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公开(公告)号:US12122684B2
公开(公告)日:2024-10-22
申请号:US18143205
申请日:2023-05-04
发明人: Jun Yamaguchi , Takumi Miyazaki , Ryo Muraguchi , Tatsuya Uehara
IPC分类号: C01G23/053 , C09C1/36 , C09D7/62
CPC分类号: C01G23/053 , C09C1/3653 , C09D7/62 , C01P2002/70 , C01P2004/03 , C01P2004/64 , C01P2006/60
摘要: Provided are titanium oxide fine particles which are excellent in transparency and are less photocatalytically active while maintaining a high refractive index, a dispersion of such fine particles, and a method for producing such a dispersion. The method for producing a dispersion of iron-containing rutile titanium oxide fine particles including a step (1) of neutralizing an aqueous metal mineral acid salt solution containing Ti and Fe in Fe2O3/(TiO2+Fe2O3)=0.001 to 0.010 to form an iron-containing hydrous titanic acid; a step (2) of adding an aqueous hydrogen peroxide solution to form an aqueous solution of iron-containing peroxotitanic acid having an average particle size of 15 to 50 nm; a step (3) of adding a tin compound so as to satisfy TiO2/SnO2=6 to 16; a step (4) of adding a sol of silica-based fine particles which contain Si and a metal element M in SiO2/MOx/2=99.9/0.1 to 80/20, the addition being made so as to satisfy SiO2/(oxides of the other elements)=0.08 to 0.22; and a step (5) of hydrothermally treating the solution obtained in the step (4).
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公开(公告)号:US20240301211A1
公开(公告)日:2024-09-12
申请号:US18547770
申请日:2022-03-30
发明人: Yuko HORI , Hirotada ARAKANE , Ryo MURAGUCHI
CPC分类号: C09C1/3653 , C09D7/61 , C01P2002/60 , C01P2004/64 , C01P2004/84
摘要: The present invention relates to particles having a rutile-type crystal structure. The particles have a crystallite diameter of 7 nm or more and contains 90% by weight or more of titanium oxide in terms of TiO2 and 0.2 to 10% by weight of tin oxide in terms of SnO2. Such particles are easily dispersed in a solvent and have a high refractive index.
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公开(公告)号:US20240254343A1
公开(公告)日:2024-08-01
申请号:US18289452
申请日:2022-05-11
发明人: Jun YAMAGUCHI , Takehiro SHIMIZU , Ryo MURAGUCHI
IPC分类号: C09D7/61 , C01G23/053 , C08K3/22 , C09D7/40 , C09D183/06
CPC分类号: C09D7/61 , C01G23/0536 , C09D7/67 , C09D183/06 , C01P2002/52 , C01P2002/78 , C01P2004/64 , C08K2003/2241 , C08K2201/011
摘要: Rutile titanium oxide particles, in which Fe and Zr are dissolved to form a solid solution, have an interplanar spacing of a (110) plane obtained by X-ray diffraction measurement of 0.3250 nm or more and an average particle size in a range from 5 nm to 50 nm.
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公开(公告)号:US20230303403A1
公开(公告)日:2023-09-28
申请号:US18143205
申请日:2023-05-04
发明人: Jun Yamaguchi , Takumi Miyazaki , Ryo Muraguchi , Tatsuya Uehara
IPC分类号: C01G23/053 , C09D7/62 , C09C1/36
CPC分类号: C01G23/053 , C09D7/62 , C09C1/3653 , C01P2002/70 , C01P2004/03 , C01P2004/64 , C01P2006/60
摘要: Provided are titanium oxide fine particles which are excellent in transparency and are less photocatalytically active while maintaining a high refractive index, a dispersion of such fine particles, and a method for producing such a dispersion. The method for producing a dispersion of iron-containing rutile titanium oxide fine particles including a step (1) of neutralizing an aqueous metal mineral acid salt solution containing Ti and Fe in Fe2O3/(TiO2+Fe2O3)=0.001 to 0.010 to form an iron-containing hydrous titanic acid; a step (2) of adding an aqueous hydrogen peroxide solution to form an aqueous solution of iron-containing peroxotitanic acid having an average particle size of 15 to 50 nm; a step (3) of adding a tin compound so as to satisfy TiO2/SnO2=6 to 16; a step (4) of adding a sol of silica-based fine particles which contain Si and a metal element M in SiO2/MOx/2=99.9/0.1 to 80/20, the addition being made so as to satisfy SiO2/(oxides of the other elements)=0.08 to 0.22; and a step (5) of hydrothermally treating the solution obtained in the step (4).
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公开(公告)号:US11618858B1
公开(公告)日:2023-04-04
申请号:US17542724
申请日:2021-12-06
申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals Ltd. , Japan Cooperation Center Petroleum
摘要: In accordance with one or more embodiments of the present disclosure, a method for hydrodearylating aromatic bottoms oil includes contacting at least one aromatic bottoms oil stream with at least one catalyst composition and hydrogen in a reactor in order to hydrodearylate the aromatic bottoms oil stream. The catalyst composition includes a catalyst support comprising framework-substituted ultra-stable Y-type (USY) zeolite substituted with at least zirconium atoms. The catalyst composition does not include a hydrogenative metal component disposed on the support.
