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    Production of linear alkyl benzene
    1.
    发明授权
    Production of linear alkyl benzene 有权
    生产线性烷基苯

    公开(公告)号：US07863492B2

    公开(公告)日：2011-01-04

    申请号：US10549769

    申请日：2004-03-10

    申请人： Edward Ludovicus Koper ,  Ivan Greager ,  Jan Hendrik Scholtz ,  Johan Pieter de Wet ,  Mieke Ann Desmet ,  Wilhelmina Jansen ,  Paul Jacobson

    发明人： Edward Ludovicus Koper ,  Ivan Greager ,  Jan Hendrik Scholtz ,  Johan Pieter de Wet ,  Mieke Ann Desmet ,  Wilhelmina Jansen ,  Paul Jacobson

    IPC分类号： C07C2/68

    CPC分类号： C07C2/66 ,  C07C15/02

    摘要： This invention relates to a process for producing linear alkyl benzene and linear paraffins, the process including the steps of obtaining a hydrocarbon condensate containing olefins, paraffins and oxygenates from a low temperature Fischer-Tropsch reaction; a) fractionating a desired carbon number distribution from the hydrocarbon condensate to form a fractionated hydrocarbon condensate stream; b) extracting oxygenates from the fractionated hydrocarbon condensate stream from step a) to form a stream containing olefins and paraffins; c) alkylating the stream containing olefins and paraffins from step b) with benzene in the presence of a suitable alkylation catalyst; and d) recovering linear alkyl benzene and linear paraffin.

    摘要翻译： 本发明涉及直链烷基苯和直链烷烃的制备方法，该方法包括以下步骤：从低温费 - 托反应获得含有烯烃，链烷烃和含氧化合物的烃缩合物; a）从烃缩合物中分馏所需的碳数分布以形成分馏的烃冷凝物流; b）从来自步骤a）的分馏的烃冷凝物流中提取含氧化合物以形成含有烯烃和链烷烃的物流; c）在合适的烷基化催化剂存在下，用苯将来自步骤b）的含有烯烃和链烷烃的物流烷基化; 和d）回收直链烷基苯和线型石蜡。

    Heat treated Fischer-Tropsch catalyst particles
    2.
    发明授权
    Heat treated Fischer-Tropsch catalyst particles 有权
    热处理费托催化剂颗粒

    公开(公告)号：US07547657B2

    公开(公告)日：2009-06-16

    申请号：US10677878

    申请日：2003-10-02

    申请人： Rafael Luis Espinoza ,  Philip Gibson ,  Jan Hendrik Scholtz

    发明人： Rafael Luis Espinoza ,  Philip Gibson ,  Jan Hendrik Scholtz

    IPC分类号： B01J23/70

    CPC分类号： C10G2/331 ,  B01J23/745 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/006 ,  B01J37/03 ,  B01J37/08 ,  C07C1/0445 ,  C07C2523/745 ,  C10G2/332 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043

    摘要： The invention provides heat treated self-supported precipitated α-Fe2O3-based Fischer-Tropsch catalyst particles. The catalyst particles are breakage resistant, thus inhibiting the formation of catalyst fines in the Fischer-Tropsch reactor, thereby maintaining the performance of the reactor and reducing the contamination of down stream processes and catalysts by the catalyst fines. The catalyst particles also exhibit superior synthesis performance in low temperature Fischer-Tropsch processes, e.g., slurry bed reactor processes for the production of wax and other syncrudes. The invention also provides a method for producing the particles and a process for using the particles.

    摘要翻译： 本发明提供热处理的自支撑沉淀的α-Fe 2 O 3基费 - 托催化剂颗粒。 催化剂颗粒具有抗破坏性，从而抑制费 - 托反应器中催化剂细粉的形成，从而保持反应器的性能，并减少催化剂细粉对下游方法和催化剂的污染。 催化剂颗粒在低温费 - 托工艺中也表现出优异的合成性能，例如用于生产蜡和其它合成油的浆料床反应器方法。 本发明还提供了一种制备颗粒的方法和使用该颗粒的方法。

    Production of linear alkyl benzene
    4.
    发明授权
    Production of linear alkyl benzene 有权
    生产线性烷基苯

    公开(公告)号：US07737312B2

    公开(公告)日：2010-06-15

    申请号：US10549768

    申请日：2004-03-10

    申请人： Ivan Greager ,  Jan Hendrik Scholtz ,  Johan Pieter de Wet ,  Mieke Ann Desmet ,  Wilhelmina Jansen ,  Paul Jacobson ,  Luis Pablo Fidel Dancuart

    发明人： Ivan Greager ,  Jan Hendrik Scholtz ,  Johan Pieter de Wet ,  Mieke Ann Desmet ,  Wilhelmina Jansen ,  Paul Jacobson ,  Luis Pablo Fidel Dancuart

    IPC分类号： C07C2/68

    CPC分类号： C07C2/66 ,  C07C7/04 ,  C07C7/10 ,  C10G2/32 ,  C10G29/205 ,  C10G2300/1022 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2400/10 ,  C10G2400/30

    摘要： This invention relates to a process for producing linear alkyl benzene, the process including the steps of obtaining a hydrocarbon condensate containing olefins, paraffins and oxygenates from a low temperature Fischer-Tropsch reaction; a) fractionating a desired carbon number distribution from the hydrocarbon condensate to form a fractionated hydrocarbon condensate stream; b) extracting oxygenates from the fractionated hydrocarbon condensate stream from step (a) to form a stream containing olefins and paraffins; c) combining the stream containing olefins and paraffins from step (b) with the feed stream from step (g) to form a combined stream; d) alkylating olefins in the combined stream from step (c) with benzene in the presence of a suitable alkylation catalyst in an alkylation reactor; e) recovering linear alkyl benzene from the alkylation reactor; f) recovering unreacted paraffins from the alkylation reactor; g) dehydrogenating the unreacted paraffins in the presence of a suitable dehydrogenation catalyst to form a feed stream containing olefins and paraffins; and h) sending the feed stream containing olefins and paraffins from step (g) to step (c).

    摘要翻译： 本发明涉及一种直链烷基苯的制备方法，该方法包括以下步骤：从低温费 - 托反应获得含有烯烃，链烷烃和含氧化合物的烃缩合物; a）从烃缩合物中分馏所需的碳数分布以形成分馏的烃冷凝物流; b）从步骤（a）的分馏的烃冷凝物流中提取含氧化合物以形成含有烯烃和链烷烃的物流; c）将来自步骤（b）的含有烯烃和链烷烃的料流与来自步骤（g）的进料流混合以形成组合料流; d）在烷基化反应器中，在合适的烷基化催化剂存在下，将来自步骤（c）的合并物流中的烯烃与苯烷基化; e）从烷基化反应器回收直链烷基苯; f）从烷基化反应器回收未反应的链烷烃; g）在合适的脱氢催化剂存在下使未反应的链烷烃脱氢以形成含有烯烃和链烷烃的进料流; 和h）将来自步骤（g）的含有烯烃和链烷烃的进料流送至步骤（c）。