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    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    1.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100311932A1

    公开(公告)日：2010-12-09

    申请号：US12859337

    申请日：2010-08-19

    申请人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/08 ,  B01J31/12

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Catalytic trimerization and tetramerization of olefinic monomers
    4.
    发明授权
    Catalytic trimerization and tetramerization of olefinic monomers 失效
    烯烃单体的催化三聚和四聚

    公开(公告)号：US07381857B2

    公开(公告)日：2008-06-03

    申请号：US11770520

    申请日：2007-06-28

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C07C2/08

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I): (R1)(R2)P-X-P(R3)(R4)  (I) where X is a bivalent organic bridging group, R1 and R3 are hydrocarbyl groups, and R2 and R4 are aromatic groups; and c) a second ligand having the general formula (II): (R1′)(R2′)P-X′-P(R3′)(R4′)  (II) where X′ is a bridging group containing nitrogen and R1′, R2′, R3′ and R4′ are hydrocarbyl groups. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    摘要翻译： 一种催化剂前体组合物，其包含a）铬，钼或钨的源; b）具有通式（I）的第一配体：<？in-line-formula description =“In-line formula”end =“lead”？>（R 1 SUP） （2）PXP（R 3）（R 4）（I）<βin-line-formula description =“In-line Formulas”end = “尾”→>其中X是二价有机桥基，R 1和R 3是烃基，R 2和R 2， SUP> 4是芳基; 和（c）具有通式（II）的第二配位体：<？in-line-formula description =“In-line formula”end =“lead”→（R 1> （二）'P-X'-P（R 3'）（R 4'）（II）<β在线式 description =“In-line Formulas”end =“tail”？>其中X'是含有氮和R 1'的桥连基团，R 2'，R“ > 3'和R 4'是烃基。 本发明还涉及包含本发明的催化剂前体组合物和助催化剂的催化剂体系。

    Catalytic trimerization and tetramerization of olefinic monomers
    5.
    发明授权
    Catalytic trimerization and tetramerization of olefinic monomers 有权

    公开(公告)号：US07259123B2

    公开(公告)日：2007-08-21

    申请号：US11398777

    申请日：2006-04-06

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： B01J31/00 ,  C07C2/08

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I); (R1)(R2)P—X—P(R3)(R4)  (I) wherein X is a bivalent organic bridging group; R1 and R3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R1 and R3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R2 and R4 are independently selected from optionally substituted aromatic groups, each R2 and R4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II); (R1′)(R2′)P—X′—P(R3′)(R4′)  (II) wherein X′ is a bridging group of the formula —N(R5′)—, wherein R5′ is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R1′, R2′, R3′ and R4′ is substituted with a polar substituent, or R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R1′, R2′, R3′ and R4′ are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
    6.
    发明授权
    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers 有权
    用于催化低聚烯烃单体的配体及其催化剂体系

    公开(公告)号：US07803886B2

    公开(公告)日：2010-09-28

    申请号：US11961638

    申请日：2007-12-20

    申请人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/535 ,  B01J31/02

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3)  (I) wherein: the R1 group and R2 group are independently selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R 4）-P（R 1）（R 2）= N（R 3）（I）其中：R 1基团和R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Transition metal complexes
    7.
    发明授权
    Transition metal complexes 失效
    过渡金属络合物

    公开(公告)号：US07547783B2

    公开(公告)日：2009-06-16

    申请号：US11088023

    申请日：2005-03-23

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C07F15/00 ,  B01J31/22 ,  C08F4/80

    CPC分类号： B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0244 ,  B01J2531/842 ,  B01J2531/845 ,  C07F11/005 ,  C07F15/025 ,  C07F15/065 ,  C08F10/00 ,  C08F4/60089 ,  C08F4/69224 ,  C08F4/7042

    摘要： A transition metal complex which is a bis-arylimine pyridine MXn complex or a [bis-arylimine pyridine MXp+][NC−]q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC− is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.

    摘要翻译： 作为双芳基亚胺吡啶MXn络合物或包含双芳基亚胺吡啶配体的[双芳基亚胺吡啶MXp +] [NC-] q络合物的过渡金属络合物，M为过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物; NC-是非配位阴离子; 并且p + q与过渡金属原子M的正式氧化态匹配。本发明的过渡金属络合物，其与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质中具有良好的溶解性和化学惰性非 极性溶剂，特别是芳族烃溶剂。 催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。

    LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS
    8.
    发明申请
    LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 失效
    用于烯烃单体低级化的配体和催化剂体系

    公开(公告)号：US20090069517A1

    公开(公告)日：2009-03-12

    申请号：US11961719

    申请日：2007-12-20

    申请人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/535 ,  C07D265/30 ,  B01J31/18 ,  C07C69/76

    CPC分类号： C07F11/005 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/20 ,  B01J2531/60 ,  B01J2531/62 ,  C07C2/36 ,  C07C2531/24 ,  C07F9/5355

    摘要： The present invention relates to ligands and catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands, the ligands having the general formula (I): (R1)2P—P(R1)m(R2)n═N(R3)  (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; with the proviso that m is 0 or 1, n is 1 or 2 and the total of m+n is 2.

    摘要翻译： 本发明涉及配体和催化剂体系，以及使用所述配体同时使烯属单体三聚和四聚的方法，具有通式（I）的配位体：<？in-line-formula description =“In-line Formulas” （R1）2P-P（R1）m（R2）nN（R3）（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中 R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基; 条件是m为0或1，n为1或2，m + n的总数为2。

    Catalyst systems for the catalytic oligomerization of olefinic monomers
    9.
    发明授权
    Catalyst systems for the catalytic oligomerization of olefinic monomers 失效
    用于催化低聚烯烃单体的催化剂体系

    公开(公告)号：US08680220B2

    公开(公告)日：2014-03-25

    申请号：US13204020

    申请日：2011-08-05

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/78 ,  B01J31/00 ,  C07F9/6574

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI): (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy or alkylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the alkylenedioxy or alkylenedimercapto structure or an optionally substituted arylenedioxy or arylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the arylenedioxy or arylenedimercapto structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的用途，具有通式（VI）的配体：（R9）（R10）P-N（R3）-P（R4）（VI） 其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R4基团是任选取代的亚烷基二氧基或亚烷基二巯基结构，其通过亚烷基二氧基或亚烷基二巯基结构的两个氧原子或硫原子与磷原子结合，或者通过两个氧与磷原子结合的任选取代的亚芳基二氧基或亚芳基二巯基结构 或亚芳基二氧基或亚芳基二巯基结构的硫原子。