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公开(公告)号:US11427730B2
公开(公告)日:2022-08-30
申请号:US16764050
申请日:2018-11-15
摘要: Provided is a dispersion liquid of silica particles, comprising silica particles having an average particle diameter of 5 to 300 nm determined from an electron micrograph and a density of 1.20 g/cm3 or more determined from a specific surface area determined by a BET method using nitrogen adsorption, wherein the dispersion liquid has a pH of less than 8, a silica concentration of 12 to 40% by mass, and a viscosity in terms of a silica concentration of 20% by mass of 40 mPa·s or less. When this silica particle is used as an abrasive, it is possible to realize a sufficient polishing speed and a smooth polished surface on which occurrence of scratches is suppressed.
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公开(公告)号:US20220072517A1
公开(公告)日:2022-03-10
申请号:US17280553
申请日:2019-09-06
IPC分类号: B01J23/883 , B01J35/10 , B01J35/00 , B01J27/14 , B01J21/04 , B01J21/06 , B01J6/00 , B01J37/02 , B01J37/06 , B01J37/08 , B01J23/882
摘要: To provide a catalyst capable of hydrotreating a hydrocarbon oil with high desulfurization activity.
A hydrotreating catalyst for a hydrocarbon oil includes: an inorganic composite oxide carrier including alumina as a main component; and an active metal component supported on the carrier, the active metal component including, as active metal species, a first metal which is at least one of molybdenum and tungsten, and a second metal which is at least one of cobalt and nickel, the hydrotreating catalyst for having a Lewis acid amount and a Brönsted acid amount per unit surface area of 0.80 μmol/m2 or more and 0.03 μmol/m2 or less, respectively, as measured by pyridine desorption at 250° C. and a BET single-point method.-
公开(公告)号:US11267715B2
公开(公告)日:2022-03-08
申请号:US16616010
申请日:2018-05-23
IPC分类号: C01B33/12 , C09K3/14 , H01L21/304
摘要: Aiming at providing a ceria-based composite particle dispersion capable of polishing silica film, Si wafer or even hard-to-process material at high polishing rate, and can give high surface accuracy, disclosed is a ceria-based composite particle dispersion that contains a ceria-based composite particle that has an average particle size of 50 to 350 nm, to solve the aforementioned problem, featured by that the ceria-based composite particle has a mother particle, a cerium-containing silica layer, a child particle, and an easily soluble silica-containing layer; the mother particle contains amorphous silica as a major ingredient; the child particle contains crystalline ceria as a major ingredient; ratio of the mass of the easily soluble silica-containing layer relative to the mass of the ceria-based composite particle falls in a specific range; mass ratio of silica and ceria in the ceria-based composite particle falls in a specific range; the ceria-based composite particle, when analyzed by X-ray diffractometry, shows only a crystal phase of ceria; and the ceria-based composite particle has an average crystallite size of the crystalline ceria, when analyzed by X-ray diffractometry, of 10 to 25 nm.
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公开(公告)号:US20220008908A1
公开(公告)日:2022-01-13
申请号:US16923346
申请日:2020-07-08
申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals Ltd. , Japan Cooperation Center Petroleum
摘要: A method for producing a hydrocracking catalyst includes preparing a framework substituted Y-type zeolite, preparing a binder, co-mulling the framework substituted Y-type zeolite, the binder, and one or more hydrogenative metal components to form a catalyst precursor, and calcining the catalyst precursor to generate the hydrocracking catalyst. The framework substituted Y-type zeolite is prepared by calcining a Y-type zeolite at 500° C. to 700° C. to form a calcined Y-type zeolite. Further, the framework substituted Y-type zeolite is prepared by forming a suspension containing the calcined Y-type zeolite, the suspension having a liquid to solid mass ratio of 5 to 15, adding acid to adjust the pH of the suspension to less than 2.0, adding and mixing one or more of a zirconium compound, a hafnium compound, or a titanium compound to the suspension, and neutralizing the pH of the suspension to obtain the framework substituted Y-type zeolite.
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公开(公告)号:US11142703B1
公开(公告)日:2021-10-12
申请号:US16985588
申请日:2020-08-05
申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals, Ltd. , Japan Cooperation Center Petroleum
摘要: Methods for cracking a hydrocarbon oil include contacting the hydrocarbon oil with a catalyst system in a fluidized catalytic cracking unit to produce light olefins and gasoline fuel. The catalyst system includes a FCC base catalyst and a catalyst additive. The FCC base catalyst includes a Y-zeolite. The catalyst additive includes a framework-substituted *BEA-type zeolite. The framework-substituted *BEA-type zeolite has a modified *BEA framework. The modified *BEA framework is a *BEA aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms selected from titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. The FCC base catalyst may include a framework-substituted ultra-stable Y (USY)-zeolite as the Y-zeolite. The framework-substituted USY-zeolite has USY aluminosilicate framework modified by substituting a portion of framework aluminum atoms with titanium atoms, zirconium atoms, hafnium atoms, or combinations thereof.
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