摘要:
Methods of making catalysts for oxidation of unsaturated and/or saturated aldehyde to unsaturated acids is disclosed where the catalyst including at least molybdenum (Mo) and phosphorus (P), where the catalyst has a pore size distribution including at least 50% medium pores and if bismuth is present, a nitric acid to molybdenum mole ratio of at least 0.5:1 or at least 6.0:1 moles of HNO3 per mole of Mo12.
摘要:
A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.
摘要:
Ultraviolet light stable polymeric resin compositions comprising an ultraviolet light degradable polymeric resin component and an effective ultraviolet light absorbing amount of a particulate metal titanate component.
摘要:
A catalyst composition useful for the dehydrogenation of hydrocarbon comprises components (A)-(G). Component (A) is a catalyst substrate. (B) is platinum. (C) is at least one of germanium, tin, lead, gallium, indium, and titanium. (D) is phosphorus, the total amount of component (D) being at a level of from 1 wt. % to 3 wt. %. (E) is at least one of magnesium, calcium, strontium, barium, radium, and a lanthanide, the total amount of component (E) being at a level of from 0.1 wt. % to 5 wt. %. (F) is chloride at a level of 0.1 wt. % to 2 wt. %. Component (G) is manganese. The catalyst may be used in the conversion of hydrocarbons wherein a hydrocarbon feed is contacted with the catalyst within a reactor under hydrocarbon conversion reaction conditions to form hydrocarbon conversion products. Sources of the various components are combined in a method to form the catalyst composition.
摘要:
A catalyst for the oxidation of an olefin to an unsaturated aldehyde comprising a mixed metal oxide having the formula (I): MoaWbMcM′dM″eZfOg (I) where M represents trivalent metals, M′ represents divalent metals, M″ represents monovalent metals, Z represents elements in the form of an oxide, a, b, c, d, e, f and g are numbers, and where the catalyst has an anion to cation molar (ACM) ratio greater than 1.00 and less than 2.00 and an M′ to M molar ratio between 1.95 and 2.15.
摘要:
Methods for making unsaturated acids using catalysts for oxidation of unsaturated and/or Saturated aldehyde to unsaturated acids is disclosed where the catalyst including at least molybdenum (Mo) and phosphorus (P), where the catalyst has a pore size distribution including at least 50% medium pores and if bismuth is present, a nitric acid to molybdenum mole ratio of at least 0.5:1 or at least 6.0:1 moles of HNO3 per mole of Mo12.
摘要:
A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula: Mo12BiaWbFecCodNieSbfCsgMghZniPjOx wherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3-5.0, c:a=2.0-6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95-1.10.
摘要翻译:用于通过气相催化氧化烯烃(例如异丁烯)来生产不饱和醛如甲基丙烯醛的催化剂含有钼,铋,铁,铯和任选的其它金属的氧化物。 催化剂具有一定的铯与铋的相对量比,铁与铋的一定相对量比,以及铋,铁,铯和某些其它金属与钼和任选的钨的一定相对量比。 对于下式的催化剂:<?in-line-formula description =“In-line Formulas”end =“lead”?> Mo sub> sub> > C sub> C sub> C sub> C sub> &lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt; in-line-formula description =“In-line 其中a为0.1〜1.5,b为0〜4,c为0.2〜5.0,d为0〜9,e为0〜9,f为0〜2.0,g为0.4 至1.5,h为0至1.5,i为0至2.0,j为0至0.5,x由其它组分的化合价决定,c:g = 3.3-5.0,c:a = 2.0-6.0和(3a + 3c + 2d + 2e + g + 2h + 2i)/(2×12 + 2b)= 0.95-1.10。
摘要:
A process for producing a conductive, fluorine-doped titanium dioxide product which is doped throughout, said process comprising the steps of: (a) reacting the precursors in a system to form fluorine-doped TiO.sub.2, said precursors consisting essentially of a titanium alkoxide and a fluorine source; (b) reducing the fluorine-doped titanium dioxide product at a temperature sufficient to form said conductive, fluorine-doped titanium dioxide product; and (c) recovering the reduced product.
摘要:
The invention is for a method for making a heteropoly acid compound catalyst from compounds containing molybdenum, vanadium, phosphorus, cesium, copper, bismuth, antimony and boron in which molybdenum, vanadium, phosphorus, cesium, copper, bismuth and boron are at their highest oxidation states and antimony has a 3+ oxidation state. The catalyst contains oxides of molybdenum, vanadium, phosphorus, cesium, copper, bismuth, antimony, boron and, optionally, other metals. The catalyst has the formula: Mo12VaPbCscCudBieSbfBgOx where Mo is molybdenum, V is vanadium, P is phosphorus, Cs is cesium, Cu is copper, Bi is bismuth, Sb is antimony, B is boron, O is oxygen, a is 0.01 to 5.0, b is 0.5 to 3.5, c is 0.01 to 2.0, d is 0.0-1.5, e is 0.0-2.0, f is 0.01-3.0, g is 0.0-4.0 and x satisfies the valences. Molybdenum is reduced by antimony and reoxidized during catalyst synthesis.
摘要:
A catalyst for the oxidation of an olefin to an unsaturated aldehyde comprising a mixed metal oxide having the formula (I): MoaWbMcM′dM″eZfOg (I) where M represents trivalent metals, M′ represents divalent metals, M″ represents monovalent metals, Z represents elements in the form of an oxide, a, b, c, d, e, f and g are numbers, and where the catalyst has an anion to cation molar (ACM) ratio greater than 1.00 and less than 2.00 and an M′ to M molar ratio between 1.95 and 2.15.