公开(公告)号：US08481448B2

公开(公告)日：2013-07-09

申请号：US12838863

申请日：2010-07-19

申请人： Wugeng Liang ,  David Sullivan ,  James W. Kauffman ,  Clark Rea ,  Joe Linzer ,  Shahid Shaikh

发明人： Wugeng Liang ,  David Sullivan ,  James W. Kauffman ,  Clark Rea ,  Joe Linzer ,  Shahid Shaikh

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J23/32 ,  B01J27/00 ,  B01J27/185 ,  B01J27/188 ,  B01J27/19 ,  B01J27/192 ,  B01J27/198 ,  C07C51/16 ,  C07C51/235

CPC分类号： C07C51/235 ,  B01J23/002 ,  B01J27/199 ,  B01J37/031 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/828

摘要： The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity.The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst.Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.

摘要翻译： 本发明是杂多酸化合物催化剂组合物，制备催化剂组合物的方法和使用催化剂组合物将饱和和/或不饱和醛氧化成不饱和羧酸的方法。 催化剂组合物是含有钼，钒，磷，铯，铋，铜和锑的杂多酸化合物。 铯含量较高（高于3.0）可达到热稳定性，但必须存在锑，铜和铋以保持良好的活性。 通过将各种杂多酸化合物的组分的化合物溶解在溶液中，沉淀杂多酸化合物，获得催化剂前体和煅烧催化剂前体以形成杂多酸化合物催化剂来制备催化剂。 不饱和醛如甲基丙烯醛可在杂多酸化合物催化剂存在下被氧化，生成不饱和羧酸，如甲基丙烯酸。

公开(公告)号：US20120016159A1

公开(公告)日：2012-01-19

申请号：US12838863

申请日：2010-07-19

申请人： Wugeng Liang ,  David Sullivan ,  James W. Kauffman ,  Clark Rea ,  Joe Linzer ,  Shahid Shaikh

发明人： Wugeng Liang ,  David Sullivan ,  James W. Kauffman ,  Clark Rea ,  Joe Linzer ,  Shahid Shaikh

IPC分类号： C07C51/25 ,  C07C51/235 ,  B01J27/199

CPC分类号： C07C51/235 ,  B01J23/002 ,  B01J27/199 ,  B01J37/031 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/828

摘要： The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity.The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst.Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.

摘要翻译： 本发明是杂多酸化合物催化剂组合物，制备催化剂组合物的方法和使用催化剂组合物将饱和和/或不饱和醛氧化成不饱和羧酸的方法。 催化剂组合物是含有钼，钒，磷，铯，铋，铜和锑的杂多酸化合物。 铯含量较高（高于3.0）可达到热稳定性，但必须存在锑，铜和铋以保持良好的活性。 通过将各种杂多酸化合物的组分的化合物溶解在溶液中，沉淀杂多酸化合物，获得催化剂前体和煅烧催化剂前体以形成杂多酸化合物催化剂来制备催化剂。 不饱和醛如甲基丙烯醛可在杂多酸化合物催化剂存在下被氧化，生成不饱和羧酸，如甲基丙烯酸。