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1.发明授权Surfactant-containing acetoacetoxy-functional and enamine-functional polymers 失效含表面活性剂的乙酰乙酰氧基官能和烯胺官能聚合物公开(公告)号：US06297328B1
公开(公告)日：2001-10-02
申请号：US09050973
申请日：1998-03-31
IPC分类号： C08F832
CPC分类号： C09J133/062 , C08F8/30 , C08F220/28 , C08F2800/20 , C09D11/106 , C09D133/062 , Y10S525/902 , C08F265/04
摘要： Surfactant-containing acetoacetoxy-functional polymers (SAAP's) are described. The acetoacetoxy-functional polymer may be a surfactant-containing enamine-functional polymer and more preferably a surfactant-containing, polymeric (polyamino)enamine (PPAE). The PPAE is the reaction product of a surfactant-containing acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The polymers may be prepared as waterborne polymer compositions, such as latexes. The waterborne polymer compositions can be prepared with high solids content while maintaining low viscosity. Waterborne polymer compositions containing the polymers of the inventions are useful in a variety of coating formulations such as, for example, paints, inks, sealants, and adhesives. When used in coating formulations, the polymers of the invention provide adhesion and crosslinking in the final film or coating. The film or coating may be cured at ambient temperatures or may be thermally cured.
摘要翻译： 描述含表面活性剂的乙酰乙酰氧基官能聚合物（SAAP）。 乙酰乙酰氧基官能聚合物可以是含表面活性剂的烯胺官能聚合物，更优选含表面活性剂的聚合（聚氨基）烯胺（PPAE））。 PPAE是含表面活性剂的乙酰乙酰氧基官能聚合物（SAAP）和聚（亚烷基亚胺）的反应产物。 聚合物可以制备为水性聚合物组合物，例如胶乳。 水性聚合物组合物可以以高固体含量制备，同时保持低粘度。 含有本发明聚合物的水性聚合物组合物可用于各种涂料配方，例如涂料，油墨，密封剂和粘合剂。 当用于涂料制剂时，本发明的聚合物在最终的膜或涂层中提供粘合和交联。 膜或涂层可以在环境温度下固化或者可以热固化。
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2.发明授权Surfactant-containing acetoacetoxy-functional and enamine-functional polymers 失效含表面活性剂的乙酰乙酰氧基官能和烯胺官能聚合物
公开(公告)号：US6028155A
公开(公告)日：2000-02-22
申请号：US861433
申请日：1997-05-21
IPC分类号： C08F8/00 , C08F220/28 , C08F246/00 , C09D133/06 , C09J133/06 , C08F228/00 , C08F224/00
CPC分类号： C09J133/062 , C08F220/28 , C08F246/00 , C08F8/30 , C09D133/062 , C08F2800/20 , C08F2810/20 , C08F2810/50
摘要： Surfactant-containing acetoacetoxy-functional polymers (SAAP's) are described. The acetoacetoxy-functional polymer may be a surfactant-containing enamine-functional polymer and more preferably a surfactant-containing, polymeric (polyamino)enamine (PPAE). The PPAE is the reaction product of a surfactant-containing acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The polymers may be prepared as waterborne polymer compositions, such as latexes. The waterborne polymer compositions can be prepared with high solids content while maintaining low viscosity. Waterborne polymer compositions containing the polymers of the inventions are useful in a variety of coating formulations such as, for example, paints, inks, sealants, and adhesives. When used in coating formulations, the polymers of the invention provide adhesion and crosslinking in the final film or coating. The film or coating may be cured at ambient temperatures or may be thermally cured.
摘要翻译： 描述含表面活性剂的乙酰乙酰氧基官能聚合物（SAAP）。 乙酰乙酰氧基官能聚合物可以是含表面活性剂的烯胺官能聚合物，更优选含表面活性剂的聚合（聚氨基）烯胺（PPAE））。 PPAE是含表面活性剂的乙酰乙酰氧基官能聚合物（SAAP）和聚（亚烷基亚胺）的反应产物。 聚合物可以制备为水性聚合物组合物，例如胶乳。 水性聚合物组合物可以以高固体含量制备，同时保持低粘度。 含有本发明聚合物的水性聚合物组合物可用于各种涂料配方，例如涂料，油墨，密封剂和粘合剂。 当用于涂料制剂时，本发明的聚合物在最终的膜或涂层中提供粘合和交联。 膜或涂层可以在环境温度下固化或者可以热固化。
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公开(公告)号：US5998543A
公开(公告)日：1999-12-07
申请号：US861431
申请日：1997-05-21
IPC分类号： B01J13/00 , C08F6/00 , C08L33/14 , C08L33/24 , C08L101/02 , C09D5/00 , C09D11/10 , C09D113/02 , C09D133/14 , C09D133/24 , C08L39/00 , C08L57/00
CPC分类号： C09D11/106
摘要： This invention provides the composition, preparation, and end-use of waterborne crosslinking technology based compositions prepared from water-based latexes. The invention provides a water-based latex comprising dispersed, waterborne amino-functional polymer particles; dispsered, waterborne acetoacetoxy-functional polymer particles; and water. In a preferred embodiment, a latex of the invention comprises dipsered, waterborne polymeric (polyamino)enamine (PPAE) particles; dispersed, waterborne acetoacetoxy-functional polymer particles; and water. The PPAE is the reaction product of a surfactant-stabilized acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The water-based latexes of the invetion provide stable emulsions containing a blend of waterborne polymer particles which undergo crosslinking upon film formation. The latex films or coatings may be cured at ambient temperatures or may be thermally cured. The latex is useful in variety of coating compositons such as, for example, paints, inks, sealants, and adhesives.
