imidazolium compounds greatly increases the colorant loading capacity of the gel and imparts desirable properties to the molded products such as reduced brittleness and anti-static properties.
摘要翻译： 公开了可用于结合到热塑性和热固性树脂中的稳定的着色剂液体凝胶。 液体凝胶包括液体载体，其为树脂的增塑剂，并且通过与烷基铵离子离子交换的亲有机质的膨胀格子状粘土凝胶化。 优选地，通过加入某些羟烷基脂肪胺或脂肪咪唑季铵来修饰凝胶。 以足够的浓度使用粘土以形成稳定的凝胶，并将其研磨成液体载体以形成基本上小于最终期望粘度的预凝胶。 将固体，细分着色剂以10至约70重量％的浓度掺入预凝胶中，并将所得混合物研磨至最终所需粘度。 脂肪胺或脂肪咪唑化合物的存在大大增加了凝胶的着色剂负载能力，并赋予模制产品所需的性能，例如降低的脆性和抗静电性能。
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公开(公告)号：US3376139A
公开(公告)日：1968-04-02
申请号：US53923666
申请日：1966-02-01
IPC分类号： G03F7/038
CPC分类号： G03F7/0388 , Y10S430/117
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