公开(公告)号：US4983752A

公开(公告)日：1991-01-08

申请号：US525309

申请日：1990-05-18

申请人： Hans-Dieter Eichhorn ,  Martin J. Dancey ,  Guenter Herrmann ,  James W. Steen

发明人： Hans-Dieter Eichhorn ,  Martin J. Dancey ,  Guenter Herrmann ,  James W. Steen

IPC分类号： B01J27/02 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J27/0576 ,  B01J27/19 ,  B01J27/285 ,  B01J27/30 ,  B01J38/485 ,  B01J2523/00 ,  B01J27/188 ,  B01J27/195 ,  B01J35/023 ,  Y02P20/52 ,  Y02P20/584

摘要： Acrylonitrile is prepared by a process which comprises the ammoxidation of propylene with ammonia and molecular oxygen or a gas containing molecular oxygen at from 300.degree. to 600.degree. C. in the presence of a metal oxide catalyst which contains tellurium and one or more of the metals iron, molybdenum and antimony, in a fluidized bed, with regeneration of the catalyst during the reaction by the addition of oxidic tellurium compounds or tellurium compounds which form oxidic tellurium compounds under the reaction conditions, in dissolved or suspended form.

摘要翻译： 丙烯腈的制备方法包括在含有碲和一种或多种金属的金属氧化物催化剂的存在下，将丙烯与氨和分子氧或含有分子氧的气体在300-600℃下进行氨氧化 铁，钼和锑在流化床中，通过在反应条件下以溶解或悬浮形式加入形成氧化碲化合物的氧化碲化合物或碲化合物在反应过程中再生催化剂。