摘要翻译： 本发明提供由水性胶乳制备的基于水性交联技术的组合物，制备和最终用途。 本发明提供一种包含分散的水性氨基官能聚合物颗粒的水性胶乳; 水性乙酰乙酰氧基官能聚合物颗粒; 和水。 在优选的实施方案中，本发明的胶乳包含浸渍的水性聚合物（聚氨基）烯胺（PPAE）颗粒; 水性乙酰乙酰氧基官能聚合物颗粒; 和水。 PPAE是表面活性剂稳定的乙酰乙酰氧基官能聚合物（SAAP）和聚（亚烷基亚胺）的反应产物。 水性胶乳的投料提供了稳定的乳液，其含有在成膜时经历交联的水性聚合物颗粒的混合物。 胶乳膜或涂层可以在环境温度下固化或者可以热固化。 胶乳可用于各种涂料组合物，例如油漆，油墨，密封剂和粘合剂。
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公开(公告)号：US5962556A
公开(公告)日：1999-10-05
申请号：US861437
申请日：1997-05-21
申请人： James Wayne Taylor
发明人： James Wayne Taylor
IPC分类号： C08L57/00 , C08F220/12 , C08F220/34 , C08L31/02 , C08L33/14 , C08L37/00 , C08K3/20 , C08L63/02
CPC分类号： C08F220/34 , C08F220/12
摘要： The present invention is directed to a functional latex polymer composition resistant to hydrolysis which contains a vinyl polymer of copolymerizable monoethylenically unsaturated monomers where at least one monomer contains at least one hydrolyzable functional group. The combined oxygen and nitrogen content of the vinyl polymer is up to about 27 wt %, based on the monomers in the vinyl polymer.
摘要翻译： 本发明涉及耐水解的功能性胶乳聚合物组合物，其包含可共聚的单烯属不饱和单体的乙烯基聚合物，其中至少一种单体含有至少一个可水解的官能团。 基于乙烯基聚合物中的单体，乙烯基聚合物的组合氧和氮含量高达约27重量％。
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公开(公告)号：US5869590A
公开(公告)日：1999-02-09
申请号：US861430
申请日：1997-05-21
CPC分类号： C09D4/00 , C09D4/06 , Y10S525/902
摘要： This invention provides polymers useful in coating compositions. The polymers are prepared via a free radical polymerization using ethylenically unsaturated monomers. The polymers of this invention possess pendant allylic groups which are capable of effecting free-radical flux when the compositions are applied to a substrate and exposed to oxygen. Coatings formed from preferred compositions possess superior solvent, print, and block resistance.
摘要翻译： 本发明提供了可用于涂料组合物中的聚合物。 通过使用烯属不饱和单体的自由基聚合制备聚合物。 本发明的聚合物具有侧链烯丙基，当将组合物施用于基底并暴露于氧气时，它们能够实现自由基通量。 由优选组合物形成的涂料具有优异的溶剂，印刷和阻挡性。
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6.发明授权Process for preparing reactive latex blends which are chemically and physically stable until film formation 失效制备化学和物理稳定直到成膜的反应性胶乳混合物的方法
公开(公告)号：US6060556A
公开(公告)日：2000-05-09
申请号：US82723
申请日：1998-05-21
IPC分类号： C08J3/03 , C08F8/30 , C08G81/00 , C08L33/14 , C08L101/02 , C09D133/06 , C09D133/14 , C09D157/12 , C08L31/00
CPC分类号： C08F8/30 , C09D133/062 , C09D133/068 , C09D133/14 , C09D157/12
摘要： This invention provides the composition, preparation, and end-use of waterborne crosslinking technology based compositions prepared from water-based latexes. The invention provides a water-based latex comprising dispersed, waterborne amino-functional polymer particles; dispersed, waterborne pendant-functional polymer particles; and water. The waterborne pendant-functional polymer comprises at least one pendant amine reactive functional moiety selected from the group consisting of carbonate, epoxide, isocyanate, isopropenyl, carboxylic acid, and allyl groups. In a preferred embodiment, a latex of the invention comprises dispersed, waterborne polymeric (polyamino)enamine (PPAE) particles; dispersed, waterborne pendant-functional polymer particles; and water. The PPAE is the reaction product of a surfactant-stabilized acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine). The water-based latexes of the invention provide stable emulsions containing a blend of waterborne polymer particles which undergo crosslinking upon film formation. The latex films or coatings may be cured at ambient temperatures or may be thermally cured. The latex is useful in variety of coating compositions such as, for example, paints, inks, sealants, and adhesives.
摘要翻译： 本发明提供由水性胶乳制备的基于水性交联技术的组合物，制备和最终用途。 本发明提供一种包含分散的水性氨基官能聚合物颗粒的水性胶乳; 分散的水性侧链官能聚合物颗粒; 和水。 水性侧链官能聚合物包含至少一种选自碳酸酯，环氧化物，异氰酸酯，异丙烯基，羧酸和烯丙基的侧胺活性官能部分。 在优选的实施方案中，本发明的胶乳包含分散的水性聚合物（聚氨基）烯胺（PPAE）颗粒; 分散的水性侧链官能聚合物颗粒; 和水。 PPAE是表面活性剂稳定的乙酰乙酰氧基官能聚合物（SAAP）和聚（亚烷基亚胺）的反应产物。 本发明的水性胶乳提供稳定的乳液，其含有水性聚合物颗粒的混合物，其在成膜时经历交联。 胶乳膜或涂层可以在环境温度下固化或者可以热固化。 胶乳可用于各种涂料组合物，例如油漆，油墨，密封胶和粘合剂。
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7.发明授权
公开(公告)号：US5891966A
公开(公告)日：1999-04-06
申请号：US988567
申请日：1997-12-11
CPC分类号： C08F8/42
摘要： The present invention provides waterborne crosslinkable polymer compositions encompassing (A) functional latex polymers containing at least one pendant ethylenically unsaturated functional group, (B) a silicon hydride compound containing at least two reactive hydrogen atoms, and (C) a catalyst suitable to attain a crosslinked film.
摘要翻译： 本发明提供了包含（A）含有至少一个侧基烯键式不饱和官能团的官能胶乳聚合物的水性交联聚合物组合物，（B）含有至少两个反应性氢原子的氢化硅化合物，和（C）适于获得 交联膜。
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公开(公告)号：US5891950A
公开(公告)日：1999-04-06
申请号：US861436
申请日：1997-05-21
IPC分类号： C08L79/02 , C08F8/00 , C08F220/28 , C08G73/04 , C09D11/10 , C09D133/06 , C08K3/04
CPC分类号： C09D133/062 , C08F220/28 , C08F8/30 , C08F8/42 , C09D11/106 , C08F2800/20 , C08F2810/20 , C08F2810/50
摘要： A water-based ink composition is described. The ink composition contains a pigment and a polymer latex. The polymer latex may be a polymeric (polyamino) enamine latex or a mixture of a polymeric (polyamino) enamine latex and an acetoacetoxy-functional polymer latex. The inks are particularly useful as laminating and surface-printing inks. Methods of printing are also described.
摘要翻译： 对水性油墨组合物进行说明。 油墨组合物含有颜料和聚合物胶乳。 聚合物胶乳可以是聚合（聚氨基）烯胺胶乳或聚合（聚氨基）烯胺胶乳和乙酰乙酰氧基官能聚合物胶乳的混合物。 油墨特别适用于层压和表面印刷油墨。 还描述了印刷方法。
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公开(公告)号：US5783626A
公开(公告)日：1998-07-21
申请号：US616866
申请日：1996-03-15
IPC分类号： C08F291/00 , C08F8/00 , C08F220/12 , C08F246/00 , C08F290/12 , C09D4/00 , C09D155/00 , C09D201/02 , C08L33/14
CPC分类号： C08F8/00
摘要： Provided are allyl-functional polymers having pendant enamine moieties and preferably also possessing pendant methacrylate groups. The presence of such groups in the polymer allows for a free-radical crosslinking reaction to take place during film formation and provides coatings having superior solvent resistance. Amino-containing waterborne particles can be prepared by reacting propylene imine with carboxylic acid-containing latexes. The amino-functionalized latexes are subsequently reacted at room temperature with for example acetoacetoxyethyl methacrylate. During ambient and thermal cure studies, clear films exhibited significant increases in solvent resistance, gel fraction, and crosslink density.
摘要翻译： 提供具有侧链烯胺部分并且优选还具有甲基丙烯酸侧基的烯丙基官能聚合物。 在聚合物中存在这样的基团允许在成膜期间发生自由基交联反应，并提供具有优异耐溶剂性的涂层。 含氨基的水性颗粒可以通过使丙烯亚胺与含羧酸的胶乳反应来制备。 氨基官能化胶乳随后在室温下与例如甲基丙烯酸乙酰乙酰氧基乙酯反应。 在环境和热固化研究期间，透明膜显示出耐溶剂性，凝胶分数和交联密度的显着增加。